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However, their use is discouraged due to their toxicological profile. Research is ongoing to find alternative more sustainable solvents. This work explores the adoption of\n                    <jats:italic>dl<\/jats:italic>\n                    \u2010limonene as an alternative to BTEX for the industrial preparation of release formulations containing carnauba wax to be employed in the peelable foils industry. A preliminary chemical\u2010physical characterization of carnauba wax was carried out using spectroscopic (ATR\u2010FTIR, NMR) and thermal analyses (DSC). Based on the chemical composition found for the carnauba wax used in the present study, different solvent mixtures and different concentrations of carnauba wax were tested to obtain a clear and stable solution. The most promising formulations were subjected to a coating test on a solid substrate (polyethylene terephthalate, PET) on a laboratory scale, followed by a peeling test to assess the resulting peeling strength. The\n                    <jats:italic>dl<\/jats:italic>\n                    \u2010limonene\/ethyl acetate mixture in the 9\u2009:\u20091 ratio has been identified as the most suitable to completely solubilize carnauba wax (0.38 wt\/vol %) and obtain an adequate release performance. The results of these experiments were then used to set up and successfully perform an industrial\u2010scale coating test.\n                  <\/jats:p>","DOI":"10.1002\/open.202400259","type":"journal-article","created":{"date-parts":[[2024,12,11]],"date-time":"2024-12-11T02:42:00Z","timestamp":1733884920000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["<i>dl<\/i>\n                    \u2010Limonene as an Alternative Sustainable Solvent to Xylenes for the Industrial Preparation of Release Formulations"],"prefix":"10.1002","volume":"14","author":[{"given":"Giuseppe","family":"D'Orazio","sequence":"first","affiliation":[{"name":"Department of Civil, Environmental, Land, Building and Chemical Engineering, DICATECh Polytechnic University of Bari  Via Edoardo Orabona 4 70125 Bari Italy"},{"name":"Department of Chemistry University of Milan  via C. Golgi 19 Milano 20133 Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rosa","family":"Ragone","sequence":"additional","affiliation":[{"name":"Department of Civil, Environmental, Land, Building and Chemical Engineering, DICATECh Polytechnic University of Bari  Via Edoardo Orabona 4 70125 Bari Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Antonino","family":"Rizzuti","sequence":"additional","affiliation":[{"name":"Department of Civil, Environmental, Land, Building and Chemical Engineering, DICATECh Polytechnic University of Bari  Via Edoardo Orabona 4 70125 Bari Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Francesca Serena","family":"Abatematteo","sequence":"additional","affiliation":[{"name":"Department of Civil, Environmental, Land, Building and Chemical Engineering, DICATECh Polytechnic University of Bari  Via Edoardo Orabona 4 70125 Bari Italy"},{"name":"IFOM ETS - The AIRC Institute of Molecular Oncology  via Adamello 16 Milano 20139 Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alessandra","family":"Ciampa","sequence":"additional","affiliation":[{"name":"Department of Civil, Environmental, Land, Building and Chemical Engineering, DICATECh Polytechnic University of Bari  Via Edoardo Orabona 4 70125 Bari Italy"},{"name":"Istituto Poligrafico e Zecca dello Stato  via del Mare 32 Foggia 71121 Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Giuseppe","family":"Ghisa","sequence":"additional","affiliation":[{"name":"Istituto Poligrafico e Zecca dello Stato  via Salaria 691 Roma 00138 Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Michela","family":"Casini","sequence":"additional","affiliation":[{"name":"Istituto Poligrafico e Zecca dello Stato  via Salaria 691 Roma 00138 Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mario","family":"Latronico","sequence":"additional","affiliation":[{"name":"Department of Civil, Environmental, Land, Building and Chemical Engineering, DICATECh Polytechnic University of Bari  Via Edoardo Orabona 4 70125 Bari Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Vito","family":"Gallo","sequence":"additional","affiliation":[{"name":"Department of Civil, Environmental, Land, Building and Chemical Engineering, DICATECh Polytechnic University of Bari  Via Edoardo Orabona 4 70125 Bari Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Piero","family":"Mastrorilli","sequence":"additional","affiliation":[{"name":"Department of Civil, Environmental, Land, Building and Chemical Engineering, DICATECh Polytechnic University of Bari  Via Edoardo Orabona 4 70125 Bari Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0003-6526-9166","authenticated-orcid":false,"given":"Biagia","family":"Musio","sequence":"additional","affiliation":[{"name":"Department of Civil, Environmental, Land, Building and Chemical Engineering, DICATECh Polytechnic University of Bari  Via Edoardo Orabona 4 70125 Bari Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,12,10]]},"reference":[{"key":"e_1_2_9_1_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1GC03662A"},{"key":"e_1_2_9_2_1","doi-asserted-by":"publisher","DOI":"10.1039\/C3GC42302F"},{"key":"e_1_2_9_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cogsc.2018.11.006"},{"key":"e_1_2_9_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/b617536h"},{"key":"e_1_2_9_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/B978-0-12-809270-5.00020-0"},{"key":"e_1_2_9_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/ie060525l"},{"key":"e_1_2_9_7_1","doi-asserted-by":"publisher","DOI":"10.1177\/074823379000600503"},{"key":"e_1_2_9_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/9783527629688.ch3"},{"key":"e_1_2_9_9_1","doi-asserted-by":"publisher","DOI":"10.1162\/jiec.2007.1231"},{"key":"e_1_2_9_10_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6GC00611F"},{"key":"e_1_2_9_11_1","doi-asserted-by":"publisher","DOI":"10.21273\/HORTSCI.50.3.474"},{"key":"e_1_2_9_12_1","doi-asserted-by":"publisher","DOI":"10.1186\/s12866-022-02453-w"},{"key":"e_1_2_9_13_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3gc40967h"},{"key":"e_1_2_9_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.isci.2021.103114"},{"key":"e_1_2_9_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/op4002565"},{"key":"e_1_2_9_16_1","first-page":"1","volume":"4","author":"Byrne F. 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