{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,6,9]],"date-time":"2026-06-09T19:18:18Z","timestamp":1781032698412,"version":"3.54.1"},"reference-count":22,"publisher":"Wiley","issue":"1","license":[{"start":{"date-parts":[[2025,9,30]],"date-time":"2025-09-30T00:00:00Z","timestamp":1759190400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["analyticalsciencejournals.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Rapid Comm Mass Spectrometry"],"published-print":{"date-parts":[[2026,1]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:sec>\n                    <jats:title>Rationale<\/jats:title>\n                    <jats:p>Cadmium is a highly toxic heavy metal associated with severe environmental and health risks, making its precise quantification in complex matrices critical. Inductively coupled plasma mass spectrometry (ICP\u2013MS) is one of the most powerful tools for trace metal analysis due to its exceptional sensitivity, selectivity, and multielement capability. However, accurate detection often requires effective preconcentration and matrix elimination strategies.<\/jats:p>\n                  <\/jats:sec>\n                  <jats:sec>\n                    <jats:title>Method<\/jats:title>\n                    <jats:p>A liquid\u2013liquid extraction procedure was developed using N,N\u2032\u2010diphenyl sebacoyl dihydroxamic acid (DPSDHA) as a selective complexing ligand for cadmium. The Cd\u2013DPSDHA binary complex formed at pH\u20099.5 was extracted into dichloromethane, effectively preconcentrating cadmium and minimizing matrix interference prior to ICP\u2013MS measurement. The optimized conditions ensured maximum recovery and stability of the analyte, thereby improving detection limits and analytical precision.<\/jats:p>\n                  <\/jats:sec>\n                  <jats:sec>\n                    <jats:title>Result<\/jats:title>\n                    <jats:p>Coupling the DPSDHA extraction with ICP\u2013MS enabled trace\u2010level determination of cadmium with excellent sensitivity and reproducibility. The method exhibited a wide linear dynamic range, low detection limits, and strong resistance to matrix interferences, ensuring accurate quantification in complex samples. Application to water, alloy, environmental, and biological samples yielded accurate results, which were consistent with certified reference values.<\/jats:p>\n                  <\/jats:sec>\n                  <jats:sec>\n                    <jats:title>Conclusions<\/jats:title>\n                    <jats:p>The combination of selective DPSDHA\u2010based extraction with ICP\u2013MS provides a robust, highly sensitive approach for cadmium determination in diverse sample matrices. This methodology enhances detection accuracy by reducing matrix effects, making it well\u2010suited for environmental monitoring, industrial quality control, and biological studies where trace\u2010level cadmium analysis is essential.<\/jats:p>\n                  <\/jats:sec>","DOI":"10.1002\/rcm.10150","type":"journal-article","created":{"date-parts":[[2025,10,1]],"date-time":"2025-10-01T04:54:28Z","timestamp":1759294468000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Ultratrace Determination of Cd (II) in Water, Salt, Environmental, Alloy, and Biological Samples by Liquid\u2013Liquid Extraction Followed by Inductively Coupled Plasma Mass Spectrometry Technique"],"prefix":"10.1002","volume":"40","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-8183-6325","authenticated-orcid":false,"given":"Chandramauly","family":"Sharma","sequence":"first","affiliation":[{"name":"Chemistry Department, M G Science Institute Gujarat University  Ahmedabad Gujarat India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kuldeep","family":"Sharma","sequence":"additional","affiliation":[{"name":"Parul Institute of Applied Sciences and Research Centre Parul University  Ahmedabad Gujarat India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bignesh","family":"Thakur","sequence":"additional","affiliation":[{"name":"Chemistry Department L J School of Applied Sciences, L J University  Ahmedabad Gujarat India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Aniket","family":"Dixit","sequence":"additional","affiliation":[{"name":"Hexicon Laboratory Pvt.Ltd.  Ahmedabad Gujarat India"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,9,30]]},"reference":[{"key":"e_1_2_8_2_1","first-page":"3","volume-title":"Membrane Technologies for Heavy Metal Removal From Water","author":"Jagaba A. H.","year":"2024"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.59324\/ejtas.2024.2(1).48"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.heliyon.2024.e28357"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.envpol.2021.116911"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1080\/27658511.2023.2293239"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.3390\/toxics11100828"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1007\/s42108\u2010024\u201000284\u20101"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.3390\/w15142532"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11356\u2010023\u201030302\u20104"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/tcr.202000153"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.12911\/22998993\/162955"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.heliyon.2024.e40370"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.envres.2024.119440"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41598\u2010024\u201058061\u20103"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1093\/bulcsj\/uoae128"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11696\u2010024\u201003387\u20105"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1080\/03067319.2023.2287123"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1080\/07366299.2023.2211631"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1134\/S1061934823110084"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1134\/S1070428024604072"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.46770\/AS.2018.01.006"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.46770\/AS.2017.03.003"}],"container-title":["Rapid Communications in Mass Spectrometry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/analyticalsciencejournals.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/rcm.10150","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,12,2]],"date-time":"2025-12-02T10:25:46Z","timestamp":1764671146000},"score":1,"resource":{"primary":{"URL":"https:\/\/analyticalsciencejournals.onlinelibrary.wiley.com\/doi\/10.1002\/rcm.10150"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,9,30]]},"references-count":22,"journal-issue":{"issue":"1","published-print":{"date-parts":[[2026,1]]}},"alternative-id":["10.1002\/rcm.10150"],"URL":"https:\/\/doi.org\/10.1002\/rcm.10150","archive":["Portico"],"relation":{"has-review":[{"id-type":"doi","id":"10.1002\/RCM.10150\/v2\/decision1","asserted-by":"object"},{"id-type":"doi","id":"10.1002\/RCM.10150\/v2\/response1","asserted-by":"object"},{"id-type":"doi","id":"10.1002\/RCM.10150\/v3\/decision1","asserted-by":"object"},{"id-type":"doi","id":"10.1002\/RCM.10150\/v3\/response1","asserted-by":"object"},{"id-type":"doi","id":"10.1002\/RCM.10150\/v1\/review2","asserted-by":"object"},{"id-type":"doi","id":"10.1002\/RCM.10150\/v1\/decision1","asserted-by":"object"},{"id-type":"doi","id":"10.1002\/RCM.10150\/v1\/review1","asserted-by":"object"},{"id-type":"doi","id":"10.1002\/RCM.10150\/v1\/review3","asserted-by":"object"}]},"ISSN":["0951-4198","1097-0231"],"issn-type":[{"value":"0951-4198","type":"print"},{"value":"1097-0231","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,9,30]]},"assertion":[{"value":"2025-08-14","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-09-18","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-09-30","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e10150"}}