{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,21]],"date-time":"2025-10-21T00:32:39Z","timestamp":1761006759597,"version":"build-2065373602"},"reference-count":17,"publisher":"Wiley","issue":"11","license":[{"start":{"date-parts":[[2016,7,24]],"date-time":"2016-07-24T00:00:00Z","timestamp":1469318400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"name":"Alanya Alaaddin Keykubat University"},{"name":"Scientific Research Projects Coordination Centers of Pamukkale, and Selcuk Universities -Turkey"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Magnetic Reson in Chemistry"],"published-print":{"date-parts":[[2016,11]]},"abstract":"<jats:p>1\u2010Pentamethylbenzyl\u20103\u2010ethylimidazoliumsilver(I)bromide and 1,3\u2010bis(pentamethylbenzyl)\u20104,5dimethylbenzimidazoliumsilver(I)bromide and their Ag<jats:sup>+<\/jats:sup> complexes were synthesized and their polycrystal forms were produced by recrystallization in dichloromethane\/Et<jats:sub>2<\/jats:sub>O solvent system. Structural determinations were carried out by <jats:sup>1<\/jats:sup>H NMR and <jats:sup>13<\/jats:sup>C NMR with a Varian 400 NMR system using tetramethylsilane as internal standard and CDCl<jats:sub>3<\/jats:sub> as solvent. The disappearance of acidic N\u2010heterocyclic carbene proton showed the formation of Ag(I) complexes. Also, elemental analyses were carried out. Electron paramagnetic resonance (EPR) measurements were performed to determine the formed radical structure on the samples irradiated at the room temperature for 72\u2009h by using <jats:sup>60<\/jats:sup>Co\u2010source with dose rate of 0.680\u2009kGy. The EPR measurements were carried out in the temperature range of 200\u2009K\u2013450\u2009K. Identical radicals were determined on the irradiated compounds. It was observed that the shapes of the spectra of the samples were independent of the temperature but, the resonance line intensities changed linearly with the temperature. Also, it was detected that the free radical on the 1\u2010pentamethylbenzyl\u20103\u2010ethylimidazoliumsilver(I)bromide is not stable compared to that on the 1,3\u2010bis(pentamethylbenzyl)\u20104,5dimethylbenzimidazoliumsilver(I)bromide. Copyright \u00a9 2016 John Wiley &amp; Sons, Ltd.<\/jats:p>","DOI":"10.1002\/mrc.4479","type":"journal-article","created":{"date-parts":[[2016,7,5]],"date-time":"2016-07-05T11:47:08Z","timestamp":1467719228000},"page":"864-869","source":"Crossref","is-referenced-by-count":3,"title":["Identification of radical structures on 1\u2010pentamethylbenzyl\u20103\u2010ethylimidazoliumsilver(I)bromide and 1,3\u2010bis(pentamethylbenzyl)\u20104,5\u2010dimethylbenzimidazoliumsilver(I)bromide exposed to gamma rays: an EPR study"],"prefix":"10.1002","volume":"54","author":[{"given":"Yusuf","family":"Ceylan","sequence":"first","affiliation":[{"name":"Selcuk University Faculty of Science, Department of Physics  Konya Turkey"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Keziban","family":"Usta","sequence":"additional","affiliation":[{"name":"Alanya Alaaddin Keykubat University Department of Metallurgical and Materials Engineering  Antalya Turkey"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ahmet","family":"Kunduracioglu","sequence":"additional","affiliation":[{"name":"Pamukkale University Vocational College, Department of Chemistry  Denizli Turkey"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ayhan","family":"Usta","sequence":"additional","affiliation":[{"name":"Alanya Alaaddin Keykubat University Department of Mechanical Engineering  Antalya Turkey"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Bekir","family":"Cetinkaya","sequence":"additional","affiliation":[{"name":"Ege University Faculty of Science, Department of Chemistry  Izmir Turkey"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2016,7,24]]},"reference":[{"key":"e_1_2_6_2_1","doi-asserted-by":"publisher","DOI":"10.3390\/met5031553"},{"key":"e_1_2_6_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2006.08.019"},{"key":"e_1_2_6_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.201100430"},{"key":"e_1_2_6_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jinorgbio.2013.09.011"},{"key":"e_1_2_6_6_1","doi-asserted-by":"publisher","DOI":"10.1186\/1752-153X-7-1"},{"key":"e_1_2_6_7_1","doi-asserted-by":"publisher","DOI":"10.1080\/10420150600762250"},{"key":"e_1_2_6_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.molstruc.2012.05.075"},{"key":"e_1_2_6_9_1","doi-asserted-by":"publisher","DOI":"10.1080\/10420150.2011.632635"},{"key":"e_1_2_6_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.molstruc.2015.07.022"},{"key":"e_1_2_6_11_1","doi-asserted-by":"publisher","DOI":"10.12693\/APhysPolA.128.B-479"},{"key":"e_1_2_6_12_1","doi-asserted-by":"publisher","DOI":"10.12693\/APhysPolA.128.B-483"},{"key":"e_1_2_6_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2010.01.002"},{"key":"e_1_2_6_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jmmm.2007.02.143"},{"key":"e_1_2_6_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-3115(99)00075-6"},{"key":"e_1_2_6_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.radphyschem.2012.08.001"},{"key":"e_1_2_6_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jorganchem.2009.03.034"},{"key":"e_1_2_6_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0009-2614(98)01456-0"}],"container-title":["Magnetic Resonance in Chemistry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fmrc.4479","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fmrc.4479","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/analyticalsciencejournals.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/mrc.4479","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,20]],"date-time":"2025-10-20T10:02:50Z","timestamp":1760954570000},"score":1,"resource":{"primary":{"URL":"https:\/\/analyticalsciencejournals.onlinelibrary.wiley.com\/doi\/10.1002\/mrc.4479"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2016,7,24]]},"references-count":17,"journal-issue":{"issue":"11","published-print":{"date-parts":[[2016,11]]}},"alternative-id":["10.1002\/mrc.4479"],"URL":"https:\/\/doi.org\/10.1002\/mrc.4479","archive":["Portico"],"relation":{},"ISSN":["0749-1581","1097-458X"],"issn-type":[{"type":"print","value":"0749-1581"},{"type":"electronic","value":"1097-458X"}],"subject":[],"published":{"date-parts":[[2016,7,24]]}}}