{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,3,20]],"date-time":"2026-03-20T14:21:24Z","timestamp":1774016484093,"version":"3.50.1"},"reference-count":39,"publisher":"Wiley","issue":"6","license":[{"start":{"date-parts":[[2026,1,14]],"date-time":"2026-01-14T00:00:00Z","timestamp":1768348800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,1,14]],"date-time":"2026-01-14T00:00:00Z","timestamp":1768348800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Macromol. Rapid Commun."],"published-print":{"date-parts":[[2026,3]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>Achieving both high strength and reprocessability in a single plastics material remains a fundamental challenge. Herein, we report the design and synthesis of novel supramolecular polydiketoenamine (PDK) network materials that were synergistically dual crosslinked by both the dynamic diketoenamine bonds and supramolecular cross\u2010links (hydrogen\u2010bonded benzene\u20101,3,5\u2010tricarboxamide units). As a result, the PDK films exhibited a well\u2010balanced combination of mechanical robustness and dynamic adaptability, achieving a high tensile strength of up to \u223c77.21\u00a0MPa along with outstanding thermal reshaping and self\u2010healing capabilities. Remarkably, beyond serving as strong structural films, the PDK plastic film exhibited superior performance as solid\u2010state adhesives for diverse substrates\u2014glass, metal, ceramic\u2014exhibiting an enhanced lap\u2010shear strength (up to \u223c23.51\u00a0MPa) and retaining over 90% of its performance on glass after multiple reprocessing cycles. This work provides a promising strategy of integrating supramolecular cross\u2010links into covalent adaptive network to construct high\u2010performance, reprocessable network polymers that bridge the gap between the robustness of thermosets and the reprocessability of the thermoplastics.<\/jats:p>","DOI":"10.1002\/marc.202500925","type":"journal-article","created":{"date-parts":[[2026,1,14]],"date-time":"2026-01-14T10:14:43Z","timestamp":1768385683000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["High\u2010Strength and Reprocessable Supramolecular Polydiketoenamine Network Materials for Sustainable Adhesives"],"prefix":"10.1002","volume":"47","author":[{"given":"Yifan","family":"Ke","sequence":"first","affiliation":[{"name":"State Key Laboratory of Advanced Fiber Materials College of Materials Science and Engineering Donghua University  Shanghai 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