{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,2,19]],"date-time":"2026-02-19T04:51:34Z","timestamp":1771476694453,"version":"3.50.1"},"reference-count":12,"publisher":"Wiley","issue":"20","license":[{"start":{"date-parts":[[2003,9,19]],"date-time":"2003-09-19T00:00:00Z","timestamp":1063929600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Rapid Comm Mass Spectrometry"],"published-print":{"date-parts":[[2003,10,30]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>The detection of unknown organic compounds, e.g., transformation products of known trace pollutants in environmental samples, is a difficult task which can be simplified if the compounds of interest are characterized by a functional group or a heteroatom which can selectively be detected. For the detection of iodinated benzene derivatives, used as X\u2010ray contrast media, we have studied whether such compounds can be selectively detected by negative ion (NI) electrospray ionization via iodide as a product ion of in\u2010source fragmentation, generated by applying a high cone voltage. It was found that selective detection of iodinated benzene derivatives is possible by liquid chromatography\/negative ion electrospray ionization (LC\/NI\u2010ESI) if the compounds are destroyed before entering the mass spectrometer. To our knowledge this is the first report of the use of NI in\u2010source fragmentation MS for analyses traditionally performed with inductively coupled plasma (ICP)\u2010MS. The novel application of NI in\u2010source fragmentation MS is a tool for those who do not possess the facilities to perform ICP\u2010MS. Furthermore, NI\u2010ESI at varying cone voltages provides both structural information and elemental detection, whereas ICP\u2010MS can only provide elemental detection. Copyright \u00a9 2003 John Wiley &amp; Sons, Ltd.<\/jats:p>","DOI":"10.1002\/rcm.1180","type":"journal-article","created":{"date-parts":[[2003,10,8]],"date-time":"2003-10-08T15:35:54Z","timestamp":1065627354000},"page":"2279-2282","source":"Crossref","is-referenced-by-count":30,"title":["Induced in\u2010source fragmentation for the selective detection of organic bound iodine by liquid chromatography\/electrospray mass spectrometry"],"prefix":"10.1002","volume":"17","author":[{"given":"Anke","family":"Putschew","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Martin","family":"Jekel","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2003,9,19]]},"reference":[{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1007\/s002160051581"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/es991118m"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0048-9697(00)00461-7"},{"key":"e_1_2_6_5_2","first-page":"183","volume":"99","author":"Sacher F","year":"2002","journal-title":"Vom Wasser"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0021-9673(01)01186-4"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1002\/rcm.238"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1366\/000370294774368965"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.1366\/000370294774368875"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1366\/0003702944027930"},{"key":"e_1_2_6_11_2","doi-asserted-by":"publisher","DOI":"10.1016\/0165-9936(96)80764-3"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1039\/a603643k"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/ac960175k"}],"container-title":["Rapid Communications in Mass Spectrometry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Frcm.1180","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/analyticalsciencejournals.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/rcm.1180","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,26]],"date-time":"2025-10-26T11:59:57Z","timestamp":1761479997000},"score":1,"resource":{"primary":{"URL":"https:\/\/analyticalsciencejournals.onlinelibrary.wiley.com\/doi\/10.1002\/rcm.1180"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2003,9,19]]},"references-count":12,"journal-issue":{"issue":"20","published-print":{"date-parts":[[2003,10,30]]}},"alternative-id":["10.1002\/rcm.1180"],"URL":"https:\/\/doi.org\/10.1002\/rcm.1180","archive":["Portico"],"relation":{},"ISSN":["0951-4198","1097-0231"],"issn-type":[{"value":"0951-4198","type":"print"},{"value":"1097-0231","type":"electronic"}],"subject":[],"published":{"date-parts":[[2003,9,19]]}}}