{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,21]],"date-time":"2025-10-21T00:34:28Z","timestamp":1761006868332,"version":"build-2065373602"},"reference-count":37,"publisher":"Wiley","issue":"3","license":[{"start":{"date-parts":[[2021,12,8]],"date-time":"2021-12-08T00:00:00Z","timestamp":1638921600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["analyticalsciencejournals.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Magnetic Reson in Chemistry"],"published-print":{"date-parts":[[2022,3]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>On the basis of the higher order perturbation formulas of <jats:italic>g<\/jats:italic> factors for a 4d<jats:sup>1<\/jats:sup> group in tetragonally compressed octahedra, the <jats:italic>g<\/jats:italic> factors, optical absorption, local structure, and their concentration dependences of pentavalent molybdenum in 40PbO\u2013(10\u2009\u2212\u2009<jats:italic>x<\/jats:italic>)Y<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub>\u201350P<jats:sub>2<\/jats:sub>O<jats:sub>5<\/jats:sub>:<jats:italic>x<\/jats:italic>MoO<jats:sub>3<\/jats:sub> (1\u2009\u2264\u2009<jats:italic>x<\/jats:italic>\u2009\u2264\u20095\u00a0mol%) glass are uniformly investigated. The experimental optical absorption spectra and <jats:italic>g<\/jats:italic> factors for Mo<jats:sup>5+<\/jats:sup> at various concentrations <jats:italic>x<\/jats:italic> are reasonably regenerated by using the reasonable exponential concentration functions of the cubic field parameter <jats:italic>D<\/jats:italic><jats:sub><jats:italic>q<\/jats:italic><\/jats:sub>, covalent factor <jats:italic>N<\/jats:italic>, and relative tetragonal compression ratio <jats:italic>\u03c1<\/jats:italic>. The tetragonal compression ratio <jats:italic>\u03c1<\/jats:italic> due to the Jahn\u2013Teller effect was found in the range of 3.8% to 4.2%. The decreasing trend of <jats:italic>D<\/jats:italic><jats:sub><jats:italic>q<\/jats:italic><\/jats:sub> and <jats:italic>N<\/jats:italic> and the increasing trend of <jats:italic>\u03c1<\/jats:italic> with concentration can be interpreted as the fact that the variations of MoO<jats:sub>3<\/jats:sub> and Y<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub> concentrations lead to the modulations of local structure and electron cloud distribution around Mo<jats:sup>5+<\/jats:sup>, associated with the adjustment of the glass network. The concentration dependence of optical basicity is also analyzed for the above glass systems.<\/jats:p>","DOI":"10.1002\/mrc.5235","type":"journal-article","created":{"date-parts":[[2021,11,25]],"date-time":"2021-11-25T18:35:24Z","timestamp":1637865324000},"page":"407-413","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Theoretical studies on the <i>g<\/i> factors, optical absorption, and their concentration variations for Mo<sup>5+<\/sup> in 40PbO\u2013(10\u2009\u2212\u2009<i>x<\/i>)Y<sub>2<\/sub>O<sub>3<\/sub>\u201350P<sub>2<\/sub>O<sub>5<\/sub>:<i>x<\/i>MoO<sub>3<\/sub> glass"],"prefix":"10.1002","volume":"60","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-7421-1332","authenticated-orcid":false,"given":"Hong\u2010Fei","family":"Zhou","sequence":"first","affiliation":[{"name":"College of Physics and Engineering Technology Chengdu Normal University  Chengdu China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Hui\u2010Ning","family":"Dong","sequence":"additional","affiliation":[{"name":"College of Physics and Engineering Technology Chengdu Normal University  Chengdu China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yi\u2010Ming","family":"Wang","sequence":"additional","affiliation":[{"name":"Department of Applied Physics, School of Physics University of Electronic Science and Technology of China  Chengdu China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2846-5331","authenticated-orcid":false,"given":"Xu\u2010Sheng","family":"Liu","sequence":"additional","affiliation":[{"name":"College of Physics and Engineering Technology Chengdu Normal University  Chengdu China"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2021,12,8]]},"reference":[{"volume-title":"Structural Chemistry of Glasses","year":"2002","author":"Rao K. 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