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Rapid Commun."],"published-print":{"date-parts":[[2026,6]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Polymer cubosomes (PCs) have attracted considerable attention in nanomaterials research due to their high specific surface areas. Polymerization\u2010induced self\u2010assembly (PISA) provides an efficient and versatile route for preparing such structures. However, the critical role of hydrophilic stabilizers with tailored architectures in PC fabrication has remained incompletely understood. Herein, we investigate the effect of stabilizers containing poly (ethylene glycol) (PEG) oligomeric side\u2010chains with elaborate adjustment of position and content on the formation of PCs via PISA. The stabilizers include poly(poly (ethylene glycol) methyl ether methacrylate (\n                    <jats:italic>o<\/jats:italic>\n                    E), poly(hydroxypropyl methacrylate (H), and their block copolymers (\n                    <jats:italic>o<\/jats:italic>\n                    E\u2010\n                    <jats:italic>b<\/jats:italic>\n                    \u2010H and H\u2010\n                    <jats:italic>b<\/jats:italic>\n                    \u2010\n                    <jats:italic>o<\/jats:italic>\n                    E), and the core\u2010forming monomer is styrene (St). Compared with the homopolymer\u2010type stabilizers, a high feeding ratio of St to stabilizers is needed to form PCs for block copolymer\u2010type stabilizers. This is attributed to impeded morphological fusion resulting from incompatibility between\n                    <jats:italic>o<\/jats:italic>\n                    E and H segments. Additionally, increasing the\n                    <jats:italic>o<\/jats:italic>\n                    E content in H\u2010\n                    <jats:italic>b<\/jats:italic>\n                    \u2010\n                    <jats:italic>o<\/jats:italic>\n                    E\u2010type stabilizers leads to a more substantial St amount for preparing PCs than in\n                    <jats:italic>o<\/jats:italic>\n                    E\u2010\n                    <jats:italic>b<\/jats:italic>\n                    \u2010H\u2010type stabilizers. We propose that excess St acts as a plasticizer, mitigating the strong steric hindrance imposed by PEG side\u2010chains near the hydrophobic\/hydrophilic interface. We believe that this work will enrich the fundamental research for PISA\u2010mediated PC preparation through stabilizer engineering.\n                  <\/jats:p>","DOI":"10.1002\/marc.70250","type":"journal-article","created":{"date-parts":[[2026,3,8]],"date-time":"2026-03-08T16:59:22Z","timestamp":1772989162000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Influence of Hydrophile Topology on the Formation of Polymer Cubosomes by Polymerization\u2010Induced Self\u2010Assembly"],"prefix":"10.1002","volume":"47","author":[{"given":"Yalan","family":"Sun","sequence":"first","affiliation":[{"name":"School of Materials Science and Engineering Beihang University  Beijing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yongbin","family":"Zhao","sequence":"additional","affiliation":[{"name":"Suzhou Laboratory  Suzhou Jiangsu P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Aihua","family":"Chen","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering Beihang University  Beijing P. R. China"},{"name":"State Key Laboratory of Tropic Ocean Engineering Materials and Materials Evaluation School of Materials Science and Engineering Beihang University  Beijing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,2,28]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms5110"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1007\/s40843-019-1261-1"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1PY00115A"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.0c05797"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0CS00021C"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202402005"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202207684"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.9b00563"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/marc.202100194"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2cs35115c"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201702591"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201804401"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.1946"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsmacrolett.9b00464"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0PY00455C"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cclet.2024.110431"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/marc.201500122"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-019-09324-5"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9SC00303G"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.0c09166"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2PY00701K"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.8b01121"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8PY01617H"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10118-025-3275-0"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.5b00850"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/pola.26478"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1002\/pola.26704"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201511159"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcb.9b03622"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1002\/marc.202400891"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.4c00080"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.langmuir.4c02131"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10118-024-3198-1"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.1c01180"}],"container-title":["Macromolecular Rapid Communications"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/marc.70250","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/marc.70250","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/marc.70250","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,6,14]],"date-time":"2026-06-14T15:19:09Z","timestamp":1781450349000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/marc.70250"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,2,28]]},"references-count":34,"journal-issue":{"issue":"11","published-print":{"date-parts":[[2026,6]]}},"alternative-id":["10.1002\/marc.70250"],"URL":"https:\/\/doi.org\/10.1002\/marc.70250","archive":["Portico"],"relation":{},"ISSN":["1022-1336","1521-3927"],"issn-type":[{"value":"1022-1336","type":"print"},{"value":"1521-3927","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,2,28]]},"assertion":[{"value":"2025-12-29","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-02-17","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-02-28","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e70250"}}