{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,3,23]],"date-time":"2026-03-23T08:09:45Z","timestamp":1774253385587,"version":"3.50.1"},"reference-count":29,"publisher":"Wiley","issue":"3","license":[{"start":{"date-parts":[[2026,2,28]],"date-time":"2026-02-28T00:00:00Z","timestamp":1772236800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,2,28]],"date-time":"2026-02-28T00:00:00Z","timestamp":1772236800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001711","name":"Swiss National Science Foundation","doi-asserted-by":"publisher","award":["TMSGI2_226131"],"award-info":[{"award-number":["TMSGI2_226131"]}],"id":[{"id":"10.13039\/501100001711","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemistryOpen"],"published-print":{"date-parts":[[2026,3]]},"abstract":"<jats:p>\n                    Metal\u2013organic frameworks (MOFs) find numerous applications due to their tunable adsorption\/desorption properties. This work is focused on the spectroscopic investigation of the adsorption and release of ethylene (C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>4<\/jats:sub>\n                    ) and 1\u2010methylcyclopropene (1\u2010MCP)\u2014natural plant growth hormone and its synthetic inhibitor\u2014in the pores of Co\n                    <jats:sub>3<\/jats:sub>\n                    (HCOO)\n                    <jats:sub>6<\/jats:sub>\n                    (Co\u2010FA) MOF. Using in situ diffuse reflectance infrared Fourier\u2010transform spectroscopy (DRIFTS), we have identified the molecular\u2010level interactions between the adsorbed molecules and Co\u2010FA pores, as evidenced by the characteristic shifts of the vibrational modes. The significant confinement of 1\u2010MCP in Co\u2010FA at room temperature was demonstrated, while moderate heating enabled its temperature\u2010controlled release. In comparison, weaker but visible ethylene adsorption of C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>4<\/jats:sub>\n                    was also demonstrated, with significant desorption readily occurring at room temperature. Validation tests on bananas confirmed the superior performance of Co\u2010FA over alternative MOFs, providing a link between molecular\u2010level structure and practical applications.\n                  <\/jats:p>","DOI":"10.1002\/open.202500559","type":"journal-article","created":{"date-parts":[[2026,3,8]],"date-time":"2026-03-08T18:03:33Z","timestamp":1772993013000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["In Situ Diffuse Reflectance Infrared Fourier\u2010Transform Spectroscopy Investigation of 1\u2010Methylcyclopropene Adsorption in Cobalt\u2013Formate Metal\u2013Organic Framework"],"prefix":"10.1002","volume":"15","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-0584-2517","authenticated-orcid":false,"given":"Anna Yu.","family":"Pnevskaya","sequence":"first","affiliation":[{"name":"The Smart Materials Research Institute Southern Federal University  Rostov\u2010on\u2010Don Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5102-6743","authenticated-orcid":false,"given":"Andrei A.","family":"Tereshchenko","sequence":"additional","affiliation":[{"name":"The Smart Materials Research Institute Southern Federal University  Rostov\u2010on\u2010Don Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8273-2560","authenticated-orcid":false,"given":"Aram","family":"Bugaev","sequence":"additional","affiliation":[{"name":"Center for Photon Science Paul Scherrer Institut  Villigen Switzerland"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2026,2,28]]},"reference":[{"key":"e_1_2_11_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr300014x"},{"key":"e_1_2_11_3_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1230444"},{"key":"e_1_2_11_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.202400438"},{"key":"e_1_2_11_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cattod.2019.03.054"},{"key":"e_1_2_11_6_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7FD00024C"},{"key":"e_1_2_11_7_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7CP05185A"},{"key":"e_1_2_11_8_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3TC04175A"},{"key":"e_1_2_11_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2024.115516"},{"key":"e_1_2_11_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.202400922"},{"key":"e_1_2_11_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.7b01471"},{"key":"e_1_2_11_12_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1217544"},{"key":"e_1_2_11_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.radphyschem.2019.108430"},{"key":"e_1_2_11_14_1","doi-asserted-by":"publisher","DOI":"10.1088\/1742-6596\/712\/1\/012004"},{"key":"e_1_2_11_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/cmdc.202400144"},{"key":"e_1_2_11_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/slct.202301543"},{"key":"e_1_2_11_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/cnma.202100226"},{"key":"e_1_2_11_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/gch2.202300244"},{"key":"e_1_2_11_19_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11947-025-03805-w"},{"key":"e_1_2_11_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsfoodscitech.4c00354"},{"key":"e_1_2_11_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.1c06503"},{"key":"e_1_2_11_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.rechem.2023.100831"},{"key":"e_1_2_11_23_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.biotechadv.2006.01.005"},{"key":"e_1_2_11_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsmaterialslett.2c00137"},{"key":"e_1_2_11_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic048986r"},{"key":"e_1_2_11_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.200800058"},{"key":"e_1_2_11_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201101733"},{"key":"e_1_2_11_28_1","doi-asserted-by":"publisher","DOI":"10.1039\/C3SC52348A"},{"key":"e_1_2_11_29_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.postharvbio.2017.04.001"},{"key":"e_1_2_11_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.1c06503"}],"container-title":["ChemistryOpen"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/open.202500559","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/open.202500559","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/open.202500559","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,3,23]],"date-time":"2026-03-23T07:31:50Z","timestamp":1774251110000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/open.202500559"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,2,28]]},"references-count":29,"journal-issue":{"issue":"3","published-print":{"date-parts":[[2026,3]]}},"alternative-id":["10.1002\/open.202500559"],"URL":"https:\/\/doi.org\/10.1002\/open.202500559","archive":["Portico"],"relation":{},"ISSN":["2191-1363","2191-1363"],"issn-type":[{"value":"2191-1363","type":"print"},{"value":"2191-1363","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,2,28]]},"assertion":[{"value":"2025-10-21","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication 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