{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,21]],"date-time":"2025-10-21T00:32:07Z","timestamp":1761006727926,"version":"build-2065373602"},"reference-count":16,"publisher":"Wiley","issue":"5","license":[{"start":{"date-parts":[[2015,12,21]],"date-time":"2015-12-21T00:00:00Z","timestamp":1450656000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"name":"Research Committee (RC) of Rhodes University"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Magnetic Reson in Chemistry"],"published-print":{"date-parts":[[2016,5]]},"abstract":"Abstract<\/jats:title>Some metal nitrides (TiN, ZrN, InN, GaN, Ca3<\/jats:sub>N2<\/jats:sub>, Mg3<\/jats:sub>N2<\/jats:sub>, and Ge3<\/jats:sub>N4<\/jats:sub>) have been studied by powder X\u2010ray diffraction (XRD) and 14<\/jats:sup>N magic angle\u2010spinning (MAS) solid\u2010state NMR spectroscopy. For Ca3<\/jats:sub>N2<\/jats:sub>, Mg3<\/jats:sub>N2<\/jats:sub>, and Ge3<\/jats:sub>N4<\/jats:sub>, no 14<\/jats:sup>N NMR signal was observed. Low speed (\u03bd<\/jats:italic>r<\/jats:italic><\/jats:sub>\u2009=\u20092\u00a0kHz for TiN, ZrN, and GaN; \u03bd<\/jats:italic>r<\/jats:italic><\/jats:sub>\u2009=\u20091\u00a0kHz for InN) and \u2018high speed\u2019 (\u03bd<\/jats:italic>r<\/jats:italic><\/jats:sub>\u2009=\u200915\u00a0kHz for TiN; \u03bd<\/jats:italic>r<\/jats:italic><\/jats:sub>\u2009=\u20095\u00a0kHz for ZrN; \u03bd<\/jats:italic>r<\/jats:italic><\/jats:sub>\u2009=\u200910\u00a0kHz for InN and GaN) MAS NMR experiments were performed. For TiN, ZrN, InN, and GaN, powder\u2010XRD was used to identify the phases present in each sample. The number of peaks observed for each sample in their 14<\/jats:sup>N MAS solid\u2010state NMR spectrum matches perfectly well with the number of nitrogen\u2010containing phases identified by powder\u2010XRD. The 14<\/jats:sup>N MAS solid\u2010state NMR spectra are symmetric and dominated by the quadrupolar interaction. The envelopes of the spinning sidebands manifold are Lorentzian, and it is concluded that there is a distribution of the quadrupolar coupling constants Qcc<\/jats:sub>'s arising from structural defects in the compounds studied. Copyright \u00a9 2015 John Wiley & Sons, Ltd.<\/jats:p>","DOI":"10.1002\/mrc.4395","type":"journal-article","created":{"date-parts":[[2015,12,21]],"date-time":"2015-12-21T01:35:04Z","timestamp":1450661704000},"page":"371-376","source":"Crossref","is-referenced-by-count":6,"title":["Powder\u2010XRD and 14<\/sup>N magic angle\u2010spinning solid\u2010state NMR spectroscopy of some metal nitrides"],"prefix":"10.1002","volume":"54","author":[{"given":"Pierre","family":"Kempgens","sequence":"first","affiliation":[{"name":"Department of Chemistry Rhodes University Grahamstown 6140 South Africa"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jonathan","family":"Britton","sequence":"additional","affiliation":[{"name":"Department of Chemistry Rhodes University Grahamstown 6140 South Africa"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2015,12,21]]},"reference":[{"volume-title":"Handbook of High\u2010resolution Multinuclear NMR","year":"1981","author":"Brevard C.","key":"e_1_2_7_2_1"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.pnmrs.2011.04.001"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/pssc.200461334"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.67.064416"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja0604865"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.matchemphys.2005.12.031"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11814-009-0020-2"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.455418"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja049603r"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.5012\/bkcs.2003.24.7.1011"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0926-2040(99)00040-5"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.55.5073"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.1746878"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3757(19980504)110:9<1342::AID-ANGE1342>3.0.CO;2-E"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0926-2040(97)00106-9"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0926-2040(02)00016-4"}],"container-title":["Magnetic Resonance in Chemistry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fmrc.4395","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/analyticalsciencejournals.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/mrc.4395","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,20]],"date-time":"2025-10-20T09:54:24Z","timestamp":1760954064000},"score":1,"resource":{"primary":{"URL":"https:\/\/analyticalsciencejournals.onlinelibrary.wiley.com\/doi\/10.1002\/mrc.4395"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2015,12,21]]},"references-count":16,"journal-issue":{"issue":"5","published-print":{"date-parts":[[2016,5]]}},"alternative-id":["10.1002\/mrc.4395"],"URL":"https:\/\/doi.org\/10.1002\/mrc.4395","archive":["Portico"],"relation":{},"ISSN":["0749-1581","1097-458X"],"issn-type":[{"type":"print","value":"0749-1581"},{"type":"electronic","value":"1097-458X"}],"subject":[],"published":{"date-parts":[[2015,12,21]]}}}