{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,3]],"date-time":"2026-09-03T18:01:41Z","timestamp":1788458501342,"version":"build-2803163510"},"reference-count":39,"publisher":"Wiley","issue":"12","license":[{"start":{"date-parts":[[2025,9,9]],"date-time":"2025-09-09T00:00:00Z","timestamp":1757376000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemistryOpen"],"published-print":{"date-parts":[[2025,12]]},"abstract":"<jats:p>\n                    Two series of robust pillared metal\u2013organic frameworks (MOFs) are obtained under solvothermal conditions by combining a metal salt with either\n                    <jats:bold>H<\/jats:bold>\n                    <jats:sub>\n                      <jats:bold>2<\/jats:bold>\n                    <\/jats:sub>\n                    <jats:bold>bpdc<\/jats:bold>\n                    , biphenyl\u20104,4\u2032\u2010dicarboxylic acid, or\n                    <jats:bold>H<\/jats:bold>\n                    <jats:sub>\n                      <jats:bold>2<\/jats:bold>\n                    <\/jats:sub>\n                    <jats:bold>pda<\/jats:bold>\n                    , 1,4\u2010phenylenediacrylic acid, forming 2D layers, which are pillared by\n                    <jats:bold>L<\/jats:bold>\n                    , an alloxazine derivative of 1,4\u2010di(pyridin\u20104\u2010yl)benzene using a one\u2010pot three\u2010component strategy. Crystallographic studies reveal the formation of two isomorphous series of compounds, namely\n                    <jats:bold>1\u2010M<\/jats:bold>\n                    (from\n                    <jats:bold>H<\/jats:bold>\n                    <jats:sub>\n                      <jats:bold>2<\/jats:bold>\n                    <\/jats:sub>\n                    <jats:bold>bpdc<\/jats:bold>\n                    with M\u2009=\u2009Co, Ni, Cu, and Zn) and\n                    <jats:bold>2\u2010M<\/jats:bold>\n                    (from\n                    <jats:bold>H<\/jats:bold>\n                    <jats:sub>\n                      <jats:bold>2<\/jats:bold>\n                    <\/jats:sub>\n                    <jats:bold>pda<\/jats:bold>\n                    with M\u2009=\u2009Co or Cu). The multifunctional compounds have high decomposition temperatures, and their sorption properties were measured, revealing relatively low surface areas. Furthermore,\n                    <jats:bold>1\u2010Zn<\/jats:bold>\n                    displays a moderate uptake of CO\n                    <jats:sub>2<\/jats:sub>\n                    and C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>4<\/jats:sub>\n                    at high pressures\n                    <jats:bold>.<\/jats:bold>\n                    In addition, for\n                    <jats:bold>1\u2010M<\/jats:bold>\n                    (M\u2009=\u2009Co, Cu or Zn), solid\u2010state electrochemistry reveals redox behavior for the MOF, centered on the ligand. This study provides evidence for the first account of a one\u2010pot formation of redox\u2010active pillared MOFs, which exhibit gas sorption abilities before the reduction.\n                  <\/jats:p>","DOI":"10.1002\/open.202500461","type":"journal-article","created":{"date-parts":[[2025,9,10]],"date-time":"2025-09-10T05:27:32Z","timestamp":1757482052000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Series of Microporous Redox\u2010Active Pillared Metal\u2013Organic Frameworks Based On Alloxazine Ligands"],"prefix":"10.1002","volume":"14","author":[{"given":"Jaison","family":"Casas","sequence":"first","affiliation":[{"name":"CMC UMR 7140 CNRS Universit\u00e9 de Strasbourg  Strasbourg F\u201067000 France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alexios I.","family":"Vicatos","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Polymer Science Stellenbosch University  Matieland 7602 South Africa"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Leonard J.","family":"Barbour","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Polymer Science Stellenbosch University  Matieland 7602 South Africa"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nathalie","family":"Kyritsakas","sequence":"additional","affiliation":[{"name":"Service de radiocristallographie de la F\u00e9d\u00e9ration de Chimie Le Bel \u2013 UAR 2042 Universit\u00e9 de Strasbourg and CNRS  Strasbourg F\u201067000 France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Abdelaziz","family":"Jouaiti","sequence":"additional","affiliation":[{"name":"CMC UMR 7140 CNRS Universit\u00e9 de Strasbourg  Strasbourg F\u201067000 France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9707-9514","authenticated-orcid":false,"given":"Sylvie","family":"Ferlay","sequence":"additional","affiliation":[{"name":"CMC UMR 7140 CNRS Universit\u00e9 de Strasbourg  Strasbourg F\u201067000 France"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,9,9]]},"reference":[{"key":"e_1_2_9_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr300014x"},{"key":"e_1_2_9_3_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CS90059F"},{"key":"e_1_2_9_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.0c00836"},{"key":"e_1_2_9_5_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1230444"},{"key":"e_1_2_9_6_1","doi-asserted-by":"publisher","DOI":"10.1039\/b802256a"},{"key":"e_1_2_9_7_1","doi-asserted-by":"publisher","DOI":"10.1039\/C2CS35251F"},{"key":"e_1_2_9_8_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3ee24506c"},{"key":"e_1_2_9_9_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2NA00061J"},{"key":"e_1_2_9_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2019.10.012"},{"key":"e_1_2_9_11_1","doi-asserted-by":"publisher","DOI":"10.1039\/b807080f"},{"key":"e_1_2_9_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.9b00685"},{"key":"e_1_2_9_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr200324t"},{"key":"e_1_2_9_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr200256v"},{"key":"e_1_2_9_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.1c01089"},{"key":"e_1_2_9_16_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-017-02256-y"},{"key":"e_1_2_9_17_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6CC00805D"},{"key":"e_1_2_9_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2021.213891"},{"key":"e_1_2_9_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2024.216004"},{"key":"e_1_2_9_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/ar00127a004"},{"key":"e_1_2_9_21_1","doi-asserted-by":"publisher","DOI":"10.1039\/9781847555397"},{"key":"e_1_2_9_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0010-8545(98)00193-3"},{"key":"e_1_2_9_23_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1QI01131F"},{"key":"e_1_2_9_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.3c04550"},{"key":"e_1_2_9_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3773(19990115)38:1\/2<140::AID-ANIE140>3.0.CO;2-9"},{"key":"e_1_2_9_26_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CS00135D"},{"key":"e_1_2_9_27_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6QI00181E"},{"key":"e_1_2_9_28_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8TA03306D"},{"key":"e_1_2_9_29_1","first-page":"e202218076","volume":"63","author":"Senkovska I.","year":"2023","journal-title":"Angew. 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