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In various solvents the cages behave differently. For instance, in dichloromethane the cage with smallest window size takes up NEt<jats:sub>4<\/jats:sub><jats:sup>+<\/jats:sup> but not NMe<jats:sub>4<\/jats:sub><jats:sup><jats:bold>+<\/jats:bold>,<\/jats:sup> which is in contrast to the two cages with larger windows hosting both ions. To find out the reason for this, kinetic experiments were carried out to determine the velocity of uptake but also to deduce the activation barriers for these processes. To support the experimental results, calculations for the guest uptakes have been performed by molecular mechanics\u2019 simulations. 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