{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,8]],"date-time":"2026-07-08T11:56:55Z","timestamp":1783511815176,"version":"3.55.0"},"reference-count":32,"publisher":"Wiley","issue":"6","license":[{"start":{"date-parts":[[2010,2,24]],"date-time":"2010-02-24T00:00:00Z","timestamp":1266969600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Rapid Comm Mass Spectrometry"],"published-print":{"date-parts":[[2010,3,30]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    The reactions of H\n                    <jats:sub>3<\/jats:sub>\n                    O\n                    <jats:sup>+<\/jats:sup>\n                    , NO\n                    <jats:sup>+<\/jats:sup>\n                    , and O\n                    <jats:inline-graphic xmlns:xlink=\"http:\/\/www.w3.org\/1999\/xlink\" xlink:href=\"graphic\/tex2gif-stack-2.gif\" xlink:title=\"urn:x-wiley:09514198:media:RCM4439:tex2gif-stack-2\"\/>\n                    with nineteen ester compounds occurring naturally in plants, and having important flavourant properties, were examined using selected ion flow tube mass spectrometry (SIFT\u2010MS). The H\n                    <jats:sub>3<\/jats:sub>\n                    O\n                    <jats:sup>+<\/jats:sup>\n                    reactions primarily generate [R\n                    <jats:sub>1<\/jats:sub>\n                    COOR\n                    <jats:sub>2<\/jats:sub>\n                    \u00b7H]\n                    <jats:sup>+<\/jats:sup>\n                    , and may also produce [R\n                    <jats:sub>2<\/jats:sub>\n                    ]\n                    <jats:sup>+<\/jats:sup>\n                    fragment ions and\/or fragmentation within the ester linkage. Collisional association\/adduct ions, [R\n                    <jats:sub>1<\/jats:sub>\n                    COOR\n                    <jats:sub>2<\/jats:sub>\n                    \u00b7NO]\n                    <jats:sup>+<\/jats:sup>\n                    , are the main products formed in the NO\n                    <jats:sup>+<\/jats:sup>\n                    reactions, although the carboxyl fragment ion is also detected frequently. The identification of the parent compound may be made more easily in the H\n                    <jats:sub>3<\/jats:sub>\n                    O\n                    <jats:sup>+<\/jats:sup>\n                    and NO\n                    <jats:sup>+<\/jats:sup>\n                    reactions. The inclusion of O\n                    <jats:inline-graphic xmlns:xlink=\"http:\/\/www.w3.org\/1999\/xlink\" xlink:href=\"graphic\/tex2gif-stack-3.gif\" xlink:title=\"urn:x-wiley:09514198:media:RCM4439:tex2gif-stack-3\"\/>\n                    reactions in the analysis provides additional information, which may be applied when the identity of a parent compound cannot be determined solely from the H\n                    <jats:sub>3<\/jats:sub>\n                    O\n                    <jats:sup>+<\/jats:sup>\n                    and NO\n                    <jats:sup>+<\/jats:sup>\n                    analysis. Consideration of the product ions generated with the three precursors suggests that SIFT\u2010MS can differentiate between many of the esters investigated, including isomers, although the product ions generated in the reactions with some esters are too similar to allow independent quantification. Our data therefore suggest that SIFT\u2010MS may be a useful tool to rapidly analyse and quantify flavourant esters in complex gas mixtures. Copyright \u00a9 2010 John Wiley &amp; Sons, Ltd.\n                  <\/jats:p>","DOI":"10.1002\/rcm.4439","type":"journal-article","created":{"date-parts":[[2010,2,24]],"date-time":"2010-02-24T11:28:24Z","timestamp":1267010904000},"page":"815-822","source":"Crossref","is-referenced-by-count":17,"title":["The reactions of H\n                    <sub>3<\/sub>\n                    O\n                    <sup>+<\/sup>\n                    , NO\n                    <sup>+<\/sup>\n                    and O with several flavourant esters studied using selected ion flow tube mass spectrometry"],"prefix":"10.1002","volume":"24","author":[{"given":"Liana","family":"Iachetta","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lada","family":"Malek","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Brian M.","family":"Ross","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2010,2,24]]},"reference":[{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1093\/chemse\/26.5.533"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1111\/j.1365-313X.2008.03446.x"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1007\/s002170050154"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1007\/BF01024605"},{"key":"e_1_2_6_6_2","first-page":"305","volume-title":"Volatile Compounds in Foods and Beverages","author":"Shaw PE","year":"1991"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1111\/j.1742-4658.2005.04732.x"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1201\/9781420037876"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/bk-1998-0714.ch015"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1080\/10408390701638902"},{"key":"e_1_2_6_11_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1097-0010(199607)71:3<329::AID-JSFA588>3.0.CO;2-8"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1515\/CCLM.2000.016"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1007\/978-3-540-49339-6_5"},{"key":"e_1_2_6_14_2","first-page":"203","volume-title":"The Chemistry of Carboxylic Acids and Esters","author":"Ma TS","year":"1969"},{"key":"e_1_2_6_15_2","doi-asserted-by":"publisher","DOI":"10.1016\/S1389-0344(01)00069-7"},{"key":"e_1_2_6_16_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.trac.2008.05.011"},{"key":"e_1_2_6_17_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.aca.2003.12.045"},{"key":"e_1_2_6_18_2","doi-asserted-by":"crossref","first-page":"13","DOI":"10.1093\/clinchem\/23.1.13","volume":"23","author":"Horning EC","year":"1977","journal-title":"Clin. Chem."},{"key":"e_1_2_6_19_2","doi-asserted-by":"publisher","DOI":"10.1002\/mas.20033"},{"key":"e_1_2_6_20_2","doi-asserted-by":"publisher","DOI":"10.1002\/rcm.849"},{"key":"e_1_2_6_21_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0168-1176(97)00085-2"},{"key":"e_1_2_6_22_2","doi-asserted-by":"publisher","DOI":"10.1186\/1756-0500-1-41"},{"key":"e_1_2_6_23_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijms.2005.12.024"},{"key":"e_1_2_6_24_2","doi-asserted-by":"publisher","DOI":"10.1002\/rcm.4340"},{"key":"e_1_2_6_25_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijms.2008.11.007"},{"key":"e_1_2_6_26_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.442828"},{"key":"e_1_2_6_27_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0168-1176(97)00246-2"},{"key":"e_1_2_6_28_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00716a026"},{"key":"e_1_2_6_29_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0168-1176(97)00277-2"},{"key":"e_1_2_6_30_2","doi-asserted-by":"publisher","DOI":"10.1186\/1471-2407-9-348"},{"key":"e_1_2_6_31_2","volume-title":"CRC Handbook of Chemistry and Physics","author":"Lide DR","year":"2006"},{"key":"e_1_2_6_32_2","volume-title":"Tables of Experimental Dipole Moments","author":"McClellan AL","year":"1963"},{"key":"e_1_2_6_33_2","volume-title":"A Table of Dipole Moments","author":"Sidgwick NV","year":"1934"}],"container-title":["Rapid Communications in Mass Spectrometry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Frcm.4439","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Frcm.4439","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/analyticalsciencejournals.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/rcm.4439","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,26]],"date-time":"2025-10-26T14:01:58Z","timestamp":1761487318000},"score":1,"resource":{"primary":{"URL":"https:\/\/analyticalsciencejournals.onlinelibrary.wiley.com\/doi\/10.1002\/rcm.4439"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2010,2,24]]},"references-count":32,"journal-issue":{"issue":"6","published-print":{"date-parts":[[2010,3,30]]}},"alternative-id":["10.1002\/rcm.4439"],"URL":"https:\/\/doi.org\/10.1002\/rcm.4439","archive":["Portico"],"relation":{},"ISSN":["0951-4198","1097-0231"],"issn-type":[{"value":"0951-4198","type":"print"},{"value":"1097-0231","type":"electronic"}],"subject":[],"published":{"date-parts":[[2010,2,24]]}}}