{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,3,5]],"date-time":"2026-03-05T23:59:42Z","timestamp":1772755182523,"version":"3.50.1"},"reference-count":54,"publisher":"Wiley","issue":"9","license":[{"start":{"date-parts":[[2009,5,28]],"date-time":"2009-05-28T00:00:00Z","timestamp":1243468800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Magnetic Reson in Chemistry"],"published-print":{"date-parts":[[2009,9]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Two series of 2,5\u2010diaryl\u20101,3,4\u2010oxadiazolines have been studied by multinuclear magnetic resonance and density functional theory calculations. A full NMR spectroscopic characterization has been performed and excellent remote Hammett correlations (\u03c3<jats:sub>p<\/jats:sub> or <jats:styled-content>$\\sigma_{\\rm {p}}^{+}$<jats:inline-graphic xmlns:xlink=\"http:\/\/www.w3.org\/1999\/xlink\" xlink:href=\"graphic\/tex2gif-ueqn-1.gif\" xlink:title=\"equation image\"\/><\/jats:styled-content>) have been found for <jats:italic>para<\/jats:italic> substitution in the two aryl rings through at least 11 bonds, notwithstanding the presence in the path of atoms that should act as insulators and a lack of correlation for some of the intermediate atoms. The computational investigation on the electronic delocalization, performed with the ACID (anisotropy of the induced current density) method, reveals indeed that electrons are delocalized in almost the entire molecule despite the presence of the insulators. Copyright \u00a9 2009 John Wiley &amp; Sons, Ltd.<\/jats:p>","DOI":"10.1002\/mrc.2453","type":"journal-article","created":{"date-parts":[[2009,5,28]],"date-time":"2009-05-28T08:46:04Z","timestamp":1243500364000},"page":"727-733","source":"Crossref","is-referenced-by-count":10,"title":["Characterization of 2,5\u2010diaryl\u20101,3,4\u2010oxadiazolines by multinuclear magnetic resonance and density functional theory calculations. Investigation on a case of very remote Hammett correlation"],"prefix":"10.1002","volume":"47","author":[{"given":"Giovanni","family":"Cerioni","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Elias","family":"Maccioni","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Maria Cristina","family":"Cardia","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Sara","family":"Vigo","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Francesca","family":"Mocci","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2009,5,28]]},"reference":[{"key":"e_1_2_1_2_2","doi-asserted-by":"publisher","DOI":"10.1016\/0306-4522(94)90311-5"},{"key":"e_1_2_1_2_3","doi-asserted-by":"publisher","DOI":"10.1007\/BF01245229"},{"key":"e_1_2_1_2_4","doi-asserted-by":"publisher","DOI":"10.1016\/S0924-977X(98)00035-2"},{"key":"e_1_2_1_2_5","first-page":"21","volume":"149","author":"Good P. F.","year":"1996","journal-title":"Am. J. Pathol."},{"key":"e_1_2_1_2_6","doi-asserted-by":"publisher","DOI":"10.2174\/0929867023369411"},{"key":"e_1_2_1_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/jm040903t"},{"key":"e_1_2_1_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr60056a010"},{"key":"e_1_2_1_5_2","doi-asserted-by":"publisher","DOI":"10.1002\/9780470171936.ch1"},{"key":"e_1_2_1_6_2","doi-asserted-by":"publisher","DOI":"10.1002\/mrc.2082"},{"key":"e_1_2_1_7_2","doi-asserted-by":"publisher","DOI":"10.1002\/mrc.1860"},{"key":"e_1_2_1_7_3","doi-asserted-by":"publisher","DOI":"10.1002\/jhet.5570180433"},{"key":"e_1_2_1_7_4","doi-asserted-by":"publisher","DOI":"10.1002\/jhet.5570170815"},{"key":"e_1_2_1_8_2","doi-asserted-by":"publisher","DOI":"10.3987\/COM-99-8615"},{"key":"e_1_2_1_8_3","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1097-458X(1998110)36:11<878::AID-OMR373>3.0.CO;2-2"},{"key":"e_1_2_1_8_4","first-page":"1093","volume":"71","author":"Giurg M.","year":"1997","journal-title":"Pol. J. Chem."},{"key":"e_1_2_1_9_2","first-page":"2545","author":"Fruttero R.","year":"1998","journal-title":"J. Chem. Res. (M)."},{"key":"e_1_2_1_10_2","doi-asserted-by":"publisher","DOI":"10.1002\/mrc.1231"},{"key":"e_1_2_1_11_2","volume-title":"Carbon\u201013 Nuclear Magnetic Resonance Spectroscopy","author":"Levy G. C.","year":"1980"},{"key":"e_1_2_1_12_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.tet.2008.03.061"},{"key":"e_1_2_1_13_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4039(00)99831-9"},{"key":"e_1_2_1_14_2","doi-asserted-by":"publisher","DOI":"10.1002\/mrc.1270110314"},{"key":"e_1_2_1_15_2","doi-asserted-by":"publisher","DOI":"10.1002\/9780470171899.ch1"},{"key":"e_1_2_1_16_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.478522"},{"key":"e_1_2_1_17_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.1480445"},{"key":"e_1_2_1_17_3","doi-asserted-by":"publisher","DOI":"10.1063\/1.474659"},{"key":"e_1_2_1_17_4","doi-asserted-by":"publisher","DOI":"10.1016\/S0009-2614(98)00106-7"},{"key":"e_1_2_1_17_5","doi-asserted-by":"publisher","DOI":"10.1063\/1.473558"},{"key":"e_1_2_1_18_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp0034426"},{"key":"e_1_2_1_18_3","doi-asserted-by":"publisher","DOI":"10.1021\/cr0300901"},{"key":"e_1_2_1_19_2","doi-asserted-by":"publisher","DOI":"10.1002\/1097-458X(200007)38:7<580::AID-MRC657>3.0.CO;2-Q"},{"key":"e_1_2_1_19_3","doi-asserted-by":"publisher","DOI":"10.1006\/jmra.1996.0112"},{"key":"e_1_2_1_20_2","doi-asserted-by":"publisher","DOI":"10.1002\/hlca.19830660522"},{"key":"e_1_2_1_21_2","first-page":"18","volume-title":"Annual Reports on NMR Spectroscopy","author":"Witanowski M.","year":"1986"},{"key":"e_1_2_1_22_2","doi-asserted-by":"publisher","DOI":"10.1039\/p19870000657"},{"key":"e_1_2_1_23_2","first-page":"223","volume-title":"17O NMR Spectroscopy in Organic Chemistry","author":"Boykin D. W.","year":"1991"},{"key":"e_1_2_1_24_2","doi-asserted-by":"publisher","DOI":"10.1002\/mrc.1260330812"},{"key":"e_1_2_1_25_2","first-page":"168","volume-title":"17O NMR Spectroscopy in Organic Chemistry","author":"Chandrasekaran S.","year":"1991"},{"key":"e_1_2_1_25_3","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1097-458X(199702)35:2<107::AID-OMR26>3.0.CO;2-Y"},{"key":"e_1_2_1_26_2","doi-asserted-by":"publisher","DOI":"10.1002\/mrc.1270220112"},{"key":"e_1_2_1_27_2","doi-asserted-by":"publisher","DOI":"10.1002\/hlca.19610440331"},{"key":"e_1_2_1_28_2","doi-asserted-by":"publisher","DOI":"10.1016\/0040-4020(80)80156-6"},{"key":"e_1_2_1_29_2","first-page":"572","volume":"33","author":"Christ H. A.","year":"1960","journal-title":"Helv. Physica Acta"},{"key":"e_1_2_1_30_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-2860(02)00445-3"},{"key":"e_1_2_1_31_2","volume-title":"Gaussian 03, Revision C.02","author":"Frisch M. J.","year":"2004"},{"key":"e_1_2_1_32_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0009-2614(98)01201-9"},{"key":"e_1_2_1_32_3","doi-asserted-by":"publisher","DOI":"10.1002\/mrc.1447"},{"key":"e_1_2_1_33_2","doi-asserted-by":"publisher","DOI":"10.1080\/00268977400100711"},{"key":"e_1_2_1_33_3","doi-asserted-by":"publisher","DOI":"10.1021\/ja00179a005"},{"key":"e_1_2_1_33_4","doi-asserted-by":"publisher","DOI":"10.1063\/1.471789"},{"key":"e_1_2_1_34_2","doi-asserted-by":"publisher","DOI":"10.1016\/0009-2614(92)85733-Q"},{"key":"e_1_2_1_34_3","doi-asserted-by":"publisher","DOI":"10.1063\/1.471789"},{"key":"e_1_2_1_35_2","doi-asserted-by":"publisher","DOI":"10.1016\/0263-7855(96)00018-5"},{"key":"e_1_2_1_36_2","doi-asserted-by":"publisher","DOI":"10.1002\/jhet.5570320543"},{"key":"e_1_2_1_37_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0014-827X(01)01192-2"}],"container-title":["Magnetic Resonance in Chemistry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fmrc.2453","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fmrc.2453","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/analyticalsciencejournals.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/mrc.2453","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,20]],"date-time":"2025-10-20T13:47:04Z","timestamp":1760968024000},"score":1,"resource":{"primary":{"URL":"https:\/\/analyticalsciencejournals.onlinelibrary.wiley.com\/doi\/10.1002\/mrc.2453"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2009,5,28]]},"references-count":54,"journal-issue":{"issue":"9","published-print":{"date-parts":[[2009,9]]}},"alternative-id":["10.1002\/mrc.2453"],"URL":"https:\/\/doi.org\/10.1002\/mrc.2453","archive":["Portico"],"relation":{},"ISSN":["0749-1581","1097-458X"],"issn-type":[{"value":"0749-1581","type":"print"},{"value":"1097-458X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2009,5,28]]}}}