{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,29]],"date-time":"2026-07-29T21:04:19Z","timestamp":1785359059458,"version":"3.55.0"},"reference-count":20,"publisher":"Wiley","issue":"20","license":[{"start":{"date-parts":[[2010,9,22]],"date-time":"2010-09-22T00:00:00Z","timestamp":1285113600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Rapid Comm Mass Spectrometry"],"published-print":{"date-parts":[[2010,10,30]]},"abstract":"Abstract<\/jats:title>\n \n Stable complexes are required during the ion chromatographic (IC) separation of Fe\u2010polycarboxylic acid complexes. Electrospray ionization mass spectrometry (ESI\u2010MS) was used to identify 1:1 stoichiometric complexes of Fe[HEDTA], Fe[EDTA]\n 1\u2212<\/jats:sup>\n and Fe[DTPA]\n 2\u2212<\/jats:sup>\n , and the spectra showed that these Fe complexes were stable in solution. Furthermore, inductively coupled plasma mass spectrometry (ICP\u2010MS) using an octopole reaction system (ORS) reduced polyatomic ion\n 40<\/jats:sup>\n Ar\n 16<\/jats:sup>\n O\n +<\/jats:sup>\n interference in the detection of\n 56<\/jats:sup>\n Fe via the addition of either H\n 2<\/jats:sub>\n or He to the ORS, with He at a flow rate 3.5\u2009mL\u2009min\n \u22121<\/jats:sup>\n being the optimum collision gas. Finally, IC\/ICP\u2010MS was used for the separation and detection of Fe complexes with an eluent containing 30\u2009mM (NH\n 4<\/jats:sub>\n )\n 2<\/jats:sub>\n HPO\n 4<\/jats:sub>\n at pH 8.0, but only Fe[HEDTA], Fe[EDTA]\n 1\u2212<\/jats:sup>\n and Fe[DTPA]\n 2\u2212<\/jats:sup>\n were observed within 10\u2009min with reasonable resolution. Detection limits in the range of 10\u201313\u2009\u00b5g L\n \u22121<\/jats:sup>\n were achieved using He as the collision gas. The proposed method was used for the determination of Fe species in soil solutions. Copyright \u00a9 2010 John Wiley & Sons, Ltd.\n <\/jats:p>","DOI":"10.1002\/rcm.4737","type":"journal-article","created":{"date-parts":[[2010,9,22]],"date-time":"2010-09-22T10:09:03Z","timestamp":1285150143000},"page":"2993-2998","source":"Crossref","is-referenced-by-count":1,"title":["Identification of Fe\u2010polycarboxylic complexes by electrospray ionization mass spectrometry and reduction of interferences by ion chromatography\/inductively coupled plasma mass spectrometry with an octopole reaction system"],"prefix":"10.1002","volume":"24","author":[{"given":"Zu\u2010Liang","family":"Chen","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiao\u2010ying","family":"Jin","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Li","family":"Gan","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2010,9,22]]},"reference":[{"key":"e_1_2_6_2_2","doi-asserted-by":"crossref","first-page":"548","DOI":"10.17221\/4192-PSE","volume":"49","author":"Kos B","year":"2001","journal-title":"Plant Soil Environ."},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1146\/annurev.arplant.49.1.643"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.chemosphere.2004.09.047"},{"key":"e_1_2_6_5_2","unstructured":"DR Parker WA Norvell RL Chaney 1995 GEOCHEM\u2010PC SSSA Special Publication 42 Madison Wisconsin 253 269"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.sab.2003.09.004"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/es001893y"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1007\/s00216-005-3315-0"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2003.10.095"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2006.09.060"},{"key":"e_1_2_6_11_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0021-9673(00)00964-X"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0021-9673(03)00527-2"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2006.07.004"},{"key":"e_1_2_6_14_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0021-9673(97)00839-X"},{"key":"e_1_2_6_15_2","doi-asserted-by":"publisher","DOI":"10.1002\/mas.20070"},{"key":"e_1_2_6_16_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.aca.2007.08.012"},{"key":"e_1_2_6_17_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.microc.2006.12.001"},{"key":"e_1_2_6_18_2","doi-asserted-by":"publisher","DOI":"10.1021\/es990309m"},{"key":"e_1_2_6_19_2","doi-asserted-by":"publisher","DOI":"10.1039\/b312250f"},{"key":"e_1_2_6_20_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0165-9936(01)00071-1"},{"key":"e_1_2_6_21_2","volume-title":"Ion Chromatography","author":"Weiss J","year":"1995"}],"container-title":["Rapid Communications in Mass Spectrometry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Frcm.4737","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/analyticalsciencejournals.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/rcm.4737","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,26]],"date-time":"2025-10-26T14:29:10Z","timestamp":1761488950000},"score":1,"resource":{"primary":{"URL":"https:\/\/analyticalsciencejournals.onlinelibrary.wiley.com\/doi\/10.1002\/rcm.4737"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2010,9,22]]},"references-count":20,"journal-issue":{"issue":"20","published-print":{"date-parts":[[2010,10,30]]}},"alternative-id":["10.1002\/rcm.4737"],"URL":"https:\/\/doi.org\/10.1002\/rcm.4737","archive":["Portico"],"relation":{},"ISSN":["0951-4198","1097-0231"],"issn-type":[{"value":"0951-4198","type":"print"},{"value":"1097-0231","type":"electronic"}],"subject":[],"published":{"date-parts":[[2010,9,22]]}}}