{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,26]],"date-time":"2025-10-26T20:54:05Z","timestamp":1761512045981,"version":"build-2065373602"},"reference-count":20,"publisher":"Wiley","issue":"2","license":[{"start":{"date-parts":[[2004,12,9]],"date-time":"2004-12-09T00:00:00Z","timestamp":1102550400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Rapid Comm Mass Spectrometry"],"published-print":{"date-parts":[[2005,1,30]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    On\u2010line\n                    <jats:italic>\u03b4<\/jats:italic>\n                    <jats:sup>34<\/jats:sup>\n                    S analysis of sulfate using an elemental analyzer has a number of advantages vs. conventional off\u2010line techniques, such as ease of operation, rapidity, and the requirement for small amounts of material. Although the analyses are performed by converting sulfate into SO\n                    <jats:sub>2<\/jats:sub>\n                    gas, the effect of sulfate\u2010\n                    <jats:italic>\u03b4<\/jats:italic>\n                    <jats:sup>18<\/jats:sup>\n                    O composition upon the SO\n                    <jats:sub>2<\/jats:sub>\n                    \u2010\n                    <jats:italic>\u03b4<\/jats:italic>\n                    <jats:sup>18<\/jats:sup>\n                    O composition and the value of\n                    <jats:italic>\u03b4<\/jats:italic>\n                    <jats:sup>66<\/jats:sup>\n                    during elemental analysis, and ultimately the calculated sulfate\u2010\n                    <jats:italic>\u03b4<\/jats:italic>\n                    <jats:sup>34<\/jats:sup>\n                    S composition, has rarely been addressed. Three BaSO\n                    <jats:sub>4<\/jats:sub>\n                    samples were prepared with known identical\n                    <jats:italic>\u03b4<\/jats:italic>\n                    <jats:sup>34<\/jats:sup>\n                    S compositions, but with a wide range of\n                    <jats:italic>\u03b4<\/jats:italic>\n                    <jats:sup>18<\/jats:sup>\n                    O compositions.\n                    <jats:italic>\u03b4<\/jats:italic>\n                    <jats:sup>18<\/jats:sup>\n                    O values were shown to range over 40\u2030, but conventional on\u2010line\n                    <jats:italic>\u03b4<\/jats:italic>\n                    <jats:sup>34<\/jats:sup>\n                    S analyses verified that the sulfate\u2010\n                    <jats:italic>\u03b4<\/jats:italic>\n                    <jats:sup>34<\/jats:sup>\n                    S compositions were identical. These results indicate that conventional on\u2010line analysis of sulfate\u2010\n                    <jats:italic>\u03b4<\/jats:italic>\n                    <jats:sup>34<\/jats:sup>\n                    S is unaffected by the value of sulfate\u2010\n                    <jats:italic>\u03b4<\/jats:italic>\n                    <jats:sup>18<\/jats:sup>\n                    O, and suggest that sulfide\u2010\n                    <jats:italic>\u03b4<\/jats:italic>\n                    <jats:sup>34<\/jats:sup>\n                    S standards can be used to calibrate sulfate\u2010\n                    <jats:italic>\u03b4<\/jats:italic>\n                    <jats:sup>34<\/jats:sup>\n                    S analyses (and vice versa). Moreover, these results suggest that it may be possible to use on\u2010line sulfur isotope analysis of SO\n                    <jats:sub>2<\/jats:sub>\n                    to measure\n                    <jats:italic>\u03b4<\/jats:italic>\n                    <jats:sup>33<\/jats:sup>\n                    S and \u0394\n                    <jats:sup>33<\/jats:sup>\n                    S in addition to\n                    <jats:italic>\u03b4<\/jats:italic>\n                    <jats:sup>34<\/jats:sup>\n                    S, as a faster and safer alternative to the SF\n                    <jats:sub>6<\/jats:sub>\n                    technique currently utilized, and hence promote further study of mass\u2010independent sulfur isotope fractionation effects. Copyright \u00a9 2004 John Wiley &amp; Sons, Ltd.\n                  <\/jats:p>","DOI":"10.1002\/rcm.1754","type":"journal-article","created":{"date-parts":[[2005,1,14]],"date-time":"2005-01-14T22:46:45Z","timestamp":1105742805000},"page":"105-107","source":"Crossref","is-referenced-by-count":6,"title":["The effect of sulfate\u2010\n                    <i>\u03b4<\/i>\n                    <sup>18<\/sup>\n                    O upon on\u2010line sulfate\u2010\n                    <i>\u03b4<\/i>\n                    <sup>34<\/sup>\n                    S analysis, and implications for measurements of\n                    <i>\u03b4<\/i>\n                    <sup>33<\/sup>\n                    S and \u0394\n                    <sup>33<\/sup>\n                    S"],"prefix":"10.1002","volume":"19","author":[{"given":"Simon R.","family":"Poulson","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2004,12,9]]},"reference":[{"key":"e_1_2_5_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/ac00090a005"},{"key":"e_1_2_5_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/ac000550f"},{"key":"e_1_2_5_4_2","first-page":"91","volume":"1","author":"Hulston JR","year":"1958","journal-title":"N.Z. 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