{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,1]],"date-time":"2026-10-01T10:11:44Z","timestamp":1790849504496,"version":"4.1.0"},"reference-count":43,"publisher":"Wiley","issue":"12","license":[{"start":{"date-parts":[[2025,8,9]],"date-time":"2025-08-09T00:00:00Z","timestamp":1754697600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["scijournals.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Pest Management Science"],"published-print":{"date-parts":[[2025,12]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:sec>\n                    <jats:title>BACKGROUND<\/jats:title>\n                    <jats:p>Extensive use of Kresoxim methyl, its ability to bio\u2010concentrate and its carcinogenic nature makes this strobilurin fungicide a prominent leaching contaminant contributing to ground water pollution. Understanding its sorption kinetics is essential for elucidating the sorption mechanisms occurring in soil and for predicting its transport across various kinds of soil. In the current study, adsorption kinetics of kresoxim methyl onto ten soil samples of different geographical regions (Shivalik hills, Bhabhar and Indo\u2010Gangetic plains) were examined.<\/jats:p>\n                  <\/jats:sec>\n                  <jats:sec>\n                    <jats:title>RESULTS<\/jats:title>\n                    <jats:p>\n                      The adsorption of Kresoxim methyl was maximum (16.096\u2009mg\u2009kg\n                      <jats:sup>\u22121<\/jats:sup>\n                      ) onto soil with high clay + silt content (86.2%) and minimum (13.813\u2009mg\u2009kg\n                      <jats:sup>\u22121<\/jats:sup>\n                      ) onto\u00a0soil with low clay + silt (44.9%). The kinetic data of Kresoxim methyl for all soil samples aligned well with pseudo\u2010first\u2010order (coefficient of determination (\n                      <jats:italic>R<\/jats:italic>\n                      <jats:sup>2<\/jats:sup>\n                      ) ranging from 0.848 to 0.987) and pseudo\u2010second\u2010order kinetic models (\n                      <jats:italic>R<\/jats:italic>\n                      <jats:sup>2<\/jats:sup>\n                      \u2009=\u20091). Mechanistic modelling revealed the applicability of chemisorption\u2010diffusion model for all soils (\n                      <jats:italic>R<\/jats:italic>\n                      <jats:sup>2<\/jats:sup>\n                      \u2009=\u20091).\n                    <\/jats:p>\n                  <\/jats:sec>\n                  <jats:sec>\n                    <jats:title>CONCLUSION<\/jats:title>\n                    <jats:p>Soil properties such as clay + silt compositions, organic matter content and surface complexation of fungicide by exchangeable micronutrient cations can be used to predict the Kresoxim methyl sorption kinetics. This approach can be extended to other pesticides, structurally and physico\u2010chemically analogous to Kresoxim methyl, providing a framework for evaluating their environmental behaviour. Besides the involvement of intra\u2010particle diffusion and chemisorption\u2010diffusion models, the adsorption of Kresoxim methyl was presumably governed by one or more supplementary mechanisms, such as hydrogen bonding. \u00a9 2025 Society of Chemical Industry.<\/jats:p>\n                  <\/jats:sec>","DOI":"10.1002\/ps.70120","type":"journal-article","created":{"date-parts":[[2025,8,9]],"date-time":"2025-08-09T07:24:29Z","timestamp":1754724269000},"page":"8117-8127","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Adsorption of strobilurin fungicide Kresoxim methyl onto diverse Indian soils: kinetic and mechanistic modeling"],"prefix":"10.1002","volume":"81","author":[{"ORCID":"https:\/\/orcid.org\/0009-0002-7120-1080","authenticated-orcid":false,"given":"Shruti","family":"Pathak","sequence":"first","affiliation":[{"name":"Department of Chemistry, College of Basic Sciences and Humanities Govind Ballabh Pant University of Agriculture and Technology  Pantnagar India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Anjana","family":"Srivastava","sequence":"additional","affiliation":[{"name":"Department of Chemistry, College of Basic Sciences and Humanities Govind Ballabh Pant University of Agriculture and Technology  Pantnagar India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5860-5748","authenticated-orcid":false,"given":"Prakash Chandra","family":"Srivastava","sequence":"additional","affiliation":[{"name":"Department of Soil Science, College of Agriculture Govind Ballabh Pant University of Agriculture and Technology  Pantnagar India"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,8,9]]},"reference":[{"key":"e_1_2_10_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.envpol.2020.114666"},{"key":"e_1_2_10_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.scitotenv.2018.10.441"},{"key":"e_1_2_10_4_1","doi-asserted-by":"publisher","DOI":"10.1007\/s00128-020-02803-2"},{"key":"e_1_2_10_5_1","doi-asserted-by":"publisher","DOI":"10.1080\/03601230701316465"},{"key":"e_1_2_10_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/ps.520"},{"key":"e_1_2_10_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/etc.3520"},{"key":"e_1_2_10_8_1","unstructured":"CIBRC Major uses of pesticides registered under the Insecticides Act Central insecticides board & registration committee directorate of plant protection quarantine & storage(1968).https:\/\/ppqs.gov.in\/sites\/default\/files\/2_major_uses_of_pesticidesfungicide.pdf. 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