{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,8]],"date-time":"2026-09-08T12:37:33Z","timestamp":1788871053499,"version":"build-2803163510"},"reference-count":50,"publisher":"Wiley","issue":"4","license":[{"start":{"date-parts":[[2005,1,27]],"date-time":"2005-01-27T00:00:00Z","timestamp":1106784000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"name":"Ministry of Education, Youth and Sport of the Czech Republic","award":["MSM 143100011."],"award-info":[{"award-number":["MSM 143100011."]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Magnetic Reson in Chemistry"],"published-print":{"date-parts":[[2005,4]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    The higher order high\u2010resolution\n                    <jats:sup>31<\/jats:sup>\n                    P and\n                    <jats:sup>19<\/jats:sup>\n                    F NMR spectra of hexafluorocyclotriphosphazene (F\n                    <jats:sub>2<\/jats:sub>\n                    PN)\n                    <jats:sub>3<\/jats:sub>\n                    were measured at 183 K and interpreted using subspectral analysis and iterative fitting computation. (F\n                    <jats:sub>2<\/jats:sub>\n                    PN)\n                    <jats:sub>3<\/jats:sub>\n                    forms a rigid nine\u2010spin system [A[X]\n                    <jats:sub>2<\/jats:sub>\n                    ]\n                    <jats:sub>3<\/jats:sub>\n                    with\n                    <jats:italic>D<\/jats:italic>\n                    <jats:sub>\n                      3\n                      <jats:italic>h<\/jats:italic>\n                    <\/jats:sub>\n                    symmetry. Two complete and very similar sets of six experimental spin\u2013spin coupling constants,\n                    <jats:sup>1<\/jats:sup>\n                    <jats:italic>J<\/jats:italic>\n                    (P,F),\n                    <jats:sup>2<\/jats:sup>\n                    <jats:italic>J<\/jats:italic>\n                    (P,P),\n                    <jats:sup>2<\/jats:sup>\n                    <jats:italic>J<\/jats:italic>\n                    (F,F),\n                    <jats:sup>3<\/jats:sup>\n                    <jats:italic>J<\/jats:italic>\n                    (P,F),\n                    <jats:sup>4<\/jats:sup>\n                    <jats:italic>J<\/jats:italic>\n                    (F,F)\n                    <jats:sub>\n                      <jats:italic>cis<\/jats:italic>\n                    <\/jats:sub>\n                    and\n                    <jats:sup>4<\/jats:sup>\n                    <jats:italic>J<\/jats:italic>\n                    (F,F)\n                    <jats:sub>\n                      <jats:italic>trans<\/jats:italic>\n                    <\/jats:sub>\n                    , were determined for the first time. Theoretical DFT calculations of chemical shifts and coupling constants were performed to assess their predictive value. The PP\/aug\u2010cc\u2010pVDZ treatment rendered the best agreement with experimental data. Copyright \u00a9 2005 John Wiley &amp; Sons, Ltd.\n                  <\/jats:p>","DOI":"10.1002\/mrc.1549","type":"journal-article","created":{"date-parts":[[2005,1,27]],"date-time":"2005-01-27T07:18:48Z","timestamp":1106810328000},"page":"294-301","source":"Crossref","is-referenced-by-count":16,"title":["Analysis and calculation of the\n                    <sup>31<\/sup>\n                    P and\n                    <sup>19<\/sup>\n                    F NMR spectra of hexafluorocyclotriphosphazene"],"prefix":"10.1002","volume":"43","author":[{"given":"Libor","family":"Kapi\u010dka","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dalibor","family":"Dastych","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Valerie","family":"Richterov\u00e1","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Milan","family":"Alberti","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Pavel","family":"Kub\u00e1\u010dek","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2005,1,27]]},"reference":[{"key":"e_1_2_1_2_2","volume-title":"Phosphorus\u2013Nitrogen Compounds","author":"Allcock HR","year":"1972"},{"key":"e_1_2_1_3_2","doi-asserted-by":"publisher","DOI":"10.1070\/RC1986v055n07ABEH003212"},{"key":"e_1_2_1_4_2","volume-title":"The Chemistry of Inorganic Homo\u2010 and Heterocycles","author":"Allen CW","year":"1987"},{"key":"e_1_2_1_5_2","doi-asserted-by":"publisher","DOI":"10.1002\/aoc.590070102"},{"key":"e_1_2_1_6_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0898-8838(05)52007-5"},{"key":"e_1_2_1_7_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0898-8838(02)53005-1"},{"key":"e_1_2_1_8_2","volume-title":"Chemistry and Applications of Polyphosphazenes","author":"Allcock HR","year":"2003"},{"key":"e_1_2_1_9_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0066-4103(08)60247-1"},{"key":"e_1_2_1_10_2","volume-title":"Simulation und Automatisierte Analyse von Kernresonanzspektren","author":"H\u00e4gele G","year":"1987"},{"key":"e_1_2_1_11_2","doi-asserted-by":"publisher","DOI":"10.1016\/0022-2364(74)90006-7"},{"key":"e_1_2_1_12_2","volume-title":"High Resolution NMR Spectroscopy","author":"Emsley JW","year":"1966"},{"key":"e_1_2_1_13_2","doi-asserted-by":"publisher","DOI":"10.3109\/10837459809028479"},{"key":"e_1_2_1_14_2","doi-asserted-by":"publisher","DOI":"10.1097\/00001813-200010000-00008"},{"key":"e_1_2_1_15_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0378-5173(00)00588-3"},{"key":"e_1_2_1_16_2","doi-asserted-by":"publisher","DOI":"10.1039\/j19700001682"},{"key":"e_1_2_1_17_2","volume-title":"Purification of Laboratory Chemicals","author":"Perrin DD","year":"1988"},{"key":"e_1_2_1_18_2","doi-asserted-by":"publisher","DOI":"10.1002\/9780470132401.ch21"},{"key":"e_1_2_1_19_2","doi-asserted-by":"publisher","DOI":"10.1139\/v65-011"},{"key":"e_1_2_1_20_2","doi-asserted-by":"publisher","DOI":"10.1139\/v65-087"},{"key":"e_1_2_1_21_2","doi-asserted-by":"publisher","DOI":"10.1016\/0079-6565(67)80011-6"},{"key":"e_1_2_1_22_2","doi-asserted-by":"publisher","DOI":"10.1039\/f29817700915"},{"key":"e_1_2_1_23_2","unstructured":"H\u00e4geleG.WIN\u2010DAISY 3.0. 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