{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,2,26]],"date-time":"2026-02-26T15:12:14Z","timestamp":1772118734815,"version":"3.50.1"},"reference-count":34,"publisher":"Wiley","issue":"1","license":[{"start":{"date-parts":[[2021,11,8]],"date-time":"2021-11-08T00:00:00Z","timestamp":1636329600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["analyticalsciencejournals.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Rapid Comm Mass Spectrometry"],"published-print":{"date-parts":[[2022,1,15]]},"abstract":"<jats:sec>\n                    <jats:title>Rationale<\/jats:title>\n                    <jats:p>Organophosphorus compounds with phosphorus atom bonded to one methyl, ethyl or propyl (normal or iso) group are listed in Schedule 2 of the Chemical Weapons Convention (CWC). Selenophosphorus compounds, listed in Schedule 2.B.4, have very limited representation in mass spectral libraries and the open literature.<\/jats:p>\n                  <\/jats:sec>\n                  <jats:sec>\n                    <jats:title>Methods<\/jats:title>\n                    <jats:p>Members of a new category of selenophosphorus compounds were prepared via microsynthetic protocols and their fragmentation pathways were investigated using electron ionization (EI) and positive electrospray ionization (ESI) mass spectrometry. The EI and ESI fragmentation pathways were suggested and supported by acquired fragment ions of deuterated analogs and density functional theory calculations.<\/jats:p>\n                  <\/jats:sec>\n                  <jats:sec>\n                    <jats:title>Results<\/jats:title>\n                    <jats:p>Mass spectrometric investigations showed some interesting fragmentation pathways, such as McLafferty\u2010type, selenono\u2013selenolo rearrangements, intramolecular electrophilic aromatic substitution reaction and \u03b1\u2010cleavage.<\/jats:p>\n                  <\/jats:sec>\n                  <jats:sec>\n                    <jats:title>Conclusions<\/jats:title>\n                    <jats:p>Efficient microsynthesis was conducted, and EI\u2010MS spectra and ESI\u2010MS\/MS spectra of a series of selenophosphorus compounds were collected and studied with the purpose of identifying CWC\u2010related chemicals during on\u2010site inspection and\/or off\u2010site analysis.<\/jats:p>\n                  <\/jats:sec>","DOI":"10.1002\/rcm.9209","type":"journal-article","created":{"date-parts":[[2021,10,8]],"date-time":"2021-10-08T19:42:10Z","timestamp":1633722130000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Structural characterization of Chemical Weapons Convention\u2010related phosphonoselenoates by electron ionization and electrospray ionization mass spectrometry"],"prefix":"10.1002","volume":"36","author":[{"given":"Seyed Esmaeil","family":"Hosseini","sequence":"first","affiliation":[{"name":"Defense Chemical Research Lab (DCRL)  Karaj Iran"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Sajjad","family":"Mousavi Faraz","sequence":"additional","affiliation":[{"name":"Defense Chemical Research Lab (DCRL)  Karaj Iran"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Mohammad Taghi","family":"Naseri","sequence":"additional","affiliation":[{"name":"Defense Chemical Research Lab (DCRL)  Karaj Iran"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Davood","family":"Ashrafi","sequence":"additional","affiliation":[{"name":"Defense Chemical Research Lab (DCRL)  Karaj Iran"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1516-9178","authenticated-orcid":false,"given":"Hamid","family":"Saeidian","sequence":"additional","affiliation":[{"name":"Department of Science Payame Noor University (PNU)  Tehran Iran"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2021,11,8]]},"reference":[{"key":"e_1_2_6_2_1","doi-asserted-by":"publisher","DOI":"10.1590\/S0103-50532009000300003"},{"key":"e_1_2_6_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.tox.2005.06.011"},{"key":"e_1_2_6_4_1","volume-title":"Chemical Weapons Disarmament in Russia: Problems and Prospects","author":"Mirzayanov S","year":"1995"},{"issue":"12","key":"e_1_2_6_5_1","first-page":"3","article-title":"Nerve agent attack on spy used Novichok poison","volume":"96","author":"Peplow M","year":"2018","journal-title":"Chem Eng News"},{"key":"e_1_2_6_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jns.2006.06.007"},{"issue":"2","key":"e_1_2_6_7_1","first-page":"97","article-title":"Acute and long\u2010term impact of chemical weapons: Lessons from the Iran\u2010Iraq war","volume":"26","author":"Haines DD","year":"2014","journal-title":"Forensic Sci Rev"},{"key":"e_1_2_6_8_1","doi-asserted-by":"publisher","DOI":"10.1007\/978-3-319-51761-2_15-1"},{"key":"e_1_2_6_9_1","unstructured":"VanninenP.Recommended Operating Procedures for Analysis in the Verification of Chemical Disarmament University of Helsinki Section 1 Part B Chapter V P114 2017."},{"key":"e_1_2_6_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.trac.2014.10.012"},{"key":"e_1_2_6_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/0470012285.ch6"},{"key":"e_1_2_6_12_1","unstructured":"Organization for the Prohibition of Chemical Weapons (OPCW) Status of laboratories designated for the analysis of authentic environmental sample S\/1775\/2019 July 23 2019."},{"key":"e_1_2_6_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.scitotenv.2019.05.205"},{"key":"e_1_2_6_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/jm00313a032"},{"key":"e_1_2_6_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/0006-2952(69)90162-2"},{"key":"e_1_2_6_16_1","doi-asserted-by":"publisher","DOI":"10.3109\/14756368509031277"},{"key":"e_1_2_6_17_1","doi-asserted-by":"publisher","DOI":"10.1080\/07328309008543845"},{"key":"e_1_2_6_18_1","doi-asserted-by":"publisher","DOI":"10.34101\/actaagrar\/64\/1859"},{"key":"e_1_2_6_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/biof.5520090105"},{"key":"e_1_2_6_20_1","doi-asserted-by":"publisher","DOI":"10.1080\/10426507.2018.1487429"},{"key":"e_1_2_6_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/jms.4045"},{"key":"e_1_2_6_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/rcm.7757"},{"key":"e_1_2_6_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/rcm.6407"},{"key":"e_1_2_6_24_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijms.2014.06.003"},{"key":"e_1_2_6_25_1","doi-asserted-by":"publisher","DOI":"10.1080\/17415993.2019.1618855"},{"key":"e_1_2_6_26_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijms.2012.03.006"},{"key":"e_1_2_6_27_1","doi-asserted-by":"publisher","DOI":"10.1007\/s00216-013-7094-8"},{"key":"e_1_2_6_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr990029p"},{"key":"e_1_2_6_29_1","doi-asserted-by":"publisher","DOI":"10.3998\/ark.5550190.0008.e10"},{"key":"e_1_2_6_30_1","volume-title":"Preparation of Methylphosphonic Dichloride: The Preparatory Manual of Chemical Warfare Agents","author":"Ledgard JB","year":"2003"},{"key":"e_1_2_6_31_1","volume-title":"Gaussian 09","author":"Frisch MJ","year":"2013"},{"key":"e_1_2_6_32_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0021-9673(01)80947-X"},{"key":"e_1_2_6_33_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijms.2016.10.002"},{"key":"e_1_2_6_34_1","doi-asserted-by":"publisher","DOI":"10.1007\/978-0-387-44899-2_1"},{"key":"e_1_2_6_35_1","doi-asserted-by":"publisher","DOI":"10.1002\/9780470027318.a0408.pub3"}],"container-title":["Rapid Communications in Mass Spectrometry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/rcm.9209","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/rcm.9209","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/analyticalsciencejournals.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/rcm.9209","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,26]],"date-time":"2025-10-26T15:29:32Z","timestamp":1761492572000},"score":1,"resource":{"primary":{"URL":"https:\/\/analyticalsciencejournals.onlinelibrary.wiley.com\/doi\/10.1002\/rcm.9209"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2021,11,8]]},"references-count":34,"journal-issue":{"issue":"1","published-print":{"date-parts":[[2022,1,15]]}},"alternative-id":["10.1002\/rcm.9209"],"URL":"https:\/\/doi.org\/10.1002\/rcm.9209","archive":["Portico"],"relation":{"has-review":[{"id-type":"doi","id":"10.1002\/RCM.9209\/v2\/review3","asserted-by":"object"},{"id-type":"doi","id":"10.1002\/RCM.9209\/v2\/review2","asserted-by":"object"},{"id-type":"doi","id":"10.1002\/RCM.9209\/v2\/review1","asserted-by":"object"},{"id-type":"doi","id":"10.1002\/RCM.9209\/v1\/decision1","asserted-by":"object"},{"id-type":"doi","id":"10.1002\/RCM.9209\/v2\/response1","asserted-by":"object"},{"id-type":"doi","id":"10.1002\/RCM.9209\/v1\/review2","asserted-by":"object"},{"id-type":"doi","id":"10.1002\/RCM.9209\/v3\/decision1","asserted-by":"object"},{"id-type":"doi","id":"10.1002\/RCM.9209\/v1\/review1","asserted-by":"object"},{"id-type":"doi","id":"10.1002\/RCM.9209\/v3\/response1","asserted-by":"object"},{"id-type":"doi","id":"10.1002\/RCM.9209\/v2\/decision1","asserted-by":"object"},{"id-type":"doi","id":"10.1002\/RCM.9209\/v1\/review3","asserted-by":"object"}]},"ISSN":["0951-4198","1097-0231"],"issn-type":[{"value":"0951-4198","type":"print"},{"value":"1097-0231","type":"electronic"}],"subject":[],"published":{"date-parts":[[2021,11,8]]},"assertion":[{"value":"2021-06-11","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2021-10-05","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2021-11-08","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e9209"}}