{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,3,9]],"date-time":"2026-03-09T03:04:35Z","timestamp":1773025475087,"version":"3.50.1"},"reference-count":28,"publisher":"Wiley","issue":"18","license":[{"start":{"date-parts":[[2003,8,18]],"date-time":"2003-08-18T00:00:00Z","timestamp":1061164800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"name":"Consejer\u00eda de la Presidencia Junta de Andaluc\u00eda","award":["A59\/02"],"award-info":[{"award-number":["A59\/02"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Rapid Comm Mass Spectrometry"],"published-print":{"date-parts":[[2003,9,30]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    A fast method for the determination of eight organotin compounds (OTs), monobutyltin (MBT), dibutyltin (DBT), tributyltin (TBT), tetrabutyltin (TeBT), monophenyltin (MPhT), diphenyltin (DPhT), triphenyltin (TPhT) and tetraphenyltin (TePhT), in water, sediments and mussels, was developed using low\u2010pressure gas chromatography\/tandem mass spectrometry (LPGC\/MS\/MS). The method is based on sodium diethyldithiocarbamate (DDTC) complexation of the ionic organotins, followed by extraction of the target matrices and derivatization by a Grignard reagent, as described in a previously published method for water samples (S. Tsunoi\n                    <jats:italic>et al.<\/jats:italic>\n                    ,\n                    <jats:italic>J. Chromatogr. A<\/jats:italic>\n                    2002; 962: 197). Solid\u2010phase extraction was selected as extraction method from water samples after comparison with liquid\u2013liquid extraction, but extraction of the OTs from sediment and mussel samples was performed using toluene. Matrix\u2010matched calibration standards were used to minimize matrix effects. The analytical process was validated by the analysis of spiked blank samples. Performance characteristics such as linearity, detection limit (LOD), quantitation limit (LOQ), precision, and recovery were determined. Recoveries of OTs in spiked matrices ranged from 86\u2013108% in water and from 78\u2013110% in sediments and mussels, with precision values lower than 18%. Detection limits ranged from 0.1\u20139.6 ng\u2009L\n                    <jats:sup>\u22121<\/jats:sup>\n                    in water, and 0.03\u20136.10\u2009\u03bcg\u2009kg\n                    <jats:sup>\u22121<\/jats:sup>\n                    in the other matrices. The present implementation of LPGC rather than conventional capillary GC permitted use of large\u2010volume injection and reduced analysis time by a factor of two. The proposed methodology was applied to the determination of OTs in real samples of water, marine sediments and mussels from the west coast of the Mediterranean Sea (Spain). Copyright \u00a9 2003 John Wiley &amp; Sons, Ltd.\n                  <\/jats:p>","DOI":"10.1002\/rcm.1152","type":"journal-article","created":{"date-parts":[[2003,9,2]],"date-time":"2003-09-02T15:35:49Z","timestamp":1062516949000},"page":"2099-2106","source":"Crossref","is-referenced-by-count":29,"title":["Trace determination of organotin compounds in water, sediment and mussel samples by low\u2010pressure gas chromatography coupled to tandem mass spectrometry"],"prefix":"10.1002","volume":"17","author":[{"given":"J. L. Mart\u00ednez","family":"Vidal","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"A. Belmonte","family":"Vega","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"F. J.","family":"Arrebola","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"M. J.","family":"Gonz\u00e1lez\u2010Rodr\u00edguez","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"M. C. Morales","family":"S\u00e1nchez","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"A. Garrido","family":"Frenich","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2003,8,18]]},"reference":[{"key":"e_1_2_7_2_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0269-7491(97)00019-5"},{"key":"e_1_2_7_3_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0269-7491(97)00186-3"},{"key":"e_1_2_7_4_2","doi-asserted-by":"publisher","DOI":"10.1007\/BF02789767"},{"key":"e_1_2_7_5_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0021-9673(00)00494-5"},{"key":"e_1_2_7_6_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0021-9673(00)00595-1"},{"key":"e_1_2_7_7_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0021-9673(02)01456-5"},{"key":"e_1_2_7_8_2","doi-asserted-by":"publisher","DOI":"10.1016\/0039-9140(93)80238-M"},{"key":"e_1_2_7_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/ac00026a013"},{"key":"e_1_2_7_10_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0021-9673(02)01194-9"},{"key":"e_1_2_7_11_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0021-9673(97)01153-9"},{"key":"e_1_2_7_12_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0021-9673(02)00534-4"},{"key":"e_1_2_7_13_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0021-9673(01)01169-4"},{"key":"e_1_2_7_14_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0021-9673(00)00076-5"},{"key":"e_1_2_7_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/ac60183a005"},{"key":"e_1_2_7_16_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0021-9673(00)80294-0"},{"key":"e_1_2_7_17_2","doi-asserted-by":"publisher","DOI":"10.1255\/ejms.185"},{"key":"e_1_2_7_18_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-4168(20001201)23:12<677::AID-JHRC677>3.0.CO;2-L"},{"key":"e_1_2_7_19_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0021-9673(01)01054-8"},{"key":"e_1_2_7_20_2","doi-asserted-by":"publisher","DOI":"10.1002\/rcm.707"},{"key":"e_1_2_7_21_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0021-9673(02)01843-5"},{"key":"e_1_2_7_22_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0021-9673(97)00733-4"},{"key":"e_1_2_7_23_2","doi-asserted-by":"publisher","DOI":"10.1016\/0003-2670(95)00386-X"},{"key":"e_1_2_7_24_2","doi-asserted-by":"publisher","DOI":"10.1002\/aoc.590050510"},{"key":"e_1_2_7_25_2","doi-asserted-by":"crossref","first-page":"97","DOI":"10.1016\/S0165-9936(99)00199-5","volume":"19","author":"Pellegrino C","year":"2000","journal-title":"Trends Anal. 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