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Rapid Commun."],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>Replacing petroleum\u2010derived monomers with bio\u2010based alternatives offers a promising route to reducing the environmental footprint of plastics. However, only a few polymeric materials designed in this way can selectively recover valuable petroleum\u2010derived segments. Herein, we report a novel strategy to construct petroleum\/bio\u2010based hybrid plastics with high tensile strength and chemical recyclability, by cross\u2010linking thioctic acid and aromatic petroleum\u2010derived epoxy monomers through dynamic imine, disulfide, and hydrogen bonds, denoted as TAE. Benefiting from the reversibly cross\u2010linked network, TAE exhibits excellent mechanical properties (Young's modulus of \u223c2.52\u00a0GPa, tensile strength of \u223c82.1\u00a0MPa) and remarkable water stability. TAE was further combined with carbon fibers (CFs) to produce CF\u2010TAE composites with outstanding mechanical performance comparable to commercial CF\u2010epoxy thermoset composites. The dynamic imine bonds can be broken by immersing the TAE plastic sheets in a mixed solvent of a polar organic solvent and acidic solution, enabling the non\u2010destructive recovery of CFs and the petroleum\u2010derived monomer. Meanwhile, the residual bio\u2010based components can be safely discarded without environmental concerns. This work addresses critical challenges in the design of sustainable polymeric materials, providing a promising strategy toward next\u2010generation recyclable plastics and fiber\u2010reinforced composites.<\/jats:p>","DOI":"10.1002\/marc.70451","type":"journal-article","created":{"date-parts":[[2026,10,7]],"date-time":"2026-10-07T12:09:35Z","timestamp":1791374975000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Thioctic Acid\u2010Derived Reversibly Cross\u2010Linked Plastics and Carbon Fiber\u2010Reinforced Polymer Composites With High Mechanical Robustness and Excellent Chemical Recyclability"],"prefix":"10.1002","author":[{"given":"Haoxiang","family":"Sun","sequence":"first","affiliation":[{"name":"State Key Laboratory of Supramolecular Structure and Materials College of Chemistry Jilin University  Changchun People's Republic of 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