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Conformational analysis of the compound in solution was performed using dynamic NMR experiments and calculations. The obtained results revealed some differences in the conformational transitions and the energy parameters of the conformational exchange of the studied compound in comparison to previously reported data for other phosphorus\u2010containing pyridoxine derivatives. It was shown that increasing the substituent at the C\u201011 carbon leads to greater differences in the populations of stable states and the corresponding equilibrium energies. 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