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Host\u2013guest complexes of cryptophane\u2010C with dichloromethane and chloroform in solution were investigated in detail by nuclear magnetic resonance techniques and density functional theory (DFT) calculations. Variable temperature proton and carbon\u201013 spectra show a variety of dynamic processes, such as guest exchange and host conformational transitions. The guest exchange was studied quantitatively by exchange spectroscopy measurements or by line\u2010shape analysis. The conformational preferences of the guest\u2010containing host were interpreted through cross\u2010relaxation measurements, providing evidence of the gauche+2 and gauche\u22122 conformations of the linkers. In addition, the mobility of the chloroform guest inside the cavity was studied by carbon\u201013 relaxation experiments. Combining different types of evidence led to a detailed picture of molecular recognition, interpreted in terms of conformational selection. 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