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These challenges are influenced by the solid\u2010state properties of the active ingredient and this makes the selection of an optimized solid\u2010state form of modern agrochemicals at early development stages very valuable. The increasing awareness of the solid state of agrochemicals is reflected in the importance of polymorphism patent applications, which may enhance the risk of litigations. This review aims to present strategies for the solid\u2010form selection process of agrochemical development candidates. It introduces the different techniques for crystallization and analytics and demonstrates the influence of the solid state on different formulation types. \u00a9 2022 The Authors. <jats:italic>Pest Management Science<\/jats:italic> published by John Wiley &amp; Sons Ltd on behalf of Society of Chemical Industry.<\/jats:p>","DOI":"10.1002\/ps.6919","type":"journal-article","created":{"date-parts":[[2022,4,14]],"date-time":"2022-04-14T04:39:57Z","timestamp":1649911197000},"page":"2746-2758","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":21,"title":["Importance of chemical polymorphism in modern crop protection"],"prefix":"10.1002","volume":"78","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-0124-275X","authenticated-orcid":false,"given":"Britta","family":"Olenik","sequence":"first","affiliation":[{"name":"Bayer AG, Chemical &amp; Pharmaceutical Development, Pharma, Material Science  Wuppertal Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Birgit","family":"Keil","sequence":"additional","affiliation":[{"name":"Bayer AG, Chemical &amp; Pharmaceutical Development, Pharma, Material Science  Wuppertal Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Peter","family":"Jeschke","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Organische Chemie und Makromolekulare Chemie Heinrich\u2010Heine\u2010Universit\u00e4t D\u00fcsseldorf  Duesseldorf Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2022,5,18]]},"reference":[{"key":"e_1_2_9_2_1","first-page":"350","article-title":"On the relationship between crystalline form and composition, I. 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