{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,2]],"date-time":"2026-10-02T12:03:20Z","timestamp":1790942600715,"version":"4.1.0"},"reference-count":35,"publisher":"Wiley","issue":"8","license":[{"start":{"date-parts":[[2011,3,29]],"date-time":"2011-03-29T00:00:00Z","timestamp":1301356800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Rapid Comm Mass Spectrometry"],"published-print":{"date-parts":[[2011,4,30]]},"abstract":"<jats:p>\n                    Electrospray ionization mass spectrometry (ESI\u2010MS) is used to probe the complex formation between tebuconazole (1) and copper(II) salts, which both are commonly used fungicides in agriculture. Experiments with model solutions containing 1 and CuCl\n                    <jats:sub>2<\/jats:sub>\n                    reveal the initial formation of the copper(II) species [(1)CuCl]\n                    <jats:sup>+<\/jats:sup>\n                    and [(1)\n                    <jats:sub>2<\/jats:sub>\n                    CuCl]\n                    <jats:sup>+<\/jats:sup>\n                    which undergo reduction to the corresponding copper(I) ions [(1)Cu]\n                    <jats:sup>+<\/jats:sup>\n                    and [(1)\n                    <jats:sub>2<\/jats:sub>\n                    Cu]\n                    <jats:sup>+<\/jats:sup>\n                    under more drastic ionization conditions in the ESI source. In additional experiments, copper\/tebuconazole complexes were also detected in samples made from soil solutions of various origin and different amount of mineralization. The direct sampling of such solutions via ESI\u2010MS is thus potentially useful for understanding of the interactions between copper(II) salts and tebuconazole in environmental samples. Copyright \u00a9 2011 John Wiley &amp; Sons, Ltd.\n                  <\/jats:p>","DOI":"10.1002\/rcm.4957","type":"journal-article","created":{"date-parts":[[2011,3,31]],"date-time":"2011-03-31T04:14:12Z","timestamp":1301544852000},"page":"1037-1042","source":"Crossref","is-referenced-by-count":37,"title":["Complexation between the fungicide tebuconazole and copper(\n                    <scp>II<\/scp>\n                    ) probed by electrospray ionization mass spectrometry"],"prefix":"10.1002","volume":"25","author":[{"given":"Jana Jaklov\u00e1","family":"Dytrtov\u00e1","sequence":"first","affiliation":[{"name":"Institute of Organic Chemistry and Biochemistry Academy of Sciences of the Czech Republic  v.v.i., Flemingovo n\u00e1m\u011bst\u00ed 2 166 10 Prague 6 Czech Republic"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Michal","family":"Jakl","sequence":"additional","affiliation":[{"name":"Department of Agro\u2010Environmental Chemistry and Plant Nutrition Faculty of Agrobiology, Food and Natural Resources Czech University of Life Sciences  Kam\u00fdck\u00e1 129 165 21 Prague Suchdol Czech Republic"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Detlef","family":"Schr\u00f6der","sequence":"additional","affiliation":[{"name":"Institute of Organic Chemistry and Biochemistry Academy of Sciences of the Czech Republic  v.v.i., Flemingovo n\u00e1m\u011bst\u00ed 2 166 10 Prague 6 Czech Republic"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Eva","family":"\u010cadkov\u00e1","sequence":"additional","affiliation":[{"name":"Department of Agro\u2010Environmental Chemistry and Plant Nutrition Faculty of Agrobiology, Food and Natural Resources Czech University of Life Sciences  Kam\u00fdck\u00e1 129 165 21 Prague Suchdol Czech Republic"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Michael","family":"Kom\u00e1rek","sequence":"additional","affiliation":[{"name":"Department of Agro\u2010Environmental Chemistry and Plant Nutrition Faculty of Agrobiology, Food and Natural Resources Czech University of Life Sciences  Kam\u00fdck\u00e1 129 165 21 Prague Suchdol Czech Republic"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2011,3,29]]},"reference":[{"key":"e_1_2_6_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2008.06.007"},{"key":"e_1_2_6_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/mas.20137"},{"key":"e_1_2_6_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp710875x"},{"key":"e_1_2_6_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200701277"},{"key":"e_1_2_6_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200800052"},{"key":"e_1_2_6_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja801079r"},{"key":"e_1_2_6_8_1","doi-asserted-by":"publisher","DOI":"10.1135\/cccc2008184"},{"key":"e_1_2_6_9_1","doi-asserted-by":"publisher","DOI":"10.1039\/b904403e"},{"key":"e_1_2_6_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja902773b"},{"key":"e_1_2_6_11_1","doi-asserted-by":"publisher","DOI":"10.1201\/9781420049220"},{"key":"e_1_2_6_12_1","volume-title":"The Report of the Joint Meeting of the FAO Panel of Experts on Pesticide Residues in Food and the Environment and the WHO Expert Group on Pesticide Residues","author":"Report of the Food and Agriculture Organization of the United Nations (FAO)","year":"1994"},{"key":"e_1_2_6_13_1","unstructured":"H. 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