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The classical Fricke dosimetry, based on the radiolytic oxidation of Fe\n                    <jats:sup>2+<\/jats:sup>\n                    to Fe\n                    <jats:sup>3+<\/jats:sup>\n                    , may be influenced by TiO\n                    <jats:sub>2<\/jats:sub>\n                    through adsorption, therefore compromising dose accuracy. A recopilation of information on adsorption phenomena from both kinetic and equilibrium perspectives, applying classical and advanced models to characterize the retention of Fe\n                    <jats:sup>2+<\/jats:sup>\n                    and Fe\n                    <jats:sup>3+<\/jats:sup>\n                    on TiO\n                    <jats:sub>2<\/jats:sub>\n                    surfaces, was performed. Particular attention is given to multicomponent systems that reflect the competitive nature of adsorption under Fricke conditions (acidic medium). We discuss how these interactions affect dosimetric responses, potentially leading to the underestimation of the radiation absorbed doses. Although the increasing use of TiO\n                    <jats:sub>2<\/jats:sub>\n                    in radiocatalysis and advanced oxidation processes, standardized protocols for chemical dosimetry in such conditions are still missing. Research gaps include insufficient adsorption mechanistic studies, limited application of multicomponent models, and scarce integration of adsorption parameters into dosimetric assessments. Finally, methodological approaches to enhance dosimetric reliability in the presence of TiO\n                    <jats:sub>2<\/jats:sub>\n                    were proposed, thereby contributing to the development of accurate and reproducible systems for several applications.\n                  <\/jats:p>","DOI":"10.1002\/open.202500524","type":"journal-article","created":{"date-parts":[[2026,3,30]],"date-time":"2026-03-30T06:40:07Z","timestamp":1774852807000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Interference of TiO\n                    <sub>2<\/sub>\n                    in Fricke Dosimetry: Adsorption Mechanisms and Dose Measurement Challenges under Gamma Irradiation"],"prefix":"10.1002","volume":"15","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-8653-7586","authenticated-orcid":false,"given":"William","family":"Villacis","sequence":"first","affiliation":[{"name":"Escuela Polit\u00e9cnica Nacional Facultad de Ingenier\u00eda Qu\u00edmica y Agroindustria Departamento de Ciencias Nucleares Centro de Irradiaci\u00f3n  Quito Ecuador"},{"name":"Facultad de Ingenier\u00eda Departamento de Qu\u00edmica Universidad de Buenos Aires  Buenos Aires Argentina"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Roque","family":"Santos","sequence":"additional","affiliation":[{"name":"Escuela Polit\u00e9cnica Nacional Facultad de Ingenier\u00eda Qu\u00edmica y Agroindustria Departamento de Ciencias Nucleares Centro de Irradiaci\u00f3n  Quito Ecuador"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Mar\u00eda Natalia","family":"Piol","sequence":"additional","affiliation":[{"name":"Facultad de Ingenier\u00eda Departamento de Qu\u00edmica Universidad de Buenos Aires  Buenos Aires Argentina"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Paul","family":"Vargas\u2010Jentzsch","sequence":"additional","affiliation":[{"name":"Escuela Polit\u00e9cnica Nacional Facultad de Ingenier\u00eda Qu\u00edmica y Agroindustria Departamento de Ciencias Nucleares Centro de Irradiaci\u00f3n  Quito Ecuador"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Cristina","family":"V\u00e1zquez","sequence":"additional","affiliation":[{"name":"Facultad de Ingenier\u00eda Departamento de Qu\u00edmica Universidad de Buenos Aires  Buenos Aires Argentina"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2026,3,29]]},"reference":[{"key":"e_1_2_11_2_1","volume-title":"ENCICLOPEDIA DE SALUD Y SEGURIDADEN ELTRABAJO","author":"Cherry R.","year":"1998"},{"issue":"1989","key":"e_1_2_11_3_1","first-page":"1","article-title":"Introducci\u00f3n Definiciones Clasificaci\u00f3n De Las Radiaciones Radiaciones Ionizantes","volume":"4","author":"De la Cerda A.","year":"2009","journal-title":"Revista Digital Para Profesionales De La Ense\u00f1anza"},{"key":"e_1_2_11_4_1","first-page":"1798","article-title":"Tipos De Radiacion, Aplicaciones, Beneficios Y Riesgos","volume":"37","author":"Hoyos M.","year":"2013","journal-title":"Revista De Actualizaci\u00f3n Cl\u00ednica"},{"key":"e_1_2_11_5_1","first-page":"231","article-title":"Cuantificaci\u00f3n De LA Dosis Absorbida Por Medio De Dosimetr\u00eda Termoluminiscente en Radiolog\u00eda Dental","volume":"14","author":"Aquino Ignacio M. 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