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Rapid Commun."],"published-print":{"date-parts":[[2026,5]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Block copolymers (BCPs) can self\u2010assemble into various nanostructures. The introduction of polymers with special properties, such as liquid crystalline (LC) and semicrystalline ones, will affect the self\u2010assembled structures of BCPs. In this work, BCPs containing a coil block polydimethylsiloxane (PDMS), an LC block poly[4\u2032\u2010(methoxy)\u20102\u2010vinylbiphenyl\u20104\u2010methyl ether] (PMVBP) that is a mesogen\u2010jacketed LC polymer (MJLCP), and a semicrystalline poly(L\u2010lactic acid) (PLLA) were synthesized. The diblock copolymer PLLA\u2010\n                    <jats:italic>b<\/jats:italic>\n                    \u2010PMVBP does not form ordered nanostructures because the solubility parameters of the two blocks are quite close. The triblock copolymer PDMS\u2010\n                    <jats:italic>b<\/jats:italic>\n                    \u2010PLLA\u2010\n                    <jats:italic>b<\/jats:italic>\n                    \u2010PMVBP forms the lamellar (LAM) structure at ambient temperature and the hexagonally packed cylindrical (HEX) structure at high temperatures. The results of temperature\u2010dependent small\u2010angle x\u2010ray scattering show that the crystallization of PLLA significantly affects the self\u2010assembled structures of the BCPs. Crystallization of PLLA may compete or couple with the microphase separation of the BCP. In addition, a rare type of phase transformation, lower disorder\u2010order transition (LDOT), is observed in the sample D\n                    <jats:sub>56<\/jats:sub>\n                    L\n                    <jats:sub>19<\/jats:sub>\n                    V\n                    <jats:sub>4<\/jats:sub>\n                    .\n                  <\/jats:p>","DOI":"10.1002\/marc.202500958","type":"journal-article","created":{"date-parts":[[2026,3,9]],"date-time":"2026-03-09T03:34:06Z","timestamp":1773027246000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Competition and Coupling Between Crystallization and Microphase Separation in a Triblock Copolymer"],"prefix":"10.1002","volume":"47","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-3791-2279","authenticated-orcid":false,"given":"Shichu","family":"Yang","sequence":"first","affiliation":[{"name":"Beijing National Laboratory for Molecular Sciences Key Laboratory of Polymer Chemistry and Physics of Ministry of Education College of Chemistry and Molecular Engineering Peking University  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2858-555X","authenticated-orcid":false,"given":"Zhihao","family":"Shen","sequence":"additional","affiliation":[{"name":"Beijing National Laboratory for Molecular Sciences Key Laboratory of Polymer Chemistry and Physics of Ministry of Education College of Chemistry and Molecular Engineering Peking University  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0585-2558","authenticated-orcid":false,"given":"Xing\u2010He","family":"Fan","sequence":"additional","affiliation":[{"name":"Beijing National Laboratory for Molecular Sciences Key Laboratory of Polymer Chemistry and Physics of Ministry of Education College of Chemistry and Molecular Engineering Peking University  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6174-8720","authenticated-orcid":false,"given":"Yuguo","family":"Ma","sequence":"additional","affiliation":[{"name":"Beijing National Laboratory for Molecular Sciences Key Laboratory of Polymer Chemistry and Physics of Ministry of Education College of Chemistry and Molecular Engineering Peking University  Beijing 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