{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,28]],"date-time":"2026-07-28T03:17:25Z","timestamp":1785208645160,"version":"3.55.0"},"reference-count":19,"publisher":"Wiley","issue":"6","license":[{"start":{"date-parts":[[2006,3,14]],"date-time":"2006-03-14T00:00:00Z","timestamp":1142294400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Magnetic Reson in Chemistry"],"published-print":{"date-parts":[[2006,5]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>The dependence of the <jats:sup>129<\/jats:sup>Xe NMR chemical shift value of XeF<jats:sub>2<\/jats:sub> on temperature and concentration was determined in a variety of prototypic media: in acidic (anhydrous HF, aHF), nonprotic but polar (dichloromethane), and basic (CD<jats:sub>3<\/jats:sub>CN\u2010EtCN, 1:3 v\/v) solvents. The <jats:sup>129<\/jats:sup>Xe NMR spectra of a representative series of organoxenon(II) salts [RXe][Y] (R = C<jats:sub>6<\/jats:sub>F<jats:sub>5<\/jats:sub>, heptafluoro\u20101,4\u2010cyclohexadien\u20101\u2010yl (<jats:italic>cyclo<\/jats:italic>\u20101,4\u2010C<jats:sub>6<\/jats:sub>F<jats:sub>7<\/jats:sub>), pentafluoro\u20101,4\u2010cyclohexadien\u20103\u2010on\u20101\u2010yl (<jats:italic>cyclo<\/jats:italic>\u20103\u2010O\u20101,4\u2010C<jats:sub>6<\/jats:sub>F<jats:sub>5<\/jats:sub>), CF<jats:sub>2<\/jats:sub> = C(CF<jats:sub>3<\/jats:sub>), (CF<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>CFC\u2261C, C<jats:sub>4<\/jats:sub>H<jats:sub>9<\/jats:sub>C\u2261C; Y = BF<jats:sub>4<\/jats:sub>, AsF<jats:sub>6<\/jats:sub>) in aHF showed, compared with XeF<jats:sub>2<\/jats:sub>\uf8ffaHF, a quantitatively less distinct but qualitatively related dependence of \u03b4(<jats:sup>129<\/jats:sup>Xe) vs temperature. The dependence of their \u03b4(<jats:sup>129<\/jats:sup>Xe) values on concentration in aHF is negligible. An explanation for the different behavior of [RXe][Y] and XeF<jats:sub>2<\/jats:sub> is offered. Copyright \u00a9 2006 John Wiley &amp; Sons, Ltd.<\/jats:p>","DOI":"10.1002\/mrc.1799","type":"journal-article","created":{"date-parts":[[2006,3,14]],"date-time":"2006-03-14T06:46:52Z","timestamp":1142318812000},"page":"648-650","source":"Crossref","is-referenced-by-count":4,"title":["The dependence on temperature and concentration of <sup>129<\/sup>Xe NMR chemical shift values of organoxenon(II) salts [RXe][Y] and of the parent molecule XeF<sub>2<\/sub>"],"prefix":"10.1002","volume":"44","author":[{"given":"Vadim V.","family":"Bardin","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hermann\u2010Josef","family":"Frohn","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2006,3,14]]},"reference":[{"key":"e_1_2_1_2_2","doi-asserted-by":"publisher","DOI":"10.1039\/c39890000047"},{"key":"e_1_2_1_3_2","doi-asserted-by":"publisher","DOI":"10.1039\/C39890000625"},{"key":"e_1_2_1_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/om010490j"},{"key":"e_1_2_1_5_2","first-page":"297","volume-title":"Inorganic Chemistry Highlights","author":"Tyrra W","year":"2002"},{"key":"e_1_2_1_6_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3773(20010417)40:8<1419::AID-ANIE1419>3.0.CO;2-J"},{"key":"e_1_2_1_7_2","doi-asserted-by":"publisher","DOI":"10.1070\/RC2001v070n03ABEH000626"},{"key":"e_1_2_1_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/om050590f"},{"key":"e_1_2_1_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic035394k"},{"key":"e_1_2_1_10_2","first-page":"1","volume-title":"Synthetic Fluorine Chemistry","author":"Schrobilgen GJ","year":"1992"},{"key":"e_1_2_1_11_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0066-4103(08)60007-1"},{"key":"e_1_2_1_12_2","doi-asserted-by":"publisher","DOI":"10.1007\/978-1-4613-1783-8_18"},{"key":"e_1_2_1_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic00187a005"},{"key":"e_1_2_1_14_2","doi-asserted-by":"publisher","DOI":"10.1351\/pac200173111795"},{"key":"e_1_2_1_15_2","doi-asserted-by":"publisher","DOI":"10.1002\/mrc.1260320410"},{"key":"e_1_2_1_16_2","volume-title":"Purification of Laboratory Chemicals","author":"Perrin DD","year":"1980"},{"key":"e_1_2_1_17_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic9801903"},{"key":"e_1_2_1_18_2","doi-asserted-by":"publisher","DOI":"10.1039\/c39930001072"},{"key":"e_1_2_1_19_2","doi-asserted-by":"crossref","first-page":"1011","DOI":"10.1515\/znb-1996-0717","volume":"51","author":"Frohn H\u2010J","year":"1996","journal-title":"Z. 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