{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,5,27]],"date-time":"2026-05-27T23:12:49Z","timestamp":1779923569988,"version":"3.53.1"},"reference-count":51,"publisher":"Wiley","issue":"10","license":[{"start":{"date-parts":[[2024,6,30]],"date-time":"2024-06-30T00:00:00Z","timestamp":1719705600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100004479","name":"Natural Science Foundation of Jiangxi Province","doi-asserted-by":"publisher","award":["20212BAB201021"],"award-info":[{"award-number":["20212BAB201021"]}],"id":[{"id":"10.13039\/501100004479","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["analyticalsciencejournals.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Magnetic Reson in Chemistry"],"published-print":{"date-parts":[[2024,10]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    The defect models of the orthorhombical and tetragonal Cu\n                    <jats:sup>2+<\/jats:sup>\n                    centers in Pb[Zr\n                    <jats:sub>0.54<\/jats:sub>\n                    Ti\n                    <jats:sub>0.46<\/jats:sub>\n                    ]O\n                    <jats:sub>3<\/jats:sub>\n                    are attributed to Cu\n                    <jats:sup>2+<\/jats:sup>\n                    ions occupying the sixfold coordinated octahedral Ti\n                    <jats:sup>4+<\/jats:sup>\n                    site with and without charge compensation, respectively. The electron paramagnetic resonance (EPR)\n                    <jats:italic>g<\/jats:italic>\n                    factors\n                    <jats:italic>g<\/jats:italic>\n                    <jats:sub>\n                      <jats:italic>i<\/jats:italic>\n                    <\/jats:sub>\n                    (\n                    <jats:italic>i<\/jats:italic>\n                    \u2009=\u2009\n                    <jats:italic>x<\/jats:italic>\n                    ,\n                    <jats:italic>y<\/jats:italic>\n                    ,\n                    <jats:italic>z<\/jats:italic>\n                    ) of the Cu\n                    <jats:sup>2+<\/jats:sup>\n                    centers in Pb[Zr\n                    <jats:sub>0.54<\/jats:sub>\n                    Ti\n                    <jats:sub>0.46<\/jats:sub>\n                    ]O\n                    <jats:sub>3<\/jats:sub>\n                    are theoretically studied by using the perturbation formulas of a 3d\n                    <jats:sup>9<\/jats:sup>\n                    ion under orthorhombically and tetragonally elongated octahedra. Based on the calculation, the impurity off\u2010center displacements are about 0.253 and 0.162\u2009\u00c5 for the orthorhombical and tetragonal Cu\n                    <jats:sup>2+<\/jats:sup>\n                    centers, respectively. Meanwhile, the planar Cu\n                    <jats:sup>2+<\/jats:sup>\n                    \u2013O\n                    <jats:sup>2\u2212<\/jats:sup>\n                    bonds are found to experience the relative variation \u0394\n                    <jats:italic>R<\/jats:italic>\n                    (\u22480.102\u2009\u00c5) along the\n                    <jats:italic>a<\/jats:italic>\n                    \u2010 and\n                    <jats:italic>b<\/jats:italic>\n                    \u2010axes for the orthorhombical Cu\n                    <jats:sup>2+<\/jats:sup>\n                    center due to the Jahn\u2013Teller (JT) effect. The theoretical EPR\n                    <jats:italic>g<\/jats:italic>\n                    factors based on the above local structures agree well with the observed values.\n                  <\/jats:p>","DOI":"10.1002\/mrc.5472","type":"journal-article","created":{"date-parts":[[2024,7,1]],"date-time":"2024-07-01T00:23:35Z","timestamp":1719793415000},"page":"732-739","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Investigations on the EPR\n                    <i>g<\/i>\n                    factors and local structures for the orthorhombic and tetragonal Cu\n                    <sup>2+<\/sup>\n                    centers in Pb[Zr\n                    <sub>0.54<\/sub>\n                    Ti\n                    <sub>0.46<\/sub>\n                    ]O\n                    <sub>3<\/sub>"],"prefix":"10.1002","volume":"62","author":[{"given":"Xiaohua","family":"Huang","sequence":"first","affiliation":[{"name":"Department of Artificial Intelligence Jiangxi University of Technology  Nanchang Jiangxi China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Meiyun","family":"Zhang","sequence":"additional","affiliation":[{"name":"Department of Artificial Intelligence Jiangxi University of Technology  Nanchang Jiangxi China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fangfang","family":"Guo","sequence":"additional","affiliation":[{"name":"Department of Artificial Intelligence Jiangxi University of Technology  Nanchang Jiangxi China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Houdao","family":"Cai","sequence":"additional","affiliation":[{"name":"Department of Artificial Intelligence Jiangxi University of Technology  Nanchang Jiangxi China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xilin","family":"Zhou","sequence":"additional","affiliation":[{"name":"Department of Artificial Intelligence Jiangxi University of Technology  Nanchang Jiangxi China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0760-3464","authenticated-orcid":false,"given":"Cuidi","family":"Feng","sequence":"additional","affiliation":[{"name":"Jiangxi Province Key Laboratory of Optoelectronic Information Science and Technology Nanchang Hangkong University  Nanchang Jiangxi China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,6,30]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.339293"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.scriptamat.2021.114208"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.4795869"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1109\/23.101181"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ceramint.2019.12.062"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11664-023-10741-y"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.201300462"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3GC01828H"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2022.140230"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/mrc.1664"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jeurceramsoc.2009.04.034"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.54.12353"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.matlet.2005.11.020"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1080\/00150190802014396"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijleo.2012.08.012"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.abf8103"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1088\/0953-8984\/22\/6\/065902"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1007\/s00339-004-3013-3"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1088\/0953-8984\/3\/43\/014"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ceramint.2024.04.124"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.molstruc.2010.05.019"},{"key":"e_1_2_8_23_1","volume-title":"Electron Paramagnetic Resonance of Transition Ions","author":"Abragam A.","year":"1970"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jnoncrysol.2012.10.019"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jallcom.2018.02.209"},{"key":"e_1_2_8_26_1","volume-title":"Introduction to the Magnetic Properties of Solids","author":"Chakravarty A. 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