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CuI\u2010catalyzed Ullmann\u2010type cross coupling of aryl halides and thiobenzoic acid is a widely used synthetic method for\n                    <jats:italic>S<\/jats:italic>\n                    \u2010aryl thiocarboxylates. Inspired by two individual methods reported earlier and associated drawbacks, a convenient one\u2010pot two\u2010step CuI\u2010catalyzed procedure for the synthesis of\n                    <jats:italic>S<\/jats:italic>\n                    \u2010(\n                    <jats:italic>N<\/jats:italic>\n                    \u2010heteroaryl) thiocarboxylates from\n                    <jats:italic>N<\/jats:italic>\n                    \u2010heteroaryl bromides and thiobenzoic acid was developed by combining of the two reaction systems and subsequent systematic optimization of the reaction conditions. This procedure employed CuI as a transition metal catalyst, a substoichiometric amount of NaI as iodide source and\n                    <jats:italic>N<\/jats:italic>\n                    ,\n                    <jats:italic>N\u2019<\/jats:italic>\n                    \u2010dimethyl\u20101,2\u2010ethanediamine and 1,10\u2010phenanthroline as two ligands sequentially in each step. This one\u2010pot procedure is highlighted by shorter reaction time, less iodide source and scalability compared to the two reported procedures while maintaining comparable overall isolated yields. Its utility was demonstrated by providing an alternative synthetic route to\n                    <jats:bold>25<\/jats:bold>\n                    and\n                    <jats:bold>26<\/jats:bold>\n                    , two dual serotonin\/dopamine receptor modulators, with fewer reaction steps and avoidance of harsh reaction conditions.\n                  <\/jats:p>","DOI":"10.1002\/open.70186","type":"journal-article","created":{"date-parts":[[2026,3,30]],"date-time":"2026-03-30T06:41:31Z","timestamp":1774852891000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["A Convenient One\u2010Pot CuI\u2010Catalyzed Procedure for the Synthesis of\n                    <i>S<\/i>\n                    \u2010(\n                    <i>N<\/i>\n                    \u2010Heteroaryl) Thiocarboxylates From\n                    <i>N<\/i>\n                    \u2010Heteroaryl Bromides and Thiobenzoic 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