{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,24]],"date-time":"2026-10-24T07:38:16Z","timestamp":1792827496281,"version":"4.5.0"},"reference-count":35,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,10,24]],"date-time":"2026-10-24T00:00:00Z","timestamp":1792800000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,10,24]],"date-time":"2026-10-24T00:00:00Z","timestamp":1792800000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Macromol. Rapid Commun."],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>Micro\u2010confinement of a filamentous hydrogel has been obtained in a fluid matrix. Microspheres are prepared emulsifying a one\u2010component luminescent lyotropic liquid crystal gel based on an Ir(III) complex in an immiscible polymeric matrix. The distribution of filaments inside microspheres, as a function of the Ir(III) complex concentration in water, and their degree of entanglement changes the interface and viscoelastic properties. By combining lyotropic liquid crystal gels and emulsions, this study introduces a new soft hybrid system and offers new possibilities of exploring functional water\u2010based liquid crystalline materials.<\/jats:p>","DOI":"10.1002\/marc.70465","type":"journal-article","created":{"date-parts":[[2026,10,24]],"date-time":"2026-10-24T07:15:53Z","timestamp":1792826153000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Micrometric Spherical Confinement of a Luminescent Lyotropic Liquid Crystal Gel"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-5127-7040","authenticated-orcid":false,"given":"Erica","family":"Fuoco","sequence":"first","affiliation":[{"name":"Physics Department University of Calabria  Arcavacata di Rende (CS) Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0007-4194-121X","authenticated-orcid":false,"given":"Lorenza","family":"Spina","sequence":"additional","affiliation":[{"name":"Physics Department University of Calabria  Arcavacata di Rende (CS) Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6898-7567","authenticated-orcid":false,"given":"Federica","family":"Ciuchi","sequence":"additional","affiliation":[{"name":"Consiglio Nazionale delle Ricerche \u2010 Istituto di Nanotecnologia CNR\u2010Nanotec Arcavacata di Rende (CS) Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0064-5103","authenticated-orcid":false,"given":"Noemi","family":"Baldino","sequence":"additional","affiliation":[{"name":"Department of Information, Modeling, Electronics and System Engineering, (D.I.M.E.S.) University of Calabria  Arcavacata di Rende (CS) Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Olga","family":"Mileti","sequence":"additional","affiliation":[{"name":"Department of Information, Modeling, Electronics and System Engineering, (D.I.M.E.S.) University of Calabria  Arcavacata di Rende (CS) Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Francesca Romana","family":"Lupi","sequence":"additional","affiliation":[{"name":"Department of Information, Modeling, Electronics and System Engineering, (D.I.M.E.S.) University of Calabria  Arcavacata di Rende (CS) Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4804-2667","authenticated-orcid":false,"given":"Iolinda","family":"Aiello","sequence":"additional","affiliation":[{"name":"Consiglio Nazionale delle Ricerche \u2010 Istituto di Nanotecnologia CNR\u2010Nanotec Arcavacata di Rende (CS) Italy"},{"name":"MAT\u2010InLAB LASCAMM CR\u2010INSTM Unit\u00e0 INSTM della Calabria Dipartimento Di Chimica e Tecnologie Chimiche University of Calabria  Arcavacata di Rende (CS) Italy"},{"name":"LPM\u2011Laboratorio Preparazione Materiali STAR\u2011Lab University of Calabria  Arcavacata di Rende (CS) Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5659-8844","authenticated-orcid":false,"given":"Nicolas","family":"Godbert","sequence":"additional","affiliation":[{"name":"MAT\u2010InLAB LASCAMM CR\u2010INSTM Unit\u00e0 INSTM della Calabria Dipartimento Di Chimica e Tecnologie Chimiche University of Calabria  Arcavacata di Rende (CS) Italy"},{"name":"LPM\u2011Laboratorio Preparazione Materiali STAR\u2011Lab University of Calabria  Arcavacata di Rende (CS) Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9418-4263","authenticated-orcid":false,"given":"Eugenia","family":"Giorno","sequence":"additional","affiliation":[{"name":"MAT\u2010InLAB LASCAMM CR\u2010INSTM Unit\u00e0 INSTM della Calabria Dipartimento Di Chimica e Tecnologie Chimiche University of Calabria  Arcavacata di Rende (CS) Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6556-3611","authenticated-orcid":false,"given":"Maria Penelope","family":"De Santo","sequence":"additional","affiliation":[{"name":"Physics Department University of Calabria  Arcavacata di Rende (CS) Italy"},{"name":"Consiglio Nazionale delle Ricerche \u2010 Istituto di Nanotecnologia CNR\u2010Nanotec Arcavacata di Rende (CS) Italy"},{"name":"Laboratorio Di Preparazione Campioni Biologici \u2013 FISICA STAR\u2011Lab University of Calabria  Arcavacata di Rende (CS) Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,10,24]]},"reference":[{"key":"e_1_2_9_2_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1205962"},{"key":"e_1_2_9_3_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1143826"},{"key":"e_1_2_9_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200300589"},{"key":"e_1_2_9_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.colsurfb.2014.04.004"},{"key":"e_1_2_9_6_1","doi-asserted-by":"crossref","first-page":"E7658","DOI":"10.1073\/pnas.1721369115","article-title":"Backbone\u2010Free Duplex\u2010Stacked Monomer Nucleic Acids Exhibiting Watson\u2013Crick Selectivity","volume":"115","author":"Smith G. P.","year":"2018","journal-title":"PNAS"},{"key":"e_1_2_9_7_1","doi-asserted-by":"publisher","DOI":"10.1039\/b926374h"},{"key":"e_1_2_9_8_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2sm26021b"},{"key":"e_1_2_9_9_1","doi-asserted-by":"publisher","DOI":"10.1039\/b714319b"},{"key":"e_1_2_9_10_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0TC00561D"},{"key":"e_1_2_9_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/cm8006952"},{"key":"e_1_2_9_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr400195e"},{"key":"e_1_2_9_13_1","doi-asserted-by":"publisher","DOI":"10.1146\/annurev\u2010matsci\u2010070115\u2010031557"},{"key":"e_1_2_9_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr9003067"},{"key":"e_1_2_9_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/1521\u20104095(200009)12:17<1237::AID\u2010ADMA1237>3.0.CO;2\u2010B"},{"key":"e_1_2_9_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/1521\u20104095(20020318)14:6<421::AID\u2010ADMA421>3.0.CO;2\u20107"},{"key":"e_1_2_9_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr9700282"},{"key":"e_1_2_9_18_1","doi-asserted-by":"publisher","DOI":"10.1039\/dc9745700007"},{"key":"e_1_2_9_19_1","doi-asserted-by":"publisher","DOI":"10.1039\/b806084c"},{"key":"e_1_2_9_20_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CS00066H"},{"key":"e_1_2_9_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/cm302318b"},{"key":"e_1_2_9_22_1","doi-asserted-by":"publisher","DOI":"10.1039\/b612546h"},{"key":"e_1_2_9_23_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.molliq.2021.116187"},{"key":"e_1_2_9_24_1","doi-asserted-by":"crossref","first-page":"241","DOI":"10.1016\/B978-0-08-102688-5.00122-7","volume-title":"Comprehensive Coordination Chemistry III","author":"Crispini A.","year":"2021"},{"key":"e_1_2_9_25_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3MH02032K"},{"key":"e_1_2_9_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/la8031094"},{"key":"e_1_2_9_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202600013"},{"key":"e_1_2_9_28_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202010394"},{"key":"e_1_2_9_29_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.molliq.2026.129409"},{"key":"e_1_2_9_30_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.2432410"},{"key":"e_1_2_9_31_1","doi-asserted-by":"publisher","DOI":"10.3390\/nano12040619"},{"key":"e_1_2_9_32_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ifset.2025.104013"},{"key":"e_1_2_9_33_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.lwt.2018.03.037"},{"key":"e_1_2_9_34_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.foodhyd.2021.107472"},{"key":"e_1_2_9_35_1","doi-asserted-by":"publisher","DOI":"10.1002\/app.27784"},{"key":"e_1_2_9_36_1","doi-asserted-by":"publisher","DOI":"10.3390\/colloids1010001"}],"container-title":["Macromolecular Rapid Communications"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/marc.70465","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/marc.70465","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/marc.70465","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,10,24]],"date-time":"2026-10-24T07:15:54Z","timestamp":1792826154000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/marc.70465"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,10,24]]},"references-count":35,"alternative-id":["10.1002\/marc.70465"],"URL":"https:\/\/doi.org\/10.1002\/marc.70465","archive":["Portico"],"relation":{},"ISSN":["1022-1336","1521-3927"],"issn-type":[{"value":"1022-1336","type":"print"},{"value":"1521-3927","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,10,24]]},"assertion":[{"value":"2026-07-24","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-10-19","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-10-24","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e70465"}}