{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,4]],"date-time":"2026-10-04T02:53:31Z","timestamp":1791082411822,"version":"4.1.0"},"reference-count":33,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,10,3]],"date-time":"2026-10-03T00:00:00Z","timestamp":1790985600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,10,3]],"date-time":"2026-10-03T00:00:00Z","timestamp":1790985600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22508188"],"award-info":[{"award-number":["22508188"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004608","name":"Natural Science Foundation of Jiangsu Province","doi-asserted-by":"publisher","award":["BK20240685"],"award-info":[{"award-number":["BK20240685"]}],"id":[{"id":"10.13039\/501100004608","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Macromol. Rapid Commun."],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>Cellulose\u2010based adhesives offer sustainable alternatives to petroleum\u2010derived products but face bottlenecks regarding organic solvent reliance, slow curing efficiency, and moisture sensitivity. Here, a solvent\u2010free, UV\u2010curable cellulosic adhesive (UCA) is developed via a supramolecular\u2013covalent hybrid strategy. Utilizing a cellulose acetate butyrate\/thymol eutectic platform, multi\u2010component functionalization with silane, photoactive acrylic moieties, and fluorinated monomer yields a transparent, photocurable prepolymer. The cured UCA exhibits a lap\u2010shear strength of 6.73\u00a0MPa on PMMA, high optical transparency, and broad temperature tolerance. Synergistic surface hydrophobicity, interfacial coupling, and dense photocrosslinking impart strong water resistance, retaining 5.86\u00a0MPa shear strength after 3\u2010day water immersion and 5.12\u00a0MPa after 1\u00a0h in 100\u00b0C boiling water. The adhesive also withstands strong acids, bases, and organic solvents. This work provides a practical route for engineering high\u2010performance bio\u2010based adhesives.<\/jats:p>","DOI":"10.1002\/marc.70449","type":"journal-article","created":{"date-parts":[[2026,10,4]],"date-time":"2026-10-04T02:20:47Z","timestamp":1791080447000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Solvent\u2010Free, UV\u2010Curable Cellulosic Adhesives Engineered via a Supramolecular Eutectic Platform for Robust Adhesion"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-7564-7832","authenticated-orcid":false,"given":"Ren'ai","family":"Li","sequence":"first","affiliation":[{"name":"Key Laboratory of Biobased Materials Science and Technology Ministry of Education Northeast Forestry University  Harbin People's Republic of China"},{"name":"College of Light Industry and Food Engineering Jiangsu Provincial Key Lab of Sustainable Pulp and Paper Technology and Biomass Materials Nanjing Forestry University  Nanjing People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Anqi","family":"Zhao","sequence":"additional","affiliation":[{"name":"College of Light Industry and Food Engineering Jiangsu Provincial Key Lab of Sustainable Pulp and Paper Technology and Biomass Materials Nanjing Forestry University  Nanjing People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hanyu","family":"Jiang","sequence":"additional","affiliation":[{"name":"College of Light Industry and Food Engineering Jiangsu Provincial Key Lab of Sustainable Pulp and Paper Technology and Biomass Materials Nanjing Forestry University  Nanjing People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lizi","family":"Li","sequence":"additional","affiliation":[{"name":"Zhejiang Yuanrun Electronic Materials Co., Ltd., Zhejiang Kan New Materials Co., Ltd  Suichang People's Republic of 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