{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,4]],"date-time":"2026-04-04T08:20:50Z","timestamp":1775290850352,"version":"3.50.1"},"reference-count":23,"publisher":"Wiley","issue":"2","license":[{"start":{"date-parts":[[2008,11,28]],"date-time":"2008-11-28T00:00:00Z","timestamp":1227830400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Magnetic Reson in Chemistry"],"published-print":{"date-parts":[[2009,2]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>The structure of novel phosphorus\u2010containing <jats:italic>N<\/jats:italic>\u2010vinylazoles prepared by action of phosphorus pentachloride has been studied by multinuclear <jats:sup>1<\/jats:sup>H, <jats:sup>13<\/jats:sup>C, <jats:sup>15<\/jats:sup>N, <jats:sup>31<\/jats:sup>P and two\u2010dimensional (2D) NMR spectroscopy. <jats:italic>N<\/jats:italic>\u2010vinyl\u2010substituted 1,2\u2010diazoles and 1,2,3\u2010triazoles have undergone phosphorylation, exclusively, on double bond. <jats:italic>N<\/jats:italic>\u2010vinylazoles\u2010based hexa\u2010coordinated phosphorus compounds have been synthesized for the first time. <jats:sup>31<\/jats:sup>P NMR spectroscopy provides the most convenient and unambiguous method for the investigation of <jats:italic>E<\/jats:italic>\u2014<jats:italic>Z<\/jats:italic>\u2010isomeric structures of phosphorylated enamines. 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