{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,5,6]],"date-time":"2026-05-06T11:23:11Z","timestamp":1778066591799,"version":"3.51.4"},"reference-count":70,"publisher":"Wiley","issue":"10","license":[{"start":{"date-parts":[[2018,4,22]],"date-time":"2018-04-22T00:00:00Z","timestamp":1524355200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100008530","name":"European Regional Development Fund","doi-asserted-by":"publisher","award":["CZ.1.05\/2.1.00\/03.0086"],"award-info":[{"award-number":["CZ.1.05\/2.1.00\/03.0086"]}],"id":[{"id":"10.13039\/501100008530","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["analyticalsciencejournals.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Rapid Comm Mass Spectrometry"],"published-print":{"date-parts":[[2018,5,30]]},"abstract":"<jats:sec>\n                    <jats:title>Rationale<\/jats:title>\n                    <jats:p>Only a few arsenic phosphides are known. A high potential for the generation of new compounds is offered by Laser Ablation Synthesis (LAS) and when Laser Desorption Ionization (LDI) is coupled with simultaneous Time\u2010Of\u2010Flight Mass Spectrometry (TOFMS), immediate identification of the clusters can be achieved.<\/jats:p>\n                  <\/jats:sec>\n                  <jats:sec>\n                    <jats:title>Methods<\/jats:title>\n                    <jats:p>LAS was used for the generation of arsenic phosphides via laser ablation of phosphorus\u2013arsenic mixtures while quadrupole ion trap time\u2010of\u2010flight mass spectrometry (QIT\u2010TOFMS) was used to acquire the mass spectra.<\/jats:p>\n                  <\/jats:sec>\n                  <jats:sec>\n                    <jats:title>Results<\/jats:title>\n                    <jats:p>\n                      Many new As\n                      <jats:sub>\n                        <jats:italic>m<\/jats:italic>\n                      <\/jats:sub>\n                      P\n                      <jats:sub>\n                        <jats:italic>n<\/jats:italic>\n                      <\/jats:sub>\n                      <jats:sup>\n                        <jats:italic>\u00b1<\/jats:italic>\n                      <\/jats:sup>\n                      clusters (479 binary and 369 mono\u2010elemental) not yet described in the literature were generated in the gas phase and their stoichiometry determined. The likely structures for some of the observed clusters arbitrary selected (20) were computed by density functional theory (DFT) optimization.\n                    <\/jats:p>\n                  <\/jats:sec>\n                  <jats:sec>\n                    <jats:title>Conclusions<\/jats:title>\n                    <jats:p>\n                      LAS is an advantageous approach for the generation of new As\n                      <jats:sub>\n                        <jats:italic>m<\/jats:italic>\n                      <\/jats:sub>\n                      P\n                      <jats:sub>\n                        <jats:italic>n<\/jats:italic>\n                      <\/jats:sub>\n                      clusters, while mass spectrometry was found to be an efficient technique for the determination of cluster stoichiometry. The results achieved might inspire the synthesis of new materials.\n                    <\/jats:p>\n                  <\/jats:sec>","DOI":"10.1002\/rcm.8106","type":"journal-article","created":{"date-parts":[[2018,3,8]],"date-time":"2018-03-08T22:32:45Z","timestamp":1520548365000},"page":"789-800","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["Laser ablation synthesis of arsenic\u2013phosphide As\n                    <sub>\n                      <i>m<\/i>\n                    <\/sub>\n                    P\n                    <sub>\n                      <i>n<\/i>\n                    <\/sub>\n                    clusters from As\u2013P mixtures. Laser desorption ionisation with quadrupole ion trap time\u2010of\u2010flight mass spectrometry: The mass spectrometer as a synthesizer"],"prefix":"10.1002","volume":"32","author":[{"given":"Pavel","family":"Kub\u00e1\u010dek","sequence":"first","affiliation":[{"name":"Department of Chemistry, Faculty of Science Masaryk University  Kamenice 5\/A14 625 00 Brno Czech Republic"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Lubom\u00edr","family":"Proke\u0161","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Faculty of Science Masaryk University  Kamenice 5\/A14 625 00 Brno Czech Republic"},{"name":"Department of Physical Electronics, Faculty of Science Masaryk University  Kotl\u00e1\u0159sk\u00e1 2 611 37 Brno Czech Republic"},{"name":"CEPLANT, R&amp;D Centre for Low\u2010Cost Plasma and Nanotechnology Surface Modifications Masaryk University  Kotl\u00e1\u0159sk\u00e1 2 611 37 Brno Czech Republic"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Annapurna","family":"Pamreddy","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Faculty of Science Masaryk University  Kamenice 5\/A14 625 00 Brno Czech Republic"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Eladia Mar\u00eda","family":"Pe\u00f1a\u2010M\u00e9ndez","sequence":"additional","affiliation":[{"name":"Departamento de Qu\u00edmica, Unidad Departamental de Qu\u00edmica Anal\u00edtica, Facultad de Ciencias Universidad de La Laguna (ULL)  Avda. Astrof\u00edsico Fco. S\u00e1nchez, s\/n 38206 La Laguna Spain"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jos\u00e9 Elias","family":"Conde","sequence":"additional","affiliation":[{"name":"Departamento de Qu\u00edmica, Unidad Departamental de Qu\u00edmica Anal\u00edtica, Facultad de Ciencias Universidad de La Laguna (ULL)  Avda. Astrof\u00edsico Fco. S\u00e1nchez, s\/n 38206 La Laguna Spain"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Milan","family":"Alberti","sequence":"additional","affiliation":[{"name":"Department of Physical Electronics, Faculty of Science Masaryk University  Kotl\u00e1\u0159sk\u00e1 2 611 37 Brno Czech Republic"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6675-5671","authenticated-orcid":false,"given":"Josef","family":"Havel","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Faculty of Science Masaryk University  Kamenice 5\/A14 625 00 Brno Czech Republic"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2018,4,22]]},"reference":[{"key":"e_1_2_6_2_1","volume-title":"Encyclopedia of Inorganic Chemistry","author":"P\u00f6ttgen R","year":"2005"},{"key":"e_1_2_6_3_1","volume-title":"Phosphorus. 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