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First, the fabrication methods are introduced. Corresponding to different methods, the morphology of the as\u2010obtained fibers is highlighted. Then, their structural characteristics are analyzed in comparison with the 2D film counterparts. The relationship between their microstructure and electrical\/mechanical properties is also discussed. In addition, their applications in Joule heating, thermoelectric conversion, multifunctional sensing, energy storage etc. are summarized with a few representative examples. Finally, our perspectives on the main challenges and future development of the fiber\u2010type PEDOT:PSS\u2010based materials and devices are outlooked.<\/jats:p>","DOI":"10.1002\/marc.202500639","type":"journal-article","created":{"date-parts":[[2025,10,17]],"date-time":"2025-10-17T17:35:42Z","timestamp":1760722542000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["Highly Conductive and Mechanically Robust PEDOT:PSS\u2010Based Fibers: Fabrication Methods, Structure\u2010Property Relations, and Potential Applications"],"prefix":"10.1002","volume":"46","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-8210-0790","authenticated-orcid":false,"given":"Zeng","family":"Fan","sequence":"first","affiliation":[{"name":"School of Physics Dalian University of Technology  Dalian Liaoning 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