{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,7]],"date-time":"2026-09-07T06:08:53Z","timestamp":1788761333457,"version":"build-2803163510"},"reference-count":58,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,9,6]],"date-time":"2026-09-06T00:00:00Z","timestamp":1788652800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc\/4.0\/"},{"start":{"date-parts":[[2026,9,6]],"date-time":"2026-09-06T00:00:00Z","timestamp":1788652800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Macromol. Rapid Commun."],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Developing recyclable thermosets without sacrificing structural integrity remains a significant hurdle in polymer circularity. In this study, we present a high\u2010performance, chemically recyclable epoxy thermoset based on 1,3,5\u2010triazine, demonstrating significant advancements in material recyclability and application potential. Utilizing liquid precursors, that is a trifunctional epoxy monomer (TOMTA) and a strategically selected secondary aromatic diamine hardener (MBMA), a cross\u2010linked network with a well\u2010defined architecture was produced under bulk conditions. The resulting thermoset exhibited exceptional thermal and mechanical properties as evidenced by a high glass transition temperature (\n                    <jats:italic>\n                      T\n                      <jats:sub>g<\/jats:sub>\n                    <\/jats:italic>\n                    \u00a0=\u00a0105\u00b0C), thermal stability (\n                    <jats:italic>\n                      T\n                      <jats:sub>d5%<\/jats:sub>\n                    <\/jats:italic>\n                    \u00a0=\u00a0256\u00b0C), a Young's modulus of 3.0\u00a0GPa, and a tensile strength of 96\u00a0MPa, placing the material in the same performance range of conventional epoxy resins. Driven by an optimized binary K\n                    <jats:sub>2<\/jats:sub>\n                    CO\n                    <jats:sub>3<\/jats:sub>\n                    \/TBD catalytic system in ethanol, the network underwent depolymerization enabled by a nucleophilic aromatic substitution reaction (S\n                    <jats:sub>N<\/jats:sub>\n                    Ar), yielding the well\u2010defined building blocks TETA and the tetraol BDHPPM in 70% and 65%, respectively, via straightforward liquid\u2010liquid extraction. Re\u2010crosslinking these recovered building blocks regenerated the network, preserving nearly identical properties across multiple recycling cycles. The system was further applied as a debondable coating for glass. This 1,3,5\u2010triazine\u2010based network utilizing S\n                    <jats:sub>N<\/jats:sub>\n                    Ar chemistry provides a robust route to high\u2010performance, recyclable epoxy thermosets.\n                  <\/jats:p>","DOI":"10.1002\/marc.70422","type":"journal-article","created":{"date-parts":[[2026,9,7]],"date-time":"2026-09-07T05:47:25Z","timestamp":1788760045000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["A Chemically Recyclable 1,3,5\u2010Triazine\u2010Based Epoxy Thermoset Enabled by Nucleophilic Aromatic Substitution Reaction"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-5735-1755","authenticated-orcid":false,"given":"Yi\u2010Ru","family":"Chen","sequence":"first","affiliation":[{"name":"Polymer Performance Materials Group Department of Chemical Engineering and Chemistry &amp; Institute for Complex Molecular Systems (ICMS) Eindhoven University of Technology  Eindhoven The Netherlands"},{"name":"Interactive Polymer Materials Research Center (IPM) Eindhoven University of Technology  Eindhoven The Netherlands"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5840-8952","authenticated-orcid":false,"given":"Fabian","family":"Eisenreich","sequence":"additional","affiliation":[{"name":"Polymer Performance Materials Group Department of Chemical Engineering and Chemistry &amp; Institute for Complex Molecular Systems (ICMS) Eindhoven University of Technology  Eindhoven The Netherlands"},{"name":"Interactive Polymer Materials Research Center (IPM) Eindhoven University of Technology  Eindhoven The Netherlands"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7614-5108","authenticated-orcid":false,"given":"A. Catarina C.","family":"Esteves","sequence":"additional","affiliation":[{"name":"Interactive Polymer Materials Research Center (IPM) Eindhoven University of Technology  Eindhoven The Netherlands"},{"name":"Laboratory of Physical Chemistry Department of Chemistry and Chemical Engineering &amp; Institute for Complex Molecular Systems (ICMS) Eindhoven University of Technology  Eindhoven The Netherlands"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7944-5728","authenticated-orcid":false,"given":"\u017deljko","family":"Tomovi\u0107","sequence":"additional","affiliation":[{"name":"Polymer Performance Materials Group Department of Chemical Engineering and Chemistry &amp; Institute for Complex Molecular Systems (ICMS) Eindhoven University of Technology  Eindhoven The Netherlands"},{"name":"Interactive Polymer Materials Research Center (IPM) Eindhoven University of Technology  Eindhoven The Netherlands"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,9,6]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacsau.2c00120"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/14356007.a09_547.pub2"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1201\/9780203756713"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jiec.2015.03.026"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.pmatsci.2015.01.004"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.polymdegradstab.2024.110980"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/asia.202300373"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201813525"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9PY01260E"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41570\u2010025\u201000686\u20107"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11426\u2010024\u20102550\u20106"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b07922"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202531566"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3PY00957B"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1039\/D5PY00124B"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4PY00038B"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.3c03189"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.8b01976"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202209912"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202504637"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.indcrop.2022.115857"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202113872"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202210405"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202519828"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.3c00761"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4SU00382A"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010024\u201049272\u20103"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202408299"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsapm.5c02478"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1002\/marc.202400678"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.polymer.2026.129986"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.2c03326"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.polymdegradstab.2015.04.016"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1002\/marc.202200538"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.reactfunctpolym.2021.105037"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1007\/978-94-011-1326-7"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1016\/B978-0-12-821632-3.00004-X"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9PY01610D"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41557\u2010018\u20100122\u20108"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41557\u2010022\u201001046\u20104"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c00778"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202407854"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202403931"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202507567"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejoc.201800835"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3PY00611E"},{"key":"e_1_2_8_48_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202409223"},{"key":"e_1_2_8_49_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202519660"},{"key":"e_1_2_8_50_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202408411"},{"key":"e_1_2_8_51_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.75558"},{"key":"e_1_2_8_52_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.6c02367"},{"key":"e_1_2_8_53_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4PY00051J"},{"key":"e_1_2_8_54_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202419240"},{"key":"e_1_2_8_55_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41893\u2010024\u201001331\u20109"},{"key":"e_1_2_8_56_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.compositesb.2022.110109"},{"key":"e_1_2_8_57_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.polymer.2023.126487"},{"key":"e_1_2_8_58_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsapm.4c02417"},{"key":"e_1_2_8_59_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.polymer.2023.125949"}],"container-title":["Macromolecular Rapid Communications"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/marc.70422","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/marc.70422","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/marc.70422","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,9,7]],"date-time":"2026-09-07T05:47:26Z","timestamp":1788760046000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/marc.70422"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,9,6]]},"references-count":58,"alternative-id":["10.1002\/marc.70422"],"URL":"https:\/\/doi.org\/10.1002\/marc.70422","archive":["Portico"],"relation":{},"ISSN":["1022-1336","1521-3927"],"issn-type":[{"value":"1022-1336","type":"print"},{"value":"1521-3927","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,9,6]]},"assertion":[{"value":"2026-08-01","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-08-26","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-09-06","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e70422"}}