{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,12,6]],"date-time":"2025-12-06T05:25:53Z","timestamp":1764998753768,"version":"3.46.0"},"reference-count":50,"publisher":"Wiley","issue":"12","license":[{"start":{"date-parts":[[2025,9,22]],"date-time":"2025-09-22T00:00:00Z","timestamp":1758499200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100002850","name":"National Fund for Scientific and Technological Development","doi-asserted-by":"publisher","award":["1220763","3220395"],"award-info":[{"award-number":["1220763","3220395"]}],"id":[{"id":"10.13039\/501100002850","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemistryOpen"],"published-print":{"date-parts":[[2025,12]]},"abstract":"<jats:p>\n                    Formic acid is obtained as a byproduct of biomass pyrolysis and is used as a liquid organic hydrogen carrier due to its low decomposition temperature, enabling hydrogen production under mild conditions with noble metals. The decomposition of FA in the vapor phase using different rhenium phases (metal, carbide, and oxide) supported on graphite and carbon nanotubes was studied within a temperature range of 80\u2013220\u2009\u00b0C, in a fixed\u2010bed reactor with a space velocity of 651\u2009mL\u2009g\n                    <jats:sub>cat<\/jats:sub>\n                    \u2009h\n                    <jats:sup>\u22121<\/jats:sup>\n                    . The catalysts were characterized by N\n                    <jats:sub>2<\/jats:sub>\n                    adsorption\u2013desorption, H\n                    <jats:sub>2<\/jats:sub>\n                    \u2010temperature\u2010programmed reduction, transmission electron microscopy, temperature programmed desorption\u2010ammonia, temperature programmed reaction\u2010methanol, X\u2010ray diffraction, and X\u2010ray photoelectron spectroscopy. Graphite\u2010supported catalysts achieved higher activity than carbon nanotube\u2010supported ones, due to the higher rhenium dispersion on graphite. Catalytic reactions revealed that ReC\/G exhibited superior performance at lower temperatures per active site, attributed to the rhenium carbide phase. High selectivity toward CO\n                    <jats:sub>2<\/jats:sub>\n                    was observed across all catalysts, except for ReOx\/G at lower temperatures, where differences in active site characteristics likely influenced performance. ReC\/G displayed the highest intrinsic activity, highlighting rhenium carbide as a more active phase than metallic or oxide rhenium.\n                  <\/jats:p>","DOI":"10.1002\/open.202500412","type":"journal-article","created":{"date-parts":[[2025,9,23]],"date-time":"2025-09-23T06:45:23Z","timestamp":1758609923000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Selective Vapor\u2010Phase Formic Acid Decomposition Over Carbon\u2010Supported Rhenium Catalysts with Metallic, Carbide, and Oxide Rhenium Phases"],"prefix":"10.1002","volume":"14","author":[{"given":"Claudio","family":"Contreras\u2010D\u00edaz","sequence":"first","affiliation":[{"name":"Departamento de Ingenier\u00eda Qu\u00edmica y Bioprocesos Pontificia Universidad Cat\u00f3lica de Chile  Avenida Vicu\u00f1a Mackenna 4860 Macul Santiago Chile"},{"name":"Millennium Nuclei on Catalytic Processes Towards Sustainable Chemistry (CSC)  Santiago 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