{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,10]],"date-time":"2026-09-10T09:55:28Z","timestamp":1789034128006,"version":"build-2803163510"},"reference-count":54,"publisher":"Wiley","issue":"6","license":[{"start":{"date-parts":[[2026,5,19]],"date-time":"2026-05-19T00:00:00Z","timestamp":1779148800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,5,19]],"date-time":"2026-05-19T00:00:00Z","timestamp":1779148800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/100018227","name":"NRFU","doi-asserted-by":"publisher","award":["2023.03\/0109"],"award-info":[{"award-number":["2023.03\/0109"]}],"id":[{"id":"10.13039\/100018227","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemistryOpen"],"published-print":{"date-parts":[[2026,6]]},"abstract":"<jats:p>\n                    Co\u2010doped (Na\n                    <jats:sup>+<\/jats:sup>\n                    , Mg\n                    <jats:sup>2+<\/jats:sup>\n                    , Zn\n                    <jats:sup>2+<\/jats:sup>\n                    , Fe\n                    <jats:sup>3+<\/jats:sup>\n                    , CO\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>2\u2010<\/jats:sup>\n                    )\u2010calcium phosphates and their composites with 10 or 25 wt% of (Mg\/Zn)Fe\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    were synthesized via a one\u2010step method from aqueous solutions and heated to 600\u00b0C. X\u2010ray powder diffraction (XRD) analysis confirmed the formation of single\u2010phase modified hydroxyapatites and biphasic calcium phosphate composites with a ferrite phase. The composite based on modified biphasic calcium phosphate with 10 wt% of ZnFe\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    exhibited a higher hardness (HV\u2009=\u20093.28\u2009GPa) than the corresponding co\u2010doped (Na\n                    <jats:sup>+<\/jats:sup>\n                    , Mg\n                    <jats:sup>2+<\/jats:sup>\n                    , Zn\n                    <jats:sup>2+<\/jats:sup>\n                    , Fe\n                    <jats:sup>3+<\/jats:sup>\n                    )\u2010hydroxyapatite (HV\u2009=\u20092.49\u2009GPa) and a composite of modified biphasic calcium phosphate with 25 wt% ZnFe\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    (HV\u2009=\u20092.91\u2009GPa). The magnetic properties, studied by the Faraday method, showed that the composite with 25 wt% MgFe\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    possessed a significantly higher magnetic susceptibility (345.9) than its ZnFe\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    counterpart (77.8). Furthermore, an increase in the\n                    <jats:italic>\u03b2<\/jats:italic>\n                    \u2010Ca\n                    <jats:sub>3<\/jats:sub>\n                    (PO\n                    <jats:sub>4<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    \u2010based phase in the 25 wt% M\n                    <jats:sup>II<\/jats:sup>\n                    Fe\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    composites was found to enhance the material's activity toward partial dissolution, a key factor in bone engineering. The antibacterial evaluation against\n                    <jats:italic>Staphylococcus aureus<\/jats:italic>\n                    and\n                    <jats:italic>Pseudomonas aeruginosa<\/jats:italic>\n                    demonstrated the functional potential of co\u2010doped (Na\n                    <jats:sup>+<\/jats:sup>\n                    , Mg\n                    <jats:sup>2+<\/jats:sup>\n                    , Zn\n                    <jats:sup>2+<\/jats:sup>\n                    , Fe\n                    <jats:sup>3+<\/jats:sup>\n                    , CO\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>2\u2010<\/jats:sup>\n                    )\u2010hydroxyapatites and composites based on modified biphasic calcium phosphates with 25 wt% M\n                    <jats:sup>II<\/jats:sup>\n                    Fe\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    . These results contribute to the development of safe materials with tailored magnetic, mechanical, and biomedical properties.\n                  <\/jats:p>","DOI":"10.1002\/open.70232","type":"journal-article","created":{"date-parts":[[2026,5,19]],"date-time":"2026-05-19T07:48:14Z","timestamp":1779176894000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Co\u2010Doped (Na\n                    <sup>+<\/sup>\n                    , Mg\n                    <sup>2+<\/sup>\n                    , Zn\n                    <sup>2+<\/sup>\n                    , Fe\n                    <sup>3+<\/sup>\n                    )\u2010Carbonated Hydroxyapatites and Composites with M\n                    <sup>II<\/sup>\n                    Fe\n                    <sub>2<\/sub>\n                    O\n                    <sub>4<\/sub>\n                    : Synthesis, Mechanic, Magnetic, and Antibacterial Properties for Medical Application"],"prefix":"10.1002","volume":"15","author":[{"given":"Yeva","family":"Komashchenko","sequence":"first","affiliation":[{"name":"Chemistry Department Taras Shevchenko National University of Kyiv  Kyiv Ukraine"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Iryna","family":"Grynyuk","sequence":"additional","affiliation":[{"name":"Department of Bioenergy, Bioinformatics and Environmental Biotechnology Igor Sikorsky Kyiv Polytechnic Institute  Kyiv Ukraine"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dmytro","family":"Prokhorenko","sequence":"additional","affiliation":[{"name":"Department of Bioenergy, Bioinformatics and Environmental Biotechnology Igor Sikorsky Kyiv Polytechnic Institute  Kyiv Ukraine"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Serhii","family":"Nedilko","sequence":"additional","affiliation":[{"name":"Physics Department Taras Shevchenko National University of Kyiv  Kyiv 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