{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,29]],"date-time":"2026-04-29T12:41:50Z","timestamp":1777466510389,"version":"3.51.4"},"reference-count":41,"publisher":"Wiley","issue":"6","license":[{"start":{"date-parts":[[2023,2,28]],"date-time":"2023-02-28T00:00:00Z","timestamp":1677542400000},"content-version":"am","delay-in-days":358,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#am"},{"start":{"date-parts":[[2022,3,7]],"date-time":"2022-03-07T00:00:00Z","timestamp":1646611200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/100000928","name":"Welch Foundation","doi-asserted-by":"publisher","award":["A\u20100030"],"award-info":[{"award-number":["A\u20100030"]}],"id":[{"id":"10.13039\/100000928","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000015","name":"U.S. Department of Energy","doi-asserted-by":"publisher","award":["DE\u2010SC0017864"],"award-info":[{"award-number":["DE\u2010SC0017864"]}],"id":[{"id":"10.13039\/100000015","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["analyticalsciencejournals.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Magnetic Reson in Chemistry"],"published-print":{"date-parts":[[2022,6]]},"abstract":"Abstract<\/jats:title>\n \n Solid\u2010state NMR experiments on\n 2<\/jats:sup>\n H,\n 31<\/jats:sup>\n P,\n 13<\/jats:sup>\n C, and\n 1<\/jats:sup>\n H nuclei, including\n 31<\/jats:sup>\n P T\n 1<\/jats:sub>\n ,\n 1<\/jats:sup>\n H T\n 1<\/jats:sub>\n , and\n 1<\/jats:sup>\n H T\n 1\u03c1<\/jats:sub>\n measurements, as well as on the kinetics of proton\u2010phosphorus cross\u2010polarization have been performed to characterize the crystalline and amorphous \u03b1\u2010zirconium phosphates, which were intercalated with D\n 2<\/jats:sub>\n O and\/or CD\n 3<\/jats:sub>\n OD. The\n 13<\/jats:sup>\n C{\n 1<\/jats:sup>\n H} CP MAS NMR experiment performed for compound\n 1\u2010CD<\/jats:bold>\n \n 3<\/jats:bold>\n <\/jats:sub>\n OD<\/jats:bold>\n (Zr (HPO\n 4<\/jats:sub>\n )\n 2<\/jats:sub>\n \n .<\/jats:bold>\n <\/jats:sup>\n 0.2CD\n 3<\/jats:sub>\n OD) with carbon cross\u2010polarization via protons of phosphate groups has provided a prove that the methanol was intercalated into the interlayer spaces of this compound. The variable\u2010temperature\n 2<\/jats:sup>\n H solid\u2010echo MAS NMR spectra of intercalated compounds demonstrated that the methanol molecules, in contrast to the mobile water, were immobile, keeping, however, free CD\n 3<\/jats:sub>\n rotations around the C\n 3<\/jats:sub>\n \u2010axis. It has been demonstrated that the intercalated species, D\n 2<\/jats:sub>\n O and CD\n 3<\/jats:sub>\n OD, do not affect the high\u2010frequency motions of the phosphate groups. By utilizing local structural models that satisfy the constraints of the experimental data, it has been suggested that the immobile methanol molecules are located in the cavity between two neighboring layers of the zirconium phosphates. Thus, the present work illustrates the reliable criteria in a comprehensive NMR approach to structural and dynamic studies of such systems.\n <\/jats:p>","DOI":"10.1002\/mrc.5262","type":"journal-article","created":{"date-parts":[[2022,3,1]],"date-time":"2022-03-01T01:15:45Z","timestamp":1646097345000},"page":"541-553","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["Elucidating structure and dynamics of crystalline \u03b1\u2010zirconium phosphates intercalated with water and methanol by multinuclear solid\u2010state MAS NMR: A comprehensive NMR approach"],"prefix":"10.1002","volume":"60","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-5011-0385","authenticated-orcid":false,"given":"Vladimir I.","family":"Bakhmutov","sequence":"first","affiliation":[{"name":"Department of Chemistry Texas A&M University College Station TX USA"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Aida","family":"Contreras\u2010Ramirez","sequence":"additional","affiliation":[{"name":"Department of Chemistry Texas A&M University College Station TX USA"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Hannah","family":"Drake","sequence":"additional","affiliation":[{"name":"Department of Chemistry Texas A&M University College Station TX USA"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Hong\u2010Cai","family":"Zhou","sequence":"additional","affiliation":[{"name":"Department of Chemistry Texas A&M University College Station TX USA"},{"name":"Department of Materials Science and Engineering Texas A&M University College Station TX USA"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2022,3,7]]},"reference":[{"key":"e_1_2_7_2_1","volume-title":"Handbook of layered materials","author":"Nathan H.","year":"2004"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10847-008-9500-y"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/elan.200503432"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2cc16218k"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3nr02206d"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/bm100659p"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.3363\/prb.23.1"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/9781118792223.ch10"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.9b02442"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jnoncrysol.2011.01.023"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/mrc.2492"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/mrc.4568"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201901956"},{"issue":"6","key":"e_1_2_7_15_1","first-page":"1","volume":"427","author":"Fu Y.","year":"2021","journal-title":"Coord. Chem. Rev."},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr100144r"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp044884a"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/mrc.5225"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.3390\/catal7060190"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.3390\/nano10050822"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/i300014a008"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/j100187a053"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr000060n"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1515\/hfsg.1990.44.5.351"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.6b11247"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.6b06417"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1097\/00004424-199111000-00005"},{"key":"e_1_2_7_28_1","first-page":"130","volume-title":"Characterization of proton exchange membrane materials for fuel cells by solid state NMR","author":"Kong X.","year":"2010"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10570-019-02718-0"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.xphs.2018.09.023"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic502473w"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1007\/s12034-007-0036-3"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1039\/b413413n"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1246\/cl.2010.736"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.8b04745"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr00083a007"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1021\/j100286a026"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp9530919"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja962425k"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1039\/b902343g"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1515\/revce-2016-0065"},{"key":"e_1_2_7_42_1","doi-asserted-by":"publisher","DOI":"10.1016\/0167-2738(94)90244-5"}],"container-title":["Magnetic Resonance in Chemistry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/mrc.5262","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/mrc.5262","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/analyticalsciencejournals.onlinelibrary.wiley.com\/doi\/am-pdf\/10.1002\/mrc.5262","content-type":"application\/pdf","content-version":"am","intended-application":"syndication"},{"URL":"https:\/\/analyticalsciencejournals.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/mrc.5262","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,20]],"date-time":"2025-10-20T13:11:00Z","timestamp":1760965860000},"score":1,"resource":{"primary":{"URL":"https:\/\/analyticalsciencejournals.onlinelibrary.wiley.com\/doi\/10.1002\/mrc.5262"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2022,3,7]]},"references-count":41,"journal-issue":{"issue":"6","published-print":{"date-parts":[[2022,6]]}},"alternative-id":["10.1002\/mrc.5262"],"URL":"https:\/\/doi.org\/10.1002\/mrc.5262","archive":["Portico"],"relation":{"has-review":[{"id-type":"doi","id":"10.1002\/MRC.5262\/v3\/response1","asserted-by":"object"},{"id-type":"doi","id":"10.1002\/MRC.5262\/v2\/decision1","asserted-by":"object"},{"id-type":"doi","id":"10.1002\/MRC.5262\/v1\/review1","asserted-by":"object"},{"id-type":"doi","id":"10.1002\/MRC.5262\/v1\/review2","asserted-by":"object"},{"id-type":"doi","id":"10.1002\/MRC.5262\/v2\/review1","asserted-by":"object"},{"id-type":"doi","id":"10.1002\/MRC.5262\/v1\/decision1","asserted-by":"object"},{"id-type":"doi","id":"10.1002\/MRC.5262\/v2\/response1","asserted-by":"object"},{"id-type":"doi","id":"10.1002\/MRC.5262\/v3\/decision1","asserted-by":"object"}]},"ISSN":["0749-1581","1097-458X"],"issn-type":[{"value":"0749-1581","type":"print"},{"value":"1097-458X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2022,3,7]]},"assertion":[{"value":"2021-10-08","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2022-02-24","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2022-03-07","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}