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Models describing the prediction of volatility and potential fate of these substances in the environment have become an important tool in the pesticide authorisation procedure at the <jats:styled-content style=\"fixed-case\">EU<\/jats:styled-content> level. The main topic of this research is to assess the rate and extent of volatilisation of ten pesticides after application on field crops.<\/jats:p><\/jats:sec><jats:sec><jats:title>RESULTS<\/jats:title><jats:p>For eight of the ten pesticides, the volatilisation rates modelled with <jats:styled-content style=\"fixed-case\">PEARL<\/jats:styled-content> (Pesticide Emission Assessment at Regional and Local scales) corresponded well to the calculated rates modelled with <jats:styled-content style=\"fixed-case\">ADMS<\/jats:styled-content> (Atmospheric Dispersion Modelling System). For the other pesticides, large differences were found between the models. Formulation might affect the volatilisation potential of pesticides. Increased leaf wetness increased the volatilisation of propyzamide and trifloxystrobin at the end of the field trial. The reliability of pesticide input parameters, in particular the vapour pressure, is discussed.<\/jats:p><\/jats:sec><jats:sec><jats:title>CONCLUSION<\/jats:title><jats:p>Volatilisation of propyzamide, pyrimethanil, chlorothalonil, diflufenican, tolylfluanid, cyprodinil and <jats:italic>E<\/jats:italic>\u2010 and <jats:italic>Z<\/jats:italic>\u2010dimethomorph from crops under realistic environmental conditions can be modelled with the <jats:styled-content style=\"fixed-case\">PEARL<\/jats:styled-content> model, as corroborated against field observations. Suggested improvements to the volatilisation component in <jats:styled-content style=\"fixed-case\">PEARL<\/jats:styled-content> should include formulation attributes and leaf wetness at the time of pesticide application. \u00a9 2015 Society of Chemical Industry<\/jats:p><\/jats:sec>","DOI":"10.1002\/ps.4149","type":"journal-article","created":{"date-parts":[[2015,9,16]],"date-time":"2015-09-16T03:32:12Z","timestamp":1442374332000},"page":"1309-1321","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":26,"title":["Volatilisation of pesticides under field conditions: inverse modelling and pesticide fate models"],"prefix":"10.1002","volume":"72","author":[{"given":"Michael","family":"Houbraken","sequence":"first","affiliation":[{"name":"Laboratory of Crop Protection Chemistry, Faculty of Bioscience Engineering Department of Crop Protection, Ghent University  Ghent Belgium"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Frederik","family":"van den Berg","sequence":"additional","affiliation":[{"name":"Alterra, Wageningen University and Research Centre  6700 AA Wageningen The Netherlands"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Clare M","family":"Butler Ellis","sequence":"additional","affiliation":[{"name":"Silsoe Spray Applications Unit Wrest Park  Silsoe Bedford UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Donald","family":"Dekeyser","sequence":"additional","affiliation":[{"name":"Institute for Agricultural and Fisheries Research (ILVO), Technology and Food Sciences Agricultural Engineering  Merelbeke Belgium"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"David","family":"Nuyttens","sequence":"additional","affiliation":[{"name":"Institute for Agricultural and Fisheries Research (ILVO), Technology and Food Sciences Agricultural Engineering  Merelbeke Belgium"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mieke","family":"De Schampheleire","sequence":"additional","affiliation":[{"name":"Laboratory of Crop Protection Chemistry, Faculty of Bioscience Engineering Department of Crop Protection, Ghent University  Ghent Belgium"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Pieter","family":"Spanoghe","sequence":"additional","affiliation":[{"name":"Laboratory of Crop Protection Chemistry, Faculty of Bioscience Engineering Department of Crop Protection, Ghent University  Ghent Belgium"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2015,10,19]]},"reference":[{"key":"e_1_2_6_2_1","doi-asserted-by":"publisher","DOI":"10.1051\/agro:2001003"},{"key":"e_1_2_6_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.biosystemseng.2010.08.002"},{"key":"e_1_2_6_4_1","doi-asserted-by":"publisher","DOI":"10.1080\/03067319508033138"},{"key":"e_1_2_6_5_1","doi-asserted-by":"publisher","DOI":"10.1023\/A:1005234329622"},{"key":"e_1_2_6_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0045-6535(97)00146-X"},{"issue":"2003","key":"e_1_2_6_7_1","article-title":"Piacenza","volume":"359","author":"Hassink J","year":"2003","journal-title":"Italy, pp."},{"key":"e_1_2_6_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chemosphere.2004.08.011"},{"key":"e_1_2_6_9_1","unstructured":"Pesticides in air: considerations for exposure assessment. 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