{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,17]],"date-time":"2026-07-17T17:04:22Z","timestamp":1784307862565,"version":"3.55.0"},"reference-count":48,"publisher":"Wiley","issue":"10","license":[{"start":{"date-parts":[[2025,12,12]],"date-time":"2025-12-12T00:00:00Z","timestamp":1765497600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2025,12,12]],"date-time":"2025-12-12T00:00:00Z","timestamp":1765497600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Macromol. Rapid Commun."],"published-print":{"date-parts":[[2026,5]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Size\u2010exclusion chromatography (SEC) equipped with refractive index (RI) and multi\u2010angle light scattering (MALS) detectors was carried out on a polystyrene (PS) sample with the weight\u2010average molecular weight 2.07 \u00d7\u20ac10\n                    <jats:sup>4<\/jats:sup>\n                    along with the matrix\u2010assisted laser desorption flight time mass spectrometry (MALDI\u2010TOF\u2010MS). The MALDI\u2010TO\u2010MS result was corrected by the relative sensitivity, which was found to decay exponentially with the molecular weight. Exchanging the elution volume for molecular weight by the calibration relation, the molecular\u2010weight distribution (MWD) curves were obtained from the chromatograms. The MWD curve determined by the SEC chromatogram was much broader than that obtained by MALS and MALDI\u2010TOF\u2010MS because of the peak\u2010broadening effect. Based on the MWD determined by MALDI\u2010TOF\u2010MS, the RI chromatogram was closely described by the calculated values using the Gaussian function. Based on the results of the PS sample, RI and MALS data of polyethylene oxide samples in water were analyzed using the exponentially modified Gaussian equation.\n                  <\/jats:p>","DOI":"10.1002\/marc.202500706","type":"journal-article","created":{"date-parts":[[2025,12,13]],"date-time":"2025-12-13T01:10:27Z","timestamp":1765588227000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Precise Determination of the Band\u2010Broadening Function for the Size\u2010Exclusion Chromatography using Multi\u2010Angle Light Scattering and Mass Spectrometric Measurements on Polymers"],"prefix":"10.1002","volume":"47","author":[{"given":"Yasushi","family":"Kondo","sequence":"first","affiliation":[{"name":"Department of Polymer Chemistry Kyoto University  Kyoto Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4432-0551","authenticated-orcid":false,"given":"Yo","family":"Nakamura","sequence":"additional","affiliation":[{"name":"Department of Polymer Chemistry Kyoto University  Kyoto Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,12,12]]},"reference":[{"key":"e_1_2_9_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/pol.1974.170120602"},{"key":"e_1_2_9_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0021-9673(00)82167-6"},{"key":"e_1_2_9_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/0003-2670(93)80373-S"},{"key":"e_1_2_9_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/j150527a009"},{"key":"e_1_2_9_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/app.1966.070100904"},{"key":"e_1_2_9_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/app.1966.070100905"},{"key":"e_1_2_9_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/app.1966.070100303"},{"key":"e_1_2_9_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/app.1969.070130416"},{"key":"e_1_2_9_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/polc.5070210109"},{"key":"e_1_2_9_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/app.1969.070130709"},{"key":"e_1_2_9_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/app.1971.070150705"},{"key":"e_1_2_9_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/ac60276a013"},{"key":"e_1_2_9_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/ac60319a011"},{"key":"e_1_2_9_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/ac50011a017"},{"key":"e_1_2_9_16_1","doi-asserted-by":"publisher","DOI":"10.1093\/chromsci\/22.1.40"},{"key":"e_1_2_9_17_1","doi-asserted-by":"publisher","DOI":"10.1093\/chromsci\/29.6.258"},{"key":"e_1_2_9_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0021-9673(01)96215-6"},{"key":"e_1_2_9_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/0021-9673(93)80442-B"},{"key":"e_1_2_9_20_1","doi-asserted-by":"publisher","DOI":"10.1016\/0021-9673(93)83380-B"},{"key":"e_1_2_9_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/ma000011c"},{"key":"e_1_2_9_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0021-9673(01)01159-1"},{"key":"e_1_2_9_23_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0021-9673(01)00594-5"},{"key":"e_1_2_9_24_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2006.06.062"},{"key":"e_1_2_9_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/masy.200751221"},{"key":"e_1_2_9_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/ma062973a"},{"key":"e_1_2_9_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/mats.201100038"},{"key":"e_1_2_9_28_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2016.03.030"},{"key":"e_1_2_9_29_1","doi-asserted-by":"publisher","DOI":"10.1039\/fs9801500127"},{"key":"e_1_2_9_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1097-0231(19981215)12:23<1895::AID-RCM414>3.0.CO;2-2"},{"key":"e_1_2_9_31_1","doi-asserted-by":"publisher","DOI":"10.1002\/rcm.224"},{"key":"e_1_2_9_32_1","doi-asserted-by":"publisher","DOI":"10.1255\/ejms.141"},{"key":"e_1_2_9_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/ac9702610"},{"key":"e_1_2_9_34_1","doi-asserted-by":"publisher","DOI":"10.1021\/ac9707794"},{"key":"e_1_2_9_35_1","doi-asserted-by":"publisher","DOI":"10.1002\/app.21803"},{"key":"e_1_2_9_36_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2004.05.099"},{"key":"e_1_2_9_37_1","doi-asserted-by":"publisher","DOI":"10.1021\/ac951103g"},{"key":"e_1_2_9_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/ac0002745"},{"key":"e_1_2_9_39_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0032-3861(02)00213-6"},{"key":"e_1_2_9_40_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.polymer.2004.10.004"},{"key":"e_1_2_9_41_1","doi-asserted-by":"publisher","DOI":"10.1295\/koron.2018-0010"},{"key":"e_1_2_9_42_1","volume-title":"Principles of Polymer Chemistry","author":"Flory P. 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