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Stable target compounds are obtained in good yields as crystalline solids by the combination of [fc(CPh\n                    <jats:sub>2<\/jats:sub>\n                    \uf8ffCH\uf8feNMe)][BF\n                    <jats:sub>4<\/jats:sub>\n                    ] with\n                    <jats:italic>N<\/jats:italic>\n                    ,\n                    <jats:italic>N<\/jats:italic>\n                    \u2032\u2010dimethylimidazolin\u20102\u2010ylidene and of [fc(CPh\n                    <jats:sub>2<\/jats:sub>\n                    \uf8ffCH\uf8feN\u2010\n                    <jats:italic>p<\/jats:italic>\n                    \u2010C\n                    <jats:sub>6<\/jats:sub>\n                    H\n                    <jats:sub>4<\/jats:sub>\n                    \u2010\n                    <jats:italic>t<\/jats:italic>\n                    Bu)](OTf) with 1,3,4,5\u2010tetramethylimidazolin\u20102\u2010ylidene, respectively, followed by treatment of the resulting addition product with KN(SiMe\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    . Due to the presence of a triaminoethene unit and a ferrocene moiety, four redox states are expected for such fcCAAC\u2013NHC heterodimers, viz., electroneutral, mono\u2010, di\u2010, and tricationic. An investigation of their redox behavior by electrochemical methods (cyclic voltammetry and differential pulse voltammetry) has revealed that these compounds undergo two consecutive one\u2010electron oxidations, with the poor stability of the dicationic species in solution preventing an observation of the tricationic redox state. A density functional theory (DFT) study shows that the highest occupied molecular orbital (HOMO) is localized on the\n                    <jats:italic>C<\/jats:italic>\n                    \uf8feCN\n                    <jats:sub>2<\/jats:sub>\n                    atom, which, in agreement with electron paramagnetic resonance\u00a0results, is the site of the first oxidation. The second oxidation mainly involves the Fe atom, where the HOMO\u22121 is localized, resulting in a species with a triplet ground state composed, to a first approximation, of a carbon\u2010centered and an iron\u2010centered radical.\n                  <\/jats:p>","DOI":"10.1002\/open.202500156","type":"journal-article","created":{"date-parts":[[2025,4,14]],"date-time":"2025-04-14T03:36:01Z","timestamp":1744601761000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Triaminoalkenes Derived from Cyclic (Alkyl)(amino)carbenes with a 1,1\u2032\u2010Ferrocenylene Backbone and\n                    <i>N<\/i>\n                    \u2010Heterocyclic Carbenes: fcCAAC\u2013NHC Heterodimers"],"prefix":"10.1002","volume":"14","author":[{"given":"Suman","family":"Yadav","sequence":"first","affiliation":[{"name":"Institute of Chemistry University of Kassel  Heinrich\u2010Plett\u2010Stra\u00dfe 40 34132 Kassel 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