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Rapid Commun."],"published-print":{"date-parts":[[2025,12]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Supramolecular coordination complexes (SCCs) possess precise molecular architectures attractive for catalysis, sensing, and nanomedicine, yet their thermal processing into bulk materials is severely hindered by strong \u03c0\u2013\u03c0 stacking interactions, typically restricting them to solution, gel, or particulate forms. Herein, this study reports a thermally\u2010processable metallacage\n                    <jats:bold>TPMc,<\/jats:bold>\n                    decorated with six polyethylene glycol chains (PEG) that overcome this fundamental limitation. PEG chains act as a \u201cmolecular lubricant\u201d that disrupts intermolecular forces and expands intermolecular distances, endowing\n                    <jats:bold>TPMc<\/jats:bold>\n                    with thermal processability that enables thermal fabrication for free\u2010standing bulk materials with various shapes while simultaneously maintaining self\u2010healing and reprocessing capabilities without structural degradation. As proof of application,\n                    <jats:bold>TPMc<\/jats:bold>\n                    bulk material was employed as an ionic conductor for ultrasensitive thermal sensing, which exhibited an ultrahigh thermal response (3294.9% at 60\u00b0C) and remained functional even after damage or reconfiguration. This work overcomes the processing barrier of SCCs, expands their potential in recyclable electronics, and paves the way for broader practical applications of SCCs\u2010based bulk materials.\n                  <\/jats:p>","DOI":"10.1002\/marc.202500612","type":"journal-article","created":{"date-parts":[[2025,10,11]],"date-time":"2025-10-11T14:20:31Z","timestamp":1760192431000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["A Thermally\u2010Processable Conductive Supramolecular Metallacage Decorated with Polyethylene Glycol Chains for Self\u2010Healable and Recyclable Electronics"],"prefix":"10.1002","volume":"46","author":[{"given":"Yinglong","family":"Bao","sequence":"first","affiliation":[{"name":"Zhejiang Key Laboratory of Organosilicon Material Technology College of Materials, Chemistry and Chemical Engineering Key Laboratory of Organosilicon Chemistry and Materials Technology of the Ministry of Education Hangzhou Normal University  Hangzhou Zhejiang P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Miaomiao","family":"Yan","sequence":"additional","affiliation":[{"name":"Zhejiang Key Laboratory of Organosilicon Material Technology College of Materials, Chemistry and Chemical Engineering Key Laboratory of Organosilicon Chemistry and Materials Technology of the Ministry of Education Hangzhou Normal University  Hangzhou Zhejiang P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Shenglong","family":"Liao","sequence":"additional","affiliation":[{"name":"School of Engineering Hangzhou Normal University Hangzhou Zhejiang P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1086-1755","authenticated-orcid":false,"given":"Shouchun","family":"Yin","sequence":"additional","affiliation":[{"name":"Zhejiang Key Laboratory of Organosilicon Material Technology College of Materials, Chemistry and Chemical Engineering Key Laboratory of Organosilicon Chemistry and Materials Technology of the Ministry of Education Hangzhou Normal University  Hangzhou Zhejiang P. R. 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