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The isotherm shapes according to Giles classification were S\u2010type for alachlor, metolachlor and chlorothalonil, changing to L\u2010type for the latter as the level of soil organic matter increased, and L\u2010type for EPTC and pirimiphos\u2010methyl. The adsorption isotherms fitted the Freundlich equation <jats:italic>x\/m<\/jats:italic>\u2009=\u2009<jats:italic>K<\/jats:italic><jats:sub>f<\/jats:sub><jats:italic>C<\/jats:italic><jats:sub>e<\/jats:sub><jats:sup>1\/<jats:italic>n<\/jats:italic><\/jats:sup>. The <jats:italic>K<\/jats:italic><jats:sub>f<\/jats:sub> values increased with the increase of organic matter content. The amounts of pesticides adsorbed over a range of concentrations of 0.1\u201320\u2009mg\u2005litre<jats:sup>\u22121<\/jats:sup> reached 63.1% for alachlor, 69.2% for metolachlor, 89.3% for EPTC, 98.4% for chlorothalonil and 96.3% for pirimiphos\u2010methyl. The increase of the amounts desorbed with acetone indicated that the sorption of organic compounds onto organic matter occurred principally via weak London\u2010type induction forces, or dispersion forces which are characteristics of the physical adsorption process.<\/jats:p><jats:p>\u00a9 2002 Society of Chemical Industry<\/jats:p>","DOI":"10.1002\/ps.464","type":"journal-article","created":{"date-parts":[[2005,1,22]],"date-time":"2005-01-22T05:26:39Z","timestamp":1106371599000},"page":"352-362","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":46,"title":["Adsorption\u2013desorption studies of alachlor, metolachlor, EPTC, chlorothalonil and pirimiphos\u2010methyl in contrasting soils"],"prefix":"10.1002","volume":"58","author":[{"given":"Georgios","family":"Patakioutas","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Triantafyllos A","family":"Albanis","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2002,2,12]]},"reference":[{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0021-9673(98)00304-5"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/es960244c"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1016\/0045-6535(96)00258-5"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0025-326X(99)00193-9"},{"key":"e_1_2_6_6_2","first-page":"209","article-title":"Pesticide residue levels in soils and crops from 37 States, 1972\u2014National Soils Monitoring Program (IV)","volume":"12","author":"Carey A E","year":"1979","journal-title":"Pesticides Monitoring Journal"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0269-7491(99)00197-9"},{"key":"e_1_2_6_8_2","first-page":"704","article-title":"Pesticide determination in estuarine and marine sediments, using gas chromatography with FTD and MSD","volume":"7","author":"Hela D G","year":"1998","journal-title":"Fresenius Environmental Bulletin"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0045-6535(00)00179-X"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0021-9673(01)89592-3"},{"key":"e_1_2_6_11_2","first-page":"51","volume-title":"Pesticides in the soil environment: processes, impact and modeling","author":"Koskinen W C","year":"1990"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1016\/0048-9697(92)90363-W"},{"key":"e_1_2_6_13_2","series-title":"Environmental chemistry of herbicides","first-page":"21","author":"Rao P S C","year":"1988"},{"key":"e_1_2_6_14_2","volume-title":"The Pesticide Manual","author":"Tomlin C D S","year":"2000"},{"key":"e_1_2_6_15_2","doi-asserted-by":"publisher","DOI":"10.1007\/978-1-4684-7092-5_1"},{"key":"e_1_2_6_16_2","doi-asserted-by":"publisher","DOI":"10.1097\/00010694-198308000-00005"},{"key":"e_1_2_6_17_2","doi-asserted-by":"publisher","DOI":"10.2307\/4040806"},{"key":"e_1_2_6_18_2","doi-asserted-by":"publisher","DOI":"10.1017\/S0043174500062287"},{"key":"e_1_2_6_19_2","unstructured":"VernettiJandFreedV\u200aH Soil behavior of four thiocarbamates Res Prog Rep WWCC Vol89(1963)."},{"key":"e_1_2_6_20_2","doi-asserted-by":"publisher","DOI":"10.1080\/10643389609388486"},{"key":"e_1_2_6_21_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0021-9673(98)00269-6"},{"key":"e_1_2_6_22_2","first-page":"429","volume-title":"Pesticides in the soil environment: processes, impacts and modeling","author":"Madhun V A","year":"1990"},{"key":"e_1_2_6_23_2","doi-asserted-by":"publisher","DOI":"10.2134\/jeq1996.00472425002500060002x"},{"key":"e_1_2_6_24_2","doi-asserted-by":"publisher","DOI":"10.1039\/jr9600003973"},{"key":"e_1_2_6_25_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0045-6535(97)10247-8"},{"key":"e_1_2_6_26_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0045-6535(97)00206-3"},{"key":"e_1_2_6_27_2","doi-asserted-by":"publisher","DOI":"10.1016\/0048-9697(92)90172-O"},{"key":"e_1_2_6_28_2","doi-asserted-by":"publisher","DOI":"10.1021\/j100542a013"},{"key":"e_1_2_6_29_2","doi-asserted-by":"crossref","first-page":"145","DOI":"10.1289\/ehp.8983145","article-title":"Adsorption of organic chemicals in soils","volume":"83","author":"Calvet R","year":"1989","journal-title":"Environ. 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