{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,17]],"date-time":"2026-08-17T14:51:05Z","timestamp":1786978265345,"version":"build-2736575974"},"reference-count":84,"publisher":"Wiley","issue":"11","license":[{"start":{"date-parts":[[2019,11,19]],"date-time":"2019-11-19T00:00:00Z","timestamp":1574121600000},"content-version":"vor","delay-in-days":18,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"publisher","award":["Schm 647\/20-2"],"award-info":[{"award-number":["Schm 647\/20-2"]}],"id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemistryOpen"],"published-print":{"date-parts":[[2019,11]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Remote control in an eight\u2010component network commanded both the synthesis and shuttling of a [2]rotaxane via metal\u2010ion translocation, the latter being easily monitored by distinct colorimetric and fluorimetric signals. Addition of zinc(II) ions to the red colored copper\u2010ion relay station rapidly liberated copper(I) ions and afforded the corresponding zinc complex that was visualized by a bright sky blue fluorescence at 460\u2005nm. In a mixture of all eight components of the network, the liberated copper(I) ions were translocated to a macrocycle that catalyzed formation of a rotaxane by a double\u2010click reaction of acetylenic and diazide compounds. The shuttling frequency in the copper\u2010loaded [2]rotaxane was determined to\n                    <jats:italic>k<\/jats:italic>\n                    <jats:sub>298<\/jats:sub>\n                    =30\u2005kHz (\u0394\n                    <jats:italic>H<\/jats:italic>\n                    <jats:sup>\u2260<\/jats:sup>\n                    =62.3\u00b10.6\u2005kJ\u2009mol\n                    <jats:sup>\u22121<\/jats:sup>\n                    , \u0394\n                    <jats:italic>S<\/jats:italic>\n                    <jats:sup>\u2260<\/jats:sup>\n                    =50.1\u00b15.1\u2005J\u2009mol\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u2009K\n                    <jats:sup>\u22121<\/jats:sup>\n                    , \u0394\n                    <jats:italic>G<\/jats:italic>\n                    <jats:sup>\u2260<\/jats:sup>\n                    <jats:sub>298<\/jats:sub>\n                    =47.4\u2005kJ\u2009mol\n                    <jats:sup>\u22121<\/jats:sup>\n                    ). Removal of zinc(II) ions from the mixture reversed the system back generating the metal\u2010free rotaxane. Further alternate addition and removal of Zn\n                    <jats:sup>2+<\/jats:sup>\n                    reversibly controlled the shuttling mode of the rotaxane in this eight\u2010component network where the ion translocation status was monitored by the naked eye.\n                  <\/jats:p>","DOI":"10.1002\/open.201900293","type":"journal-article","created":{"date-parts":[[2019,11,19]],"date-time":"2019-11-19T14:21:04Z","timestamp":1574173264000},"page":"1355-1360","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":17,"title":["Remote Control of the Synthesis of a [2]Rotaxane and its Shuttling via Metal\u2010Ion Translocation"],"prefix":"10.1002","volume":"8","author":[{"given":"Indrajit","family":"Paul","sequence":"first","affiliation":[{"name":"Center of Micro and Nanochemistry and Engineering, Organische Chemie I Universit\u00e4t Siegen  Adolf-Reichwein-Str. 2 D-57068 Siegen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Amit","family":"Ghosh","sequence":"additional","affiliation":[{"name":"Center of Micro and Nanochemistry and Engineering, Organische Chemie I Universit\u00e4t Siegen  Adolf-Reichwein-Str. 2 D-57068 Siegen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5296-6251","authenticated-orcid":false,"given":"Michael","family":"Bolte","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Anorganische und Analytische Chemie Goethe-Universit\u00e4t Frankfurt  Max-von-Laue-Strasse 7 D-60438 Frankfurt (Main) Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8622-2883","authenticated-orcid":false,"given":"Michael","family":"Schmittel","sequence":"additional","affiliation":[{"name":"Center of Micro and Nanochemistry and Engineering, Organische Chemie I Universit\u00e4t Siegen  Adolf-Reichwein-Str. 2 D-57068 Siegen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2019,11,19]]},"reference":[{"key":"e_1_2_5_1_1","unstructured":"\u00a0"},{"key":"e_1_2_5_2_2","doi-asserted-by":"publisher","DOI":"10.1039\/c4cs00029c"},{"key":"e_1_2_5_3_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201411619"},{"key":"e_1_2_5_3_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201411619"},{"key":"e_1_2_5_4_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41570-017-0061"},{"key":"e_1_2_5_5_2","doi-asserted-by":"publisher","DOI":"10.1039\/C7CS00199A"},{"key":"e_1_2_5_6_2","doi-asserted-by":"publisher","DOI":"10.1039\/C8CS00097B"},{"key":"e_1_2_5_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.7b02523"},{"key":"e_1_2_5_8_1","unstructured":"\u00a0"},{"key":"e_1_2_5_9_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201702531"},{"key":"e_1_2_5_9_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201702531"},{"key":"e_1_2_5_10_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201800638"},{"key":"e_1_2_5_10_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201800638"},{"key":"e_1_2_5_11_1","unstructured":"\u00a0"},{"key":"e_1_2_5_12_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr970049w"},{"key":"e_1_2_5_13_2","doi-asserted-by":"publisher","DOI":"10.1039\/b512178g"},{"key":"e_1_2_5_14_2","doi-asserted-by":"publisher","DOI":"10.1039\/B710908N"},{"key":"e_1_2_5_15_2","doi-asserted-by":"publisher","DOI":"10.1039\/C3CS60178A"},{"key":"e_1_2_5_16_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr5005869"},{"key":"e_1_2_5_17_1","unstructured":"\u00a0"},{"key":"e_1_2_5_18_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3773(20001002)39:19<3348::AID-ANIE3348>3.0.CO;2-X"},{"key":"e_1_2_5_18_3","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3757(20001002)112:19<3484::AID-ANGE3484>3.0.CO;2-O"},{"key":"e_1_2_5_19_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200504313"},{"key":"e_1_2_5_19_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200504313"},{"key":"e_1_2_5_20_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.5b00146"},{"key":"e_1_2_5_21_1","unstructured":"\u00a0"},{"key":"e_1_2_5_22_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00013a096"},{"key":"e_1_2_5_23_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.6b03457"},{"key":"e_1_2_5_24_1","unstructured":"\u00a0"},{"key":"e_1_2_5_25_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja053690l"},{"key":"e_1_2_5_26_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja0663529"},{"key":"e_1_2_5_27_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201612549"},{"key":"e_1_2_5_27_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201612549"},{"key":"e_1_2_5_28_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.7b03996"},{"key":"e_1_2_5_29_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b00941"},{"key":"e_1_2_5_30_1","unstructured":"\u00a0"},{"key":"e_1_2_5_31_2","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.082099199"},{"key":"e_1_2_5_32_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200390085"},{"key":"e_1_2_5_33_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201506474"},{"key":"e_1_2_5_33_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201506474"},{"key":"e_1_2_5_34_1","unstructured":"\u00a0"},{"key":"e_1_2_5_35_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b13016"},{"key":"e_1_2_5_36_2","doi-asserted-by":"publisher","DOI":"10.1002\/cphc.201700387"},{"key":"e_1_2_5_37_2","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.2839"},{"key":"e_1_2_5_38_2","doi-asserted-by":"publisher","DOI":"10.1039\/C9CC00922A"},{"key":"e_1_2_5_39_1","unstructured":"\u00a0"},{"key":"e_1_2_5_40_2","doi-asserted-by":"publisher","DOI":"10.1039\/b922293f"},{"key":"e_1_2_5_41_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr200077m"},{"key":"e_1_2_5_42_1","unstructured":"\u00a0"},{"key":"e_1_2_5_43_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201400804"},{"key":"e_1_2_5_43_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201400804"},{"key":"e_1_2_5_44_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b12951"},{"key":"e_1_2_5_45_2","doi-asserted-by":"publisher","DOI":"10.1039\/C8CC01496E"},{"key":"e_1_2_5_46_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b01182"},{"key":"e_1_2_5_47_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b07737"},{"key":"e_1_2_5_48_1","unstructured":"\u00a0"},{"key":"e_1_2_5_49_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200905947"},{"key":"e_1_2_5_49_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200905947"},{"key":"e_1_2_5_50_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201000276"},{"key":"e_1_2_5_51_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja210113y"},{"key":"e_1_2_5_52_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja411011a"},{"key":"e_1_2_5_53_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja501765y"},{"key":"e_1_2_5_54_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201509108"},{"key":"e_1_2_5_54_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201509108"},{"key":"e_1_2_5_55_2","doi-asserted-by":"publisher","DOI":"10.1039\/C6SC02012G"},{"key":"e_1_2_5_56_2","doi-asserted-by":"publisher","DOI":"10.1039\/C7CC03358C"},{"key":"e_1_2_5_57_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.7b02703"},{"key":"e_1_2_5_58_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201806607"},{"key":"e_1_2_5_58_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201806607"},{"key":"e_1_2_5_59_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b02867"},{"key":"e_1_2_5_60_1","doi-asserted-by":"publisher","DOI":"10.1007\/s00422-015-0652-8"},{"key":"e_1_2_5_61_1","first-page":"28","volume":"94","author":"Breslow R.","year":"2016","journal-title":"Chem. Eng. News"},{"key":"e_1_2_5_62_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic060403l"},{"key":"e_1_2_5_63_1","unstructured":"\u00a0"},{"key":"e_1_2_5_64_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja073513f"},{"key":"e_1_2_5_65_2","doi-asserted-by":"publisher","DOI":"10.1039\/B901974J"},{"key":"e_1_2_5_66_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja0525096"},{"key":"e_1_2_5_67_1","unstructured":"\u00a0"},{"key":"e_1_2_5_68_2","doi-asserted-by":"publisher","DOI":"10.1016\/0010-8545(85)80043-6"},{"key":"e_1_2_5_69_2","doi-asserted-by":"publisher","DOI":"10.1111\/j.1751-1097.1989.tb02900.x"},{"key":"e_1_2_5_70_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja0294663"},{"key":"e_1_2_5_71_1","doi-asserted-by":"publisher","DOI":"10.1021\/ed072p1086.1"},{"key":"e_1_2_5_71_2","unstructured":"Reich H.\u2005J. NMR Spectrum Calculations: WinD NMR Version 7.1.13; Department of Chemistry University of Wisconsin."},{"key":"e_1_2_5_72_1","doi-asserted-by":"publisher","DOI":"10.1002\/ijch.201800124"}],"container-title":["ChemistryOpen"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/open.201900293","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/open.201900293","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/open.201900293","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,20]],"date-time":"2025-10-20T10:36:30Z","timestamp":1760956590000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/open.201900293"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2019,11]]},"references-count":84,"journal-issue":{"issue":"11","published-print":{"date-parts":[[2019,11]]}},"alternative-id":["10.1002\/open.201900293"],"URL":"https:\/\/doi.org\/10.1002\/open.201900293","archive":["Portico"],"relation":{},"ISSN":["2191-1363","2191-1363"],"issn-type":[{"value":"2191-1363","type":"print"},{"value":"2191-1363","type":"electronic"}],"subject":[],"published":{"date-parts":[[2019,11]]},"assertion":[{"value":"2019-09-25","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2019-11-19","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}