{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,26]],"date-time":"2025-10-26T16:01:11Z","timestamp":1761494471196,"version":"build-2065373602"},"reference-count":27,"publisher":"Wiley","issue":"15","license":[{"start":{"date-parts":[[2003,6,24]],"date-time":"2003-06-24T00:00:00Z","timestamp":1056412800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Rapid Comm Mass Spectrometry"],"published-print":{"date-parts":[[2003,8,15]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Using a laser ablation\/inert buffer gas ion source coupled with a reflectron time\u2010of\u2010flight mass spectrometer, the gas\u2010phase reactions between the IVA group element ions M\n                    <jats:sup>+<\/jats:sup>\n                    (M\u2009=\u2009Si, Ge, Sn and Pb) and benzene seeded in argon gas were studied. In addition to the association reaction pathway (forming [M(C\n                    <jats:sub>6<\/jats:sub>\n                    H\n                    <jats:sub>6<\/jats:sub>\n                    )\n                    <jats:sub>x<\/jats:sub>\n                    ]\n                    <jats:sup>+<\/jats:sup>\n                    , x\u2009=\u20091, 2, etc.), benzene was dissociated to form complex ions [M(C\n                    <jats:sub>5<\/jats:sub>\n                    H\n                    <jats:sub>5<\/jats:sub>\n                    )]\n                    <jats:sup>+<\/jats:sup>\n                    , [M(C\n                    <jats:sub>7<\/jats:sub>\n                    H\n                    <jats:sub>5<\/jats:sub>\n                    )]\n                    <jats:sup>+<\/jats:sup>\n                    and [M(C\n                    <jats:sub>9<\/jats:sub>\n                    H\n                    <jats:sub>x<\/jats:sub>\n                    )]\n                    <jats:sup>+<\/jats:sup>\n                    (x\u2009=\u20095, 7 and 9), etc. DFT theoretical calculations indicated that, in the association products [M(C\n                    <jats:sub>6<\/jats:sub>\n                    H\n                    <jats:sub>6<\/jats:sub>\n                    )]\n                    <jats:sup>+<\/jats:sup>\n                    , the M atom is close to one carbon atom of benzene, while in most of the dissociation complexes, pentagonal structures (M\/cyclopentadienyl derivatives) were formed, with the M atom situated near the fivefold axis of the five\u2010membered ring. The bond patterns in these complexes are discussed. Copyright \u00a9 2003 John Wiley &amp; Sons, Ltd.\n                  <\/jats:p>","DOI":"10.1002\/rcm.1115","type":"journal-article","created":{"date-parts":[[2003,7,15]],"date-time":"2003-07-15T06:08:49Z","timestamp":1058249329000},"page":"1743-1748","source":"Crossref","is-referenced-by-count":10,"title":["Reactions between M\n                    <sup>+<\/sup>\n                    (M\u2009=\u2009Si, Ge, Sn and Pb) and benzene in the gas phase"],"prefix":"10.1002","volume":"17","author":[{"given":"Xiaopeng","family":"Xing","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Zhixin","family":"Tian","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Hongtao","family":"Liu","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Zichao","family":"Tang","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2003,6,24]]},"reference":[{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr00006a002"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00013a001"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/j100202a007"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1016\/0168-1176(93)03872-J"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/j100010a013"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/j100044a008"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/om9807349"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja0035452"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/bk-1990-0428.ch004"},{"key":"e_1_2_6_11_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic00317a024"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1016\/0009-2614(89)85173-5"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00292a022"},{"key":"e_1_2_6_14_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00309a600"},{"key":"e_1_2_6_15_2","doi-asserted-by":"publisher","DOI":"10.1016\/0009-2614(90)85367-L"},{"key":"e_1_2_6_16_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0009-2614(97)00336-9"},{"key":"e_1_2_6_17_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja970218u"},{"key":"e_1_2_6_18_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.475972"},{"volume-title":"The Chemistry of Ge, Tin and Lead","year":"1975","author":"Rochow EG","key":"e_1_2_6_19_2"},{"key":"e_1_2_6_20_2","doi-asserted-by":"publisher","DOI":"10.1007\/978-1-4899-7170-8"},{"key":"e_1_2_6_21_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.1141536"},{"key":"e_1_2_6_22_2","first-page":"83","volume":"15","author":"Xing XP","year":"2002","journal-title":"Chin. 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