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Rapid Commun."],"published-print":{"date-parts":[[2026,6]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>We study the impact of polymer composition on the self\u2010assembly and optical properties in water of amphiphilic copolymers containing perylene imides (PIs) as pendant groups. To achieve this, a new perylene imide acrylate monomer is synthesized, in only four synthetic steps, and copolymerized with various comonomers to produce amphiphilic copolymers with block, statistical or block\u2010statistical architectures. We observe that the assembly in water is affected by changes in the macromolecular architecture or by the comonomer used, resulting not only in spherical, but also in vesicular nanoparticles. We found differences in the copolymer architecture also influence the perylene's intramolecular aggregation within the chain, with the formation of H\u2010type aggregates. The generally observed red\u2010shifted emission was attributed to the formation of excimer\u2010like species, which might be interesting for electron transport applications. Finally, we demonstrate that by employing Polymerization\u2010Induced Self\u2010Assembly (PISA), fluorescent nanoparticles can readily be obtained in a water\/ethanol (50\/50) mixture at high solids (20 wt%).<\/jats:p>","DOI":"10.1002\/marc.70260","type":"journal-article","created":{"date-parts":[[2026,3,20]],"date-time":"2026-03-20T03:45:46Z","timestamp":1773978346000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Stirring up Emission: Tuning the Emissive Properties of Perylene Imide\u2010Polymers in Water via Polymer Design"],"prefix":"10.1002","volume":"47","author":[{"given":"S\u00e9bastien","family":"Berru\u00e9e","sequence":"first","affiliation":[{"name":"Institut Parisien de Chimie Mol\u00e9culaire (IPCM) Sorbonne Universit\u00e9, CNRS, Polymer Chemistry Team  Paris 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