{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,2]],"date-time":"2026-10-02T03:53:20Z","timestamp":1790913200883,"version":"4.1.0"},"reference-count":31,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,10,1]],"date-time":"2026-10-01T00:00:00Z","timestamp":1790812800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,10,1]],"date-time":"2026-10-01T00:00:00Z","timestamp":1790812800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Macromol. Rapid Commun."],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    In chemically driven soft materials, polymer architecture can shape how chemical reactions are transduced into material\u2010level dynamic behavior. However, the relationship between polymer architecture and the resulting dynamics remains insufficiently understood. Here, using Arrhenius analysis, we perform a cross\u2010hierarchical comparison of the temperature dependence of Belousov\u2013Zhabotinsky (BZ) reaction\u2010driven oscillatory dynamics across three structurally related systems: molecular Ru(bpy)\n                    <jats:sub>3<\/jats:sub>\n                    Cl\n                    <jats:sub>2<\/jats:sub>\n                    , a linear self\u2010oscillating polymer (SOP), and a self\u2010oscillating microgel (SOMG). In these systems, Ru(bpy)\n                    <jats:sub>3<\/jats:sub>\n                    complex is present in solution as a molecular catalyst or covalently incorporated into either a linear polymer or a crosslinked microgel network. The resulting apparent activation energies\n                    <jats:italic>E<\/jats:italic>\n                    <jats:sub>a, app<\/jats:sub>\n                    are used to quantify the overall temperature dependence of their oscillatory dynamics. In the SOP, the redox and coacervation\/dissolution oscillations exhibit similar\n                    <jats:italic>E<\/jats:italic>\n                    <jats:sub>a, app<\/jats:sub>\n                    values, indicating that periodic liquid\u2013liquid phase separation had only a limited effect on the overall temperature dependence. In contrast, in the SOMG, the flocculation\/dispersion oscillation exhibits a substantially higher\n                    <jats:italic>E<\/jats:italic>\n                    <jats:sub>a, app<\/jats:sub>\n                    than the redox oscillation. Moreover, the relative order of\n                    <jats:italic>E<\/jats:italic>\n                    <jats:sub>a, app<\/jats:sub>\n                    between the SOP and SOMG is reversed between the redox and structural oscillatory modes. These results indicate that\n                    <jats:italic>E<\/jats:italic>\n                    <jats:sub>a, app<\/jats:sub>\n                    is modulated by both the underlying polymer architecture and the architecture\u2010dependent structural dynamics accompanying BZ\u2010driven oscillations.\n                  <\/jats:p>","DOI":"10.1002\/marc.70448","type":"journal-article","created":{"date-parts":[[2026,10,2]],"date-time":"2026-10-02T02:54:52Z","timestamp":1790909692000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Cross\u2010Hierarchical Analysis of Self\u2010Oscillating Polymer Materials Through Activation Energy"],"prefix":"10.1002","author":[{"given":"Zhouna","family":"Tang","sequence":"first","affiliation":[{"name":"Department of Materials Engineering School of Engineering The University of Tokyo  Tokyo Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5137-6129","authenticated-orcid":false,"given":"Takafumi","family":"Enomoto","sequence":"additional","affiliation":[{"name":"Department of Materials Engineering School of Engineering The University of Tokyo  Tokyo Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0558-2922","authenticated-orcid":false,"given":"Ryo","family":"Yoshida","sequence":"additional","affiliation":[{"name":"Department of Materials Engineering School of Engineering The University of Tokyo  Tokyo Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,10,1]]},"reference":[{"key":"e_1_2_9_2_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6CS00738D"},{"issue":"18","key":"e_1_2_9_3_1","doi-asserted-by":"crossref","first-page":"5519","DOI":"10.1039\/C7CS00246G","article-title":"Dissipative Out\u2010of\u2010Equilibrium Assembly of Man\u2010Made Supramolecular Materials","volume":"46","author":"Rossum S. A. P.","year":"2017","journal-title":"Chemical Society Reviews"},{"key":"e_1_2_9_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7CS00089H"},{"issue":"3","key":"e_1_2_9_5_1","doi-asserted-by":"crossref","first-page":"552","DOI":"10.1016\/j.chempr.2019.11.008","article-title":"The Design of Dissipative Molecular Assemblies Driven by Chemical Reaction Cycles","volume":"6","author":"Rie\u00df B.","year":"2020","journal-title":"Chem"},{"key":"e_1_2_9_6_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.1723792"},{"key":"e_1_2_9_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0370\u20101573(99)00012\u20105"},{"key":"e_1_2_9_8_1","doi-asserted-by":"publisher","DOI":"10.1038\/pj.2010.110"},{"key":"e_1_2_9_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr8004235"},{"key":"e_1_2_9_10_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7CS00734E"},{"key":"e_1_2_9_11_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41428\u2010022\u201000638\u20108"},{"key":"e_1_2_9_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja9602511"},{"key":"e_1_2_9_13_1","doi-asserted-by":"crossref","unstructured":"H.Sun T.Enomoto T.Yasuda X.Li A. M.Akimoto andR.Yoshida \u201cSelf\u2010Oscillating Coacervates: An Internal Chemical Clock Sustains Membraneless Protocell Populations \u201d (Research Square 2026) https:\/\/doi.org\/10.21203\/rs.3.rs\u20107590335\/v2.","DOI":"10.21203\/rs.3.rs-7590335\/v2"},{"key":"e_1_2_9_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200703953"},{"key":"e_1_2_9_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/j100287a047"},{"key":"e_1_2_9_16_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevE.62.793"},{"key":"e_1_2_9_17_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7SM00563F"},{"key":"e_1_2_9_18_1","doi-asserted-by":"publisher","DOI":"10.3390\/ijms131216281"},{"issue":"5477","key":"e_1_2_9_19_1","doi-asserted-by":"crossref","first-page":"703","DOI":"10.1038\/251703a0","article-title":"Monomolecular Treatment of Chemical Oscillation","volume":"251","author":"K\u00f6r\u00f6s E.","year":"1974","journal-title":"Nature"},{"key":"e_1_2_9_20_1","doi-asserted-by":"publisher","DOI":"10.1246\/bcsj.55.2042"},{"key":"e_1_2_9_21_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.440418"},{"issue":"57","key":"e_1_2_9_22_1","doi-asserted-by":"crossref","first-page":"30412","DOI":"10.1039\/C4RA03539A","article-title":"The Effect of Temperature on the Dynamics of a Homogeneous Oscillatory System Operated in Batch and Under Flow","volume":"4","author":"Nogueira P. A.","year":"2014","journal-title":"RSC Advances"},{"key":"e_1_2_9_23_1","doi-asserted-by":"publisher","DOI":"10.1039\/b820464k"},{"key":"e_1_2_9_24_1","doi-asserted-by":"publisher","DOI":"10.1016\/0167\u20102789(95)00018\u2010Y"},{"key":"e_1_2_9_25_1","doi-asserted-by":"publisher","DOI":"10.1016\/0009\u20102614(96)00023\u20101"},{"key":"e_1_2_9_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201404757"},{"key":"e_1_2_9_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201511871"},{"key":"e_1_2_9_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.langmuir.5c06076"},{"key":"e_1_2_9_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/la049913n"},{"key":"e_1_2_9_30_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cis.2013.11.001"},{"key":"e_1_2_9_31_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.colsurfa.2016.03.010"},{"key":"e_1_2_9_32_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0032\u20103861(97)10130\u20106"}],"container-title":["Macromolecular Rapid Communications"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/marc.70448","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/marc.70448","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/marc.70448","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,10,2]],"date-time":"2026-10-02T02:54:53Z","timestamp":1790909693000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/marc.70448"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,10,1]]},"references-count":31,"alternative-id":["10.1002\/marc.70448"],"URL":"https:\/\/doi.org\/10.1002\/marc.70448","archive":["Portico"],"relation":{},"ISSN":["1022-1336","1521-3927"],"issn-type":[{"value":"1022-1336","type":"print"},{"value":"1521-3927","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,10,1]]},"assertion":[{"value":"2026-07-16","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-09-28","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-10-01","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e70448"}}