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We used nuclear magnetic resonance (NMR) diffusometry, dynamic light scattering, and conductometry to measure the critical micelle concentration (CMC) of rhamnolipid solutions and determined the effective hydrodynamic radii of rhamnolipid monomers and micelles. Based on selective measurements of the self\u2010diffusion coefficients of molecules, performed by NMR diffusometry, the solubilizing properties of rhamnolipids were studied depending on their concentration in solution; aromatic hydrocarbons, benzene, toluene, ethylbenzene, and para\u2010xylene were taken as solubilizates. On the basis of the measurement results, we estimated the distribution coefficient of the solubilizate between the micellar (solubilized) and free (in the aqueous phase) states and the solubilizing capacity of rhamnolipid micelles.\n                  <\/jats:p>","DOI":"10.1002\/mrc.5337","type":"journal-article","created":{"date-parts":[[2023,2,25]],"date-time":"2023-02-25T06:09:20Z","timestamp":1677305360000},"page":"345-355","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":21,"title":["Micellar and solubilizing properties of rhamnolipids"],"prefix":"10.1002","volume":"61","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-4131-9934","authenticated-orcid":false,"given":"Victor P.","family":"Arkhipov","sequence":"first","affiliation":[{"name":"Department of Physics Kazan National Research Technological University  Kazan 420015 Russian Federation"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ruslan V.","family":"Arkhipov","sequence":"additional","affiliation":[{"name":"Institute of Physics Kazan Federal University  Kazan 420008 Russian Federation"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4273-3443","authenticated-orcid":false,"given":"Ekaterina V.","family":"Petrova","sequence":"additional","affiliation":[{"name":"Department of Analytical Chemistry Kazan National Research Technological University  Kazan 420015 Russian Federation"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6810-1882","authenticated-orcid":false,"given":"Andrei","family":"Filippov","sequence":"additional","affiliation":[{"name":"Chemistry of Interfaces Lule\u00e5 University of Technology  Lule\u00e5 SE\u201097187 Sweden"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2023,3]]},"reference":[{"key":"e_1_2_7_2_1","first-page":"27","volume-title":"Microbial Surfactants","author":"Pardhi D. 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