{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,27]],"date-time":"2026-08-27T02:30:12Z","timestamp":1787797812294,"version":"build-2784847793"},"reference-count":55,"publisher":"Wiley","issue":"12","license":[{"start":{"date-parts":[[2023,8,31]],"date-time":"2023-08-31T00:00:00Z","timestamp":1693440000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100012226","name":"Fundamental Research Funds for the Central Universities","doi-asserted-by":"publisher","award":["2662022YJ015"],"award-info":[{"award-number":["2662022YJ015"]}],"id":[{"id":"10.13039\/501100012226","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["32272579"],"award-info":[{"award-number":["32272579"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["32102261"],"award-info":[{"award-number":["32102261"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["31972302"],"award-info":[{"award-number":["31972302"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["scijournals.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Pest Management Science"],"published-print":{"date-parts":[[2023,12]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:sec>\n                    <jats:title>BACKGROUND<\/jats:title>\n                    <jats:p>Weeds grow aggressively in agricultural fields, leading to reduced crop yields and an inability to meet the growing demand for food. Herbicides are currently the most effective method for weed control. However, the overuse of herbicides has resulted in the evolution of resistance mutants and has caused environmental pollution. Therefore, new technologies are urgently required to address this global challenge.<\/jats:p>\n                  <\/jats:sec>\n                  <jats:sec>\n                    <jats:title>RESULTS<\/jats:title>\n                    <jats:p>\n                      We report a copper\u2010benzene\u20101,4\u2010dicarboxylate metal organic framework (Cu\u2010BDC MOF)\u2010functionalized carboxyl hollow mesoporous silica (HMS\u2010COOH) delivery system for the pH\u2010controlled release of the acetyl\u2010CoA carboxylase (ACCase)\u2010inhibiting herbicide quizalofop\u2010\n                      <jats:italic>p<\/jats:italic>\n                      \u2010ethyl (QE). The delivery system (QE@HMS@Cu\u2010BDC) enabled the efficient control of barnyard grasses that are susceptible and resistant to ACCase\u2010inhibiting herbicides, which showed 93.33% and 88.33% FW control efficacy at 67.5\u2009g\u2009ha\n                      <jats:sup>\u22121<\/jats:sup>\n                      , respectively. With the lowest pH value (3), QE and copper ion were released slowly to total 70.30% and 78.55% levels (respectively) from QE@HMS@Cu\u2010BDC after 89\u2009h. QE@HMS@Cu\u2010BDC showed better absorption, conduction, transportation and ACCase activity inhibition performance than that of QE emulsifiable concentrate (EC) in both susceptible and ACCase\u2010herbicide resistant barnyard grasses. In addition, with the safener effect of carrier HMS@Cu\u2010BDC and the aid of the safener fenchlorazole\u2010ethyl (FE), the application of QE@HMS@Cu\u2010BDC was shown to mitigate the damage caused by QE to rice plants.\n                    <\/jats:p>\n                  <\/jats:sec>\n                  <jats:sec>\n                    <jats:title>CONCLUSION<\/jats:title>\n                    <jats:p>This work found that the new material HMS\u2010COOH@Cu\u2010BDC can be used to mitigate herbicide\u2010induced oxidative stress and improve rice plant safety. Futhermore, the QE@HMS\u2010COOH@Cu\u2010BDC constructed in this research might be used as an efficient nanopesticide formulation for weed controls in paddy rice fields. \u00a9 2023 Society of Chemical Industry.<\/jats:p>\n                  <\/jats:sec>","DOI":"10.1002\/ps.7729","type":"journal-article","created":{"date-parts":[[2023,8,19]],"date-time":"2023-08-19T02:29:06Z","timestamp":1692412146000},"page":"5237-5249","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":19,"title":["A\n                    <scp>pH<\/scp>\n                    \u2010responsive\n                    <scp>MOF<\/scp>\n                    \u2010functionalized hollow mesoporous silica controlled herbicide delivery system exhibits enhanced activity against\n                    <scp>ACCase<\/scp>\n                    \u2010herbicide\u2010resistant weeds"],"prefix":"10.1002","volume":"79","author":[{"given":"Xi\u2010le","family":"Deng","sequence":"first","affiliation":[{"name":"Key Laboratory for Biology and Control of Weeds, Hunan Agricultural Biotechnology Research Institute Hunan Academy of Agricultural Sciences  Changsha China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jia\u2010qing","family":"Li","sequence":"additional","affiliation":[{"name":"The Center of Crop Nanobiotechnology, College of Plant Science and Technology Huazhong Agricultural University  Wuhan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ji\u2010ming","family":"Yi","sequence":"additional","affiliation":[{"name":"College of Plant Protection Hunan Agricultural University  Changsha China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ren\u2010jie","family":"Lian","sequence":"additional","affiliation":[{"name":"The Center of Crop Nanobiotechnology, College of Plant Science and Technology Huazhong 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