{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,3,21]],"date-time":"2026-03-21T21:01:57Z","timestamp":1774126917563,"version":"3.50.1"},"reference-count":48,"publisher":"Wiley","issue":"9","license":[{"start":{"date-parts":[[2019,7,2]],"date-time":"2019-07-02T00:00:00Z","timestamp":1562025600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc-nd\/4.0\/"}],"funder":[{"name":"Ministry for Science and Culture of the State of Lower Saxony","award":["DFG GRK1885"],"award-info":[{"award-number":["DFG GRK1885"]}]},{"name":"Ministry for Science and Culture of the State of Lower Saxony","award":["DFG GRK2226"],"award-info":[{"award-number":["DFG GRK2226"]}]},{"name":"Major Research Instrumentation Programme","award":["INST 184\/157-1 FUGG"],"award-info":[{"award-number":["INST 184\/157-1 FUGG"]}]},{"name":"Ministry of Science and Culture"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemistryOpen"],"published-print":{"date-parts":[[2019,9]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Derivatives of 2,5\u2010diaminoterephthalate (DAT) are efficient fluorescence dyes that are also redox\u2010active, thus allowing for the electrochemical manipulation of spectral properties. The electrochemical behaviour of seven DAT derivatives was studied by cyclic voltammetry in dichloromethane. In the absence of a proton donor, DATs should be oxidized in two one\u2010electron steps. The first step is usually quasi\u2010reversible while the second step is either quasi\u2010reversible or irreversible. Some electrochemical properties such as the formal potentials and the ratio between the anodic and the cathodic current were determined from the cyclic voltammograms. Correlation between the formal potential of first oxidation and the absorption or the fluorescence emission wavelengths are established for this specific type of dyes. These correlations were confirmed with density functional theory calculations.<\/jats:p>","DOI":"10.1002\/open.201900138","type":"journal-article","created":{"date-parts":[[2019,7,2]],"date-time":"2019-07-02T03:28:29Z","timestamp":1562038109000},"page":"1176-1182","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Electron Transfer and Electron Excitation Processes in 2,5\u2010Diaminoterephthalate Derivatives with Broad Scope for Functionalization"],"prefix":"10.1002","volume":"8","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-5706-0325","authenticated-orcid":false,"given":"Aleksandra","family":"Markovic","sequence":"first","affiliation":[{"name":"Carl von Ossietzky University Oldenburg School of Mathematics and Science, Chemistry Department  D-26111 Oldenburg Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Leon","family":"Buschbeck","sequence":"additional","affiliation":[{"name":"Carl von Ossietzky University Oldenburg School of Mathematics and Science, Chemistry Department  D-26111 Oldenburg Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1389-6013","authenticated-orcid":false,"given":"Thorsten","family":"Kl\u00fcner","sequence":"additional","affiliation":[{"name":"Carl von Ossietzky University Oldenburg School of Mathematics and Science, Chemistry Department  D-26111 Oldenburg Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1433-6579","authenticated-orcid":false,"given":"Jens","family":"Christoffers","sequence":"additional","affiliation":[{"name":"Carl von Ossietzky University Oldenburg School of Mathematics and Science, Chemistry Department  D-26111 Oldenburg Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6884-5515","authenticated-orcid":false,"given":"Gunther","family":"Wittstock","sequence":"additional","affiliation":[{"name":"Carl von Ossietzky University Oldenburg School of Mathematics and Science, Chemistry Department  D-26111 Oldenburg Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2019,7,2]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/cber.188601901105"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/jo01358a026"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/prac.19793210604"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/jlac.19123930102"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejoc.201701447"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/am501502v"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1055\/s-1998-2097"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja045742x"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2ob26218e"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja506376j"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200805693"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/cbic.201200027"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejoc.201200879"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1007\/978-1-4615-0121-3_5"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1074\/jbc.M603700200"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/prot.21231"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.biochem.6b00005"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1039\/b901970g"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201700774"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejoc.200800054"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1099-0690(200002)2000:3<455::AID-EJOC455>3.0.CO;2-N"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1055\/s-0034-1379963"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/ar970210p"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201402316"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/ar9801301"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.1145"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms2603"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201500494"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1039\/B607709A"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.cgd.7b00986"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6CE00318D"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.coelec.2018.10.007"},{"key":"e_1_2_7_33_1","unstructured":"G. Dryhurst K.\u2005M. Kadish F. Scheller R. Renneberg Biological Electrochemistry Academic Press London 1982."},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.4061\/2011\/816202"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1016\/0022-0728(86)90059-8"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jelechem.2006.09.006"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1021\/ol036108b"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejoc.201101645"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.8b00347"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejoc.201301769"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1021\/jo0482357"},{"key":"e_1_2_7_42_1","unstructured":"L. Buschbeck PhD Thesis Carl von Ossietzky Universit\u00e4t Oldenburg Oldenburg 2018."},{"key":"e_1_2_7_43_1","unstructured":"L. Freimuth PhD Thesis Carl von Ossietzky Universit\u00e4t of Oldenburg Oldenburg 2016."},{"key":"e_1_2_7_44_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.464913"},{"key":"e_1_2_7_45_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.37.785"},{"key":"e_1_2_7_46_1","doi-asserted-by":"publisher","DOI":"10.1139\/p80-159"},{"key":"e_1_2_7_47_1","doi-asserted-by":"publisher","DOI":"10.1021\/j100096a001"},{"key":"e_1_2_7_48_1","author":"Frisch M. J.","year":"2016","journal-title":"Gaussian"}],"container-title":["ChemistryOpen"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fopen.201900138","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/open.201900138","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/open.201900138","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/open.201900138","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,20]],"date-time":"2025-10-20T13:11:17Z","timestamp":1760965877000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/open.201900138"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2019,7,2]]},"references-count":48,"journal-issue":{"issue":"9","published-print":{"date-parts":[[2019,9]]}},"alternative-id":["10.1002\/open.201900138"],"URL":"https:\/\/doi.org\/10.1002\/open.201900138","archive":["Portico"],"relation":{},"ISSN":["2191-1363","2191-1363"],"issn-type":[{"value":"2191-1363","type":"print"},{"value":"2191-1363","type":"electronic"}],"subject":[],"published":{"date-parts":[[2019,7,2]]},"assertion":[{"value":"2019-04-17","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2019-07-02","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}